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1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
Identification of Substance or Preparation Trade Name :
NAUTILUS FAST EPOXY FINE FILLER comp. B
Use of the substance / preparation: Epoxy Filler
Supplier: Cecchi Gustavo & C., Via Coppino 253, Viareggio 55049 (LU)
tel 0039 0584/383694 fax 0039 0584/395182 www.cecchi.it - info@cecchi.it
Information in case of emergency: +39 0584/383694
2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CHIP: Xn: R21/22; C: R34; Sens.: R43; Xn: R68
Classification under CLP: Eye Dam. 1: H318; Muta. 2: H341; Skin Irrit. 2: H315; Skin Sens. 1: H317
Most important adverse effects: Harmful in contact with skin and if swallowed. Causes burns. May cause sensitisation
by skin contact. Possible risk of irreversible effects.
2.2. Label elements
Label elements under CLP:
Hazard statements: H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H318: Causes serious eye damage.
H341: Suspected of causing genetic defects.
Signal words: Danger
Hazard pictograms: GHS05: Corrosion
GHS07: Exclamation mark
GHS08: Health hazard
Precautionary statements: P202: Do not handle until all safety precautions have been read and understood.
P280: Wear.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical.
P310: Immediately call a POISON CENTER or doctor.
P321: Specific treatment (see on this label).
Label elements under CHIP:
Hazard symbols: Corrosive.
Risk phrases: R21/22: Harmful in contact with skin and if swallowed.
R34: Causes burns.
R43: May cause sensitisation by skin contact.
R68: Possible risk of irreversible effects.
Safety phrases: S26: In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye / face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
Precautionary phrases: Restricted to professional users.
2.3. Other hazards
PBT: This substance is not identified as a PBT substance.
3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients:
BENZYL ALCOHOL
EINECS CAS CHIP Classification CLP Classification Percent
202-859-9 100-51-6 Xn: R20/22 Acute Tox. 4: H332; Acute Tox. 4: H302 1-10%
M-XYLYLENDIAMIN
- - Xn: R20/22; C: R34; Sens.: R43; -:
R52/53
Acute Tox. 4: H302+332; Aquatic
Chronic 3: H412; Skin Corr. 1B: H314;
Skin Sens. 1: H317
1-10%
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL
202-013-9 90-72-2 Xn: R22; Xi: R36/38 Acute Tox. 4: H302; Eye Irrit. 2: H319;
Skin Irrit. 2: H315
1-10%
PHENOL
203-632-7 108-95-2 T: R23/24/25; C: R34; Xn:
R48/20/21/22; Xn: R68
Muta. 2: H341; Acute Tox. 3: H331;
Acute Tox. 3: H311; Acute Tox. 3:
H301; STOT RE 2: H373; Skin Corr.
1B: H314
1-10%
N-OCTYLAMIN
- - Xn: R20/21/22; C: R35 Acute Tox. 4: H302+312+332; Skin
Corr. 1A: H314
1-10%
4: First aid measures
4.1. Description of first aid measures
Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin.
Drench the affected skin with running water for 10 minutes or longer if substance is still
on skin. Transfer to hospital if there are burns or symptoms of poisoning.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist
examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10
minutes. If unconscious, check for breathing and apply artificial respiration if necessary.
If unconscious and breathing is OK, place in the recovery position. Transfer to hospital
as soon as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If
unconscious and breathing is OK, place in the recovery position. If conscious, ensure
the casualty sits or lies down. If breathing becomes bubbly, have the casualty sit and
provide oxygen if available. Transfer to hospital as soon as possible.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be
bleeding from the mouth or nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may
cause coughing or wheezing.
4.3. Indication of any immediate medical attention and special treatment needed
5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: Corrosive. In combustion emits toxic fumes.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact
with skin and eyes.
6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions: Notify the police and fire brigade immediately. If outside keep bystanders upwind and
away from danger point. Mark out the contaminated area with signs and prevent access
to unauthorised personnel. Do not attempt to take action without suitable protective
clothing - see section 8 of SDS. Turn leaking containers leak-side up to prevent the
escape of liquid.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific
substance. Absorb into dry earth or sand. Transfer to a closable, labelled salvage
container for disposal by an appropriate method.
