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1. DESIGNATION OF PRODUCT AND COMPANY
Trade name C-Systems 10 10 CFS component B
Chemical description: Cycloaliphatic amine based compound
Supplier: Cecchi Gustavo & C., Via Coppino 253, Viareggio 55049 (LU) –
tel 0039 0584/383694 fax 0039 0584/395182 www.cecchi.it - info@cecchi.it
2. Hazards identification
2.1 Classification of the substance or mixture
Classification (67/548/EEC, 1999/45/EC)
Corrosive R35: Causes severe burns.
Harmful R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
Toxic to Reproduction Category 3 R62: Possible risk of impaired fertility.
R63: Possible risk of harm to the unborn child.
Sensitising R43: May cause sensitization by skin contact.
Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)
Labelling according to EC Directives (1999/45/EC)
Hazard pictograms :
Corrosive
Dangerous for the environment
R-phrase(s) : R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R35 Causes severe burns.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R62 Possible risk of impaired fertility.
R63 Possible risk of harm to the unborn child.
S-phrase(s) : S26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S57 Use appropriate container to avoid environmental contamination.
S60 This material and its container must be disposed of as hazardous waste.
Hazardous components which must be listed on the label:
• 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
• 98-54-4 4-tert-butylphenol
• 161278-21-3 Formaldehyde, oligomeric reaction products with 1-chloro-2,3- epoxypropane and phenol, reaction products with 3-aminomethyl-3,5,5- trimethylcyclohexylamine
• 1477-55-0 m-phenylenebis(methylamine)
• 84852-15-3 4-nonylphenol, branched
• 80-05-7 4,4'-isopropylidenediphenol
• 140-31-8 2-piperazin-1-ylethylamine
3. Composition/information on ingredients
3.2 Mixtures
Chemical nature : Cycloaliphatic amine based mixture
Hazardous components
Chemical Name CAS-No.
EC-No.
Registration number
Classification (67/548/EEC)
Classification (REGULATION (EC) No 1272/2008)
Concentration [%]
- 3-aminomethyl-3,5,5- trimethylcyclohexylamine 2855-13-2 220-666-8 / C; R34 Xn; R21/22 R43
R52-R53 Acute Tox. 4; H312 Acute Tox. 4; H302 Skin Corr. 1B; H314 Skin Sens. 1; H317 Aquatic Chronic 3;
H412 >= 30 - < 50
- benzyl alcohol 100-51-6 Xn; R20/22 Acute Tox. 4; H332 >= 20 - < 25
- 4-tert-butylphenol 98-54-4 202-679-0 C; R35 N; R51/53 Xi; R43 Xn; R20/22 Xn; R62
Xn; R63 Acute Tox. 4; H302 Acute Tox. 4; H332 Skin Corr. 1A; H314 Skin Sens. 1; H317 Aquatic Chronic 2;
H411 >= 10 - < 12,5
- Formaldehyde, oligomeric reaction products with 1-chloro- 2,3-epoxypropane and phenol, reaction
products with 3- aminomethyl-3,5,5- trimethylcyclohexylamine 161278-21-3 Xn; R21/22 C; R34
R43 R52/53 Acute Tox. 4; H302 Acute Tox. 4; H312 Skin Corr. 1B; H314Skin Sens. 1; H317
Aquatic Chronic 3; H412 >= 7 - < 10
- mphenylenebis( methylamine) 1477-55-0 216-032-5 01- 2119480150- 50 C; R34 R52/53 Xn; R20/22
R43 Acute Tox. 4; H302 Acute Tox. 3; H331 Skin Corr. 1B; H314 Skin Sens. 1; H317
Aquatic Chronic 3; H412 >= 7 - < 10
- 4-nonylphenol, branched 84852-15-3 284-325-5 / Repr.Cat.3; R62- R63 C; R34 Xn; R22
N; R50-R53 Repr. 2; H361fd Acute Tox. 4; H302 Skin Corr. 1B; H314 Aquatic Acute 1; H400
Aquatic Chronic 1; H410 >= 5 - < 7
- 4,4'- isopropylidenediphenol 80-05-7 201-245-8 / Repr.Cat.3; R62 Xi; R37-R41 R43
R52 Repr. 2; H361f STOT SE 3; H335 Eye Dam. 1; H318 Skin Sens. 1; H317 >= 3 - < 5
- 2-piperazin-1- ylethylamine 140-31-8 205-411-0 C; R34 Xn; R21/22 R43
R52-R53 Acute Tox. 4; H312 Acute Tox. 4; H302 Skin Corr. 1B; H314 Skin Sens. 1; H317
Aquatic Chronic 3; H412 >= 1 - < 2,5
- nonylphenol 25154-52-3 246-672-0 / Repr.Cat.3; R62- R63 C; R34 Xn; R22 N; R50-R53
Repr. 2; H361 Acute Tox. 4; H302 Skin Corr. 1B; H314 Aquatic Acute 1;
H400 Aquatic Chronic 1; H410
For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.
4. First aid measures
4.1 Description of first aid measures
General advice : Do not leave the victim unattended.
If inhaled : If unconscious place in recovery position and seek medical advice.
If symptoms persist, call a physician.
In case of skin contact : Do not wash off with: Cleansing agents, acidic.
Before washing use a dry brush to remove dust from skin.
Cool melted product on skin with plenty of water. Do not remove solidified product.
In case of eye contact : Remove contact lenses.
Protect unharmed eye.
If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
5. Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media : Water
Dry powder
Carbon dioxide (CO2)
5.2 Special hazards arising from the substance or mixture
Specific hazards during Firefighting : Burning produces irritant fumes.
5.3 Advice for firefighters
Special protective equipment for firefighters : Wear self contained breathing apparatus for fire fighting if
necessary.
Further information : Standard procedure for chemical fires.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions : Evacuate personnel to safe areas.
Use personal protective equipment.
6.2 Environmental precautions
Environmental precautions : If the product contaminates rivers and lakes or drains inform
respective authorities.
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up : Wipe up with absorbent material (e.g. cloth, fleece).
Keep in suitable, closed containers for disposal.
6.4 Reference to other sections
Inform the responsible authorities in case of gas leakage, or of entry into waterways, soil or drains.
7. Handling and storage
7.1 Precautions for safe handling
Advice on safe handling : For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the application area.
Advice on protection against fire and explosion
: Normal measures for preventive fire protection.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
: Electrical installations / working materials must comply with the technological safety standards.
Advice on common storage : No materials to be especially mentioned.
Other data : No decomposition if stored and applied as directed.
8. Exposure controls/personal protection
8.1 Control parameters
Components CAS-No. Value Control
parameters Update Basis
4,4'- isopropyliden ediphenol 80-05-7 TWA 10 mg/m3 2009-12-19 2009/161/EU
Further information : Indicative
TWA 10 mg/m3 2011-12-01 GB EH40
Further information : 2: Where no specific short-term exposure limit is listed, a figure three times the long-term
exposure should be used
8.2 Exposure controls
Engineering measures
Recommended minimum velocity for exhaust ventilation
Personal protective equipment
Respiratory protection : No personal respiratory protective equipment normally
required.
Eye protection : Safety glasses
Skin and body protection : Protective suit
Hygiene measures : General industrial hygiene practice.
Environmental exposure controls
General advice : If the product contaminates rivers and lakes or drains inform respective authorities.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance : liquid
Colour : light yellow
Odour : ammoniacal
Flash point : 150 °C
Boiling point: > 200 °C
Density : 1,01 g/cm3 at 25 °C
Viscosity, dynamic : 450 - 650 mPa.s at 25 °C
10. Stability and reactivity
10.1 Reactivity
10.2 Chemical stability
10.3 Possibility of hazardous reactions
Hazardous reactions : Stable under recommended storage conditions., No hazards
to be specially mentioned.
10.4 Conditions to avoid
Conditions to avoid : no data available
10.5 Incompatible materials
Materials to avoid : Toxic gases may be released if in contact with the following:
Azo-compounds
Halogenated compounds
Ammonia
10.6 Hazardous decomposition products
Hazardous decomposition products
: Stable under normal conditions.
Carbon dioxide (CO2), carbon monoxide (CO), oxides of
nitrogen (NOx), dense black smoke.
11. Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Acute oral toxicity : no data available
Skin corrosion/irritation
Skin irritation : no data available
Serious eye damage/eye irritation
Eye irritation : no data available
Respiratory or skin sensitization
Sensitisation : no data available
Target Organ Systemic Toxicant - Repeated exposure
: no data available
Further information : no data available
12. Ecological information
12.1 Toxicity
Toxicity to fish :
no data available
Toxicity to daphnia and other : no data available
aquatic invertebrates
12.2 Persistence and degradability
Biodegradability : no data available
12.3 Bioaccumulative potential
Bioaccumulation : no data available
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
12.6 Other adverse effects
Additional ecological Information : no data available
13. Disposal considerations
13.1 Waste treatment methods
Contaminated packaging : Empty containers should be taken to an approved waste
handling site for recycling or disposal.
14. Transport information
Land transport
ADR / RID:
Class: 8
Packaging group: III
UN number: 2735
ADR/RID-Labels: 8
Description of the goods: AMINES, LIQUID, CORROSIVE, N.O.S. (Isophorone diamine)
ENVIRONMENTALLY HