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1. DESIGNATION OF PRODUCT AND COMPANY
Trade name C-Systems 10 10 UV PROTECTION component A
Chemical description: Epoxy resin based compound.
Supplier: Cecchi Gustavo & C., Via Coppino 253, Viareggio 55049 (LU) –
tel 0039 0584/383694 fax 0039 0584/395182 www.cecchi.it - info@cecchi.it
2. Hazards identification
2.1 Classification of the substance or mixture
Classification (67/548/EEC, 1999/45/EC)
Sensitising R43: May cause sensitization by skin contact.
Irritant R36/38: Irritating to eyes and skin.
Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic
environment.
2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)
Labelling according to EC Directives (1999/45/EC)
Hazard pictograms:
Irritant
Dangerous for the environment
R-phrase(s) :
R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S-phrase(s):
S24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S37 Wear suitable gloves.
S57 Use appropriate container to avoid environmental contamination.
S60 This material and its container must be disposed of as hazardous waste.
Hazardous components which must be listed on the label:
• 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) and epoxy resin (number
average molecular weight <= 700)
• 2425-79-8 1,4-bis(2,3-epoxypropoxy)butane
• 28064-14-4 Phenol, polymer with formaldehyde, oxiranylmethyl ether
• 68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl]derivs
3. Composition/information on ingredients
3.2 Mixtures
Chemical nature :
Hazardous components
>= 50 -<= 100 reaction product: bisphenol-A- (epichlorhydrin) and epoxy resin (number average molecular weight <= 700)
No. Index: 603-074-00-8, CAS: 25068-38-6, EC: 500-033-5
Xi,N; R36/38-43-51/53
3.3/2 Eye Irrit. 2 H319
3.2/2 Skin Irrit. 2 H315
3.4.2/1 Skin Sens. 1 H317
4.1/C2 Aquatic Chronic 2 H411
>= 12,5 - < 20 1,4-bis(2,3-epoxypropoxy)butane
No. Index: 603-072-00-7, CAS: 2425-79-8, EC: 219-371-7
Xn,Xi; R20/21-36/38-43
3.3/2 Eye Irrit. 2 H319
3.2/2 Skin Irrit. 2 H315
3.4.2/1 Skin Sens. 1 H317
3.1/4/Dermal Acute Tox. 4 H312
3.1/4/Inhal Acute Tox. 4 H332
>= 7 - < 10 Phenol, polymer with formaldehyde, oxiranylmethyl ether
28064-14-4
Xi; R36/38 R43 N; R51/53
Skin Irrit. 2; H315 Eye Irrit. 2; H319 Skin Sens. 1; H317 Aquatic Chronic 2; H411
>= 1 - < 3 oxirane, mono[(C12-14-alkyloxy)methyl]derivs
68609-97-2 271-846-8
Xi; R38 R43
Skin Irrit. 2; H315 Skin Sens. 1; H317
>= 0,25 - < 0,5 sebacato di metile e 1,2,2,6,6-pentametil-4-piperidile
82919-37-7 280-060-4
Xi; R43 N; R50/53
Skin Sens. 1; H317 Aquatic Acute 1; H400 Aquatic Chronic 1; H410
>= 0,25 - < 0,5 methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate
41556-26-7 255-437-1
Xi; R43 N; R50/53
Skin Sens. 1; H317 Aquatic Acute 1; H400 Aquatic Chronic 1; H410
For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.
4. First aid measures
4.1 Description of first aid measures
General advice : Do not leave the victim unattended.
If inhaled : If unconscious place in recovery position and seek medical advice.
If symptoms persist, call a physician.
In case of skin contact : Do not wash off with:
Cleansing agents, acidic.
Do NOT use solvents or thinners.
Before washing use a dry brush to remove dust from skin.
In case of eye contact : Remove contact lenses.
Protect unharmed eye.
If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
5. Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media: Foam
5.2 Special hazards arising from the substance or mixture
Specific hazards during firefighting
: Burning produces irritant fumes.
5.3 Advice for firefighters
Special protective equipment for firefighters
: Wear self contained breathing apparatus for fire fighting if necessary.
Further information : Standard procedure for chemical fires.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions : Refer to protective measures listed in sections 7 and 8.
Evacuate personnel to safe areas.
Use personal protective equipment.
6.2 Environmental precautions
Environmental precautions : If the product contaminates rivers and lakes or drains inform
respective authorities.
