NAUTILUS EPOXY FAST LIGHT FILLER comp. A

Rev. 1 di may 2013 - n° lotto 317002

 

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
Trade Name :                                                           NAUTILUS FAST EPOXY LIGHT FILLER comp. A
Use of the substance / preparation:                    Epoxy Filler
 Supplier:                                         Cecchi Gustavo & C., Via Coppino 253, Viareggio 55049 (LU)
tel 0039 0584/383694 fax 0039 0584/395182 www.cecchi.it - info@cecchi.it
Information in case of emergency:      +39 0584/383694

2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CHIP: Xi: R36/38; Sens.: R43; N: R51/53
Classification under CLP: Aquatic Chronic 2: H411; Eye Irrit. 2: H319; Skin Irrit. 2: H315; Skin Sens. 1: H317
Most important adverse effects: Irritating to eyes and skin. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
2.2. Label elements
Label elements under CLP:
Hazard statements: H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H411: Toxic to aquatic life with long lasting effects.
Signal words: Warning
Hazard pictograms: GHS07: Exclamation mark
GHS09: Environmental
Precautionary statements: P264: Wash thoroughly after handling.
P273: Avoid release to the environment.
P280: Wear.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P321: Specific treatment (see on this label).
P332+313: If skin irritation occurs: Get medical.
Label elements under CHIP:
Hazard symbols: Dangerous for the environment.
Irritant.
Risk phrases: R36/38: Irritating to eyes and skin.
R43: May cause sensitisation by skin contact.
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Safety phrases: S24: Avoid contact with skin.
S37: Wear suitable gloves.
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
Precautionary phrases: Restricted to professional users.
2.3. Other hazards
PBT: This substance is not identified as a PBT substance.

3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients:
BISPHENOL A-(EPICHLORHYDRIN) {REACTION PRODUCT}
EINECS CAS CHIP Classification CLP Classification Percent
500-033-5 25068-38-6 Xi: R36/38; Sens.: R43; N: R51/53 Eye Irrit. 2: H319; Skin Irrit. 2: H315;
Skin Sens. 1: H317; Aquatic Chronic
2: H411
40-70%
1,4-BIS[(VINYLOXY)METHYL]CYCLOHEXANE
413-370-7 17351-75-6 Sens.: R43; N: R51/53 Skin Sens. 1: H317; Aquatic Chronic
2: H411
10-20%
1,4-BIS(2,3-EPOXYPROPOXY) BUTANE
219-371-7 2425-79-8 Xn: R20/21; Xi: R36/38; Sens.:
R43
Acute Tox. 4: H332; Acute Tox. 4:
H312; Eye Irrit. 2: H319; Skin Irrit. 2:
H315; Skin Sens. 1: H317
1-10%

4: First aid measures
4.1. Description of first aid measures
Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash
immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.
Ingestion: Wash out mouth with water. Consult a doctor.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a
doctor.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and redness. The eyes may water profusely.
Ingestion: There may be soreness and redness of the mouth and throat.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may
cause coughing or wheezing.
4.3. Indication of any immediate medical attention and special treatment needed

5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: In combustion emits toxic fumes.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions: Refer to section 8 of SDS for personal protection details. If outside do not approach from downwind. If outside keep bystanders upwind and away from danger point. Mark out the
contaminated area with signs and prevent access to unauthorised personnel. Turn
leaking containers leak-side up to prevent the escape of liquid.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for
disposal by an appropriate method.
6.4. Reference to other sections

7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area.
Do not handle in a confined space. Avoid the formation or spread of mists in the air.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions: Store in cool, well ventilated area. Keep container tightly closed. The floor of the storage room must be impermeable to prevent the escape of liquids.
Suitable packaging: Coated steel.
7.3. Specific end use(s)

8: Exposure controls/personal protection
8.1. Control parameters
Workplace exposure limits: Not applicable.
8.2. Exposure controls
Engineering measures: Ensure there is sufficient ventilation of the area. The floor of the storage room must be impermeable to prevent the escape of liquids.
Respiratory protection: Self-contained breathing apparatus must be available in case of emergency.
Hand protection: Nitrile gloves. Breakthrough time of the glove material > 8 hours.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Impermeable protective clothing.

9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Liquid
Colour: White
Solubility in water: Not miscible
Also soluble in: Most organic solvents.
Viscosity: Viscous
Boiling point/range°C: n.V. Melting point/range°C: n.V.
Flammability limits %: lower: n.V.
upper: n.V.
Flash point°C: 147 Part.coeff. n-octanol/water: n.V.
Autoflammability°C: n.a. Vapour pressure: n.V.
Relative density: 0,5-0,7 g/ml pH: n.a.
VOC g/l: ENTFÄLLT
9.2. Other information
Other information: Not applicable.

10: Stability and reactivity
10.1. Reactivity
10.2. Chemical stability
Chemical stability: Stable under normal conditions.
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
Conditions to avoid: Heat.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents. Strong acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.

11: Toxicological information
11.1. Information on toxicological effects
Toxicity values: Not applicable.
Symptoms / routes of exposure
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and redness. The eyes may water profusely.
Ingestion: There may be soreness and redness of the mouth and throat.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may
cause coughing or wheezing.

12: Ecological information
12.1. Toxicity
Ecotoxicity values: Not applicable.
12.2. Persistence and degradability
Persistence and degradability: Not biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: Bioaccumulation potential.
12.4. Mobility in soil
Mobility: Readily absorbed into soil.
12.5. Results of PBT and vPvB assessment
PBT identification: This substance is not identified as a PBT substance.
12.6. Other adverse effects
Other adverse effects: Toxic to aquatic organisms. Toxic to soil organisms.

13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal
company.
Waste code number: 08 04 09
Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes.
NB: The user's attention is drawn to the possible existence of regional or national
regulations regarding disposal.

14: Transport information
14.1. UN number
UN number: UN3082
14.2. UN proper shipping name
Shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
   BISPHENOL A-(EPICHLORHYDRIN) {REACTION PRODUCT}
  1,4-BIS[(VINYLOXY)METHYL]CYCLOHEXANE
14.3. Transport hazard class(es)
Transport class: 9
14.4. Packing group
Packing group: III
14.5. Environmental hazards
Environmentally hazardous: Yes Marine pollutant: No
14.6. Special precautions for user
Tunnel code: E
Transport category: 3

15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.2. Chemical Safety Assessment
Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.
Phrases used in s.2 and 3: H312: Harmful in contact with skin.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H411: Toxic to aquatic life with long lasting effects.
R20/21: Harmful by inhalation and in contact with skin.
R36/38: Irritating to eyes and skin.
R43: May cause sensitisation by skin contact.
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.