6.4. Reference to other sections
7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions: Store in cool, well ventilated area. Keep container tightly closed.
Suitable packaging: Coated steel.
7.3. Specific end use(s)
8: Exposure controls/personal protection
8.1. Control parameters
Hazardous ingredients:
PHENOL
Workplace exposure limits: Respirable dust
State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL
UK 2 ppm - - -
8.2. Exposure controls
Engineering measures: Ensure there is sufficient ventilation of the area.
Respiratory protection: Self-contained breathing apparatus must be available in case of emergency.
Hand protection: Impermeable gloves. Gloves (solvent-resistant).
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
Skin protection: Impermeable protective clothing.
9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Liquid
Odour: Aromatic
Solubility in water: Not miscible
Also soluble in: Most organic solvents.
Viscosity: Viscous
Boiling point/range°C: n.V. Melting point/range°C: n.V.
Flammability limits %: lower: n.V. upper: n.V.
Flash point°C: > 100 Part.coeff. n-octanol/water: n.V.
Autoflammability°C: n.a. Vapour pressure: n.V.
Relative density: 1,78 g/cm3 VOC g/l: Entfällt
9.2. Other information
Other information: Not applicable.
10: Stability and reactivity
10.1. Reactivity
10.2. Chemical stability
Chemical stability: Stable under normal conditions.
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
Conditions to avoid: Heat.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents. Strong acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.
11: Toxicological information
11.1. Information on toxicological effects
Toxicity values: Not applicable.
Symptoms / routes of exposure
Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be
bleeding from the mouth or nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may
cause coughing or wheezing.
12: Ecological information
12.1. Toxicity
Ecotoxicity values: Not applicable.
12.2. Persistence and degradability
Persistence and degradability: Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: No bioaccumulation potential.
12.4. Mobility in soil
Mobility: Readily absorbed into soil.
12.5. Results of PBT and vPvB assessment
PBT identification: This substance is not identified as a PBT substance.
12.6. Other adverse effects
Other adverse effects: Negligible ecotoxicity.
13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal
company.
Waste code number: 08 05 01
Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes.
NB: The user's attention is drawn to the possible existence of regional or national
regulations regarding disposal.
14: Transport information
14.1. UN number
UN number: UN1759
14.2. UN proper shipping name
Shipping name: CORROSIVE SOLID, (M-XYLYLENDIAMIN)
14.3. Transport hazard class(es)
Transport class: 8
14.4. Packing group
Packing group: II
14.5. Environmental hazards
Environmentally hazardous: No Marine pollutant: No
14.6. Special precautions for user
Tunnel code: E
Transport category: 2
15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.2. Chemical Safety Assessment
Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.
Phrases used in s.2 and 3: H301: Toxic if swallowed.
H302: Harmful if swallowed.
H302+312+332: Harmful if swallowed, in contact with skin or if inhaled.
H302+332: Harmful if swallowed or if inhaled.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H318: Causes serious eye damage.
H319: Causes serious eye irritation.
H331: Toxic if inhaled.
H332: Harmful if inhaled.
H341: Suspected of causing genetic defects <state route of exposure if it is conclusively
proven that no other routes of exposure cause the hazard>.
H373: May cause damage to organs <or state all organs affected, if known> through
prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H412: Harmful to aquatic life with long lasting effects.
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
R20/22: Harmful by inhalation and if swallowed.
R21/22: Harmful in contact with skin and if swallowed.
R22: Harmful if swallowed.
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
R34: Causes burns.
R35: Causes severe burns.
R36/38: Irritating to eyes and skin.
R43: May cause sensitisation by skin contact.
R48/20/21/22: Harmful: danger of serious damage to health by prolonged exposure
through inhalation, in contact with skin and if swallowed.
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R68: Possible risk of irreversible effects.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from
handling or from contact with the above product.
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