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up : Wipe up with absorbent material (e.g. cloth, fleece).
Keep in suitable, closed containers for disposal.
6.4 Reference to other sections
Only qualified personnel equipped with suitable protective equipment may intervene.
7. Handling and storage
7.1 Precautions for safe handling
Advice on safe handling : For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the application area.
Advice on protection against fire and explosion
: Normal measures for preventive fire protection.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
: Electrical installations / working materials must comply withthe technological safety standards.
Advice on common storage : No materials to be especially mentioned.
Other data : No decomposition if stored and applied as directed.
8. Exposure controls/personal protection
8.1 Control parameters
Contains no substances with occupational exposure limit values.
8.2 Exposure controls
Personal protective equipment
Respiratory protection : No personal respiratory protective equipment normally required.
Hand protection : Chemical resistant gloves made of butyl rubber or nitrile rubber category III according to EN 374.
Eye protection : Safety glasses
Skin and body protection : Protective suit
Hygiene measures : General industrial hygiene practice.
Protective measures : Wear full protective clothing and self-contained breathing apparatus.
Environmental exposure controls
General advice : If the product contaminates rivers and lakes or drains inform respective authorities.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance : liquid
Colour : light yellow
Odour : slight
Flash point : 150 °C
Bolling point: > 200 °C
Density : 1,15 g/cm3 at 25 °C
Viscosity, dynamic : 800 - 1.200 mPa.s at 25 °C
10. Stability and reactivity
10.1 Reactivity
10.2 Chemical stability
10.3 Possibility of hazardous reactions
Hazardous reactions : Stable under recommended storage conditions., No hazards to be specially mentioned.
10.4 Conditions to avoid
Conditions to avoid : no data available
10.5 Incompatible materials
Materials to avoid : Incompatible with oxidizing agents.
10.6 Hazardous decomposition products
Hazardous decomposition products
: This product may release the following:
Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke).
Stable under normal conditions.
11. Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Acute oral toxicity : no data available
Skin corrosion/irritation
Skin irritation : no data available
Serious eye damage/eye irritation
Eye irritation : no data available
Respiratory or skin sensitization
Sensitisation : no data available
Target Organ Systemic Toxicant - Repeated exposure
: no data available
Further information : no data available
12. Ecological information
12.1 Toxicity
Toxicity to fish : no data available
Toxicity to daphnia and other aquatic invertebrates : no data available
12.2 Persistence and degradability
Biodegradability : no data available
12.3 Bioaccumulative potential
Bioaccumulation : no data available
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
12.6 Other adverse effects
Additional ecological information : no data available
13. Disposal considerations
13.1 Waste treatment methods
Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal.
14. Transport information
Land transport
ADR / RID:
Class: 9
Packaging group: III
UN number: 3082
ADR/RID-Labels: 9
Description of the goods: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy resin)
Sea transport
IMDG:
Class: 9
Packaging group: III
UN number: 3082
Labels: 9
EmS: F-A S-F
Description of the goods: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy resin)
Marine Pollutant
Air transport
IATA-DGR :
Class: 9
Packaging group: III
UN/ID No.: UN 3082
Labels: 9
Description of the goods: Environmentally hazardous substance, liquid, n.o.s. (Epoxy resin)
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Major Accident Hazard Legislation
: 96/82/EC Update: 2003
Dangerous for the environment
9b
Quantity 1: 200 t
Quantity 2: 500 t
15.2 Chemical Safety Assessment
16. Other information
Full text of R-phrases referred to under sections 2 and 3
R20/21 Harmful by inhalation and in contact with skin.
R36/38 Irritating to eyes and skin.
R38 Irritating to skin.
R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51 Toxic to aquatic organisms.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R53 May cause long-term adverse effects in the aquatic environment.
Full text of H-Statements referred to under sections 2 and 3.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
The information contained herein is based on the present state of our knowledge and does
therefore not guarantee certain properties.
The information contained herein is based on what we believe to be reliable data, but it is presented without guarantee or warranty by our part and Cecchi Gustavo & C. disclaims any liability incurred from the use thereof.
Nothing contained herein is to be construed as recommendations for use in violation of any existing patent, foreign or domestic, or of applicable laws and regulations.
Apply to Cecchi Gustavo & C. for further information about the product and its use. It is recommended to pass on this MSDS to customers and handlers.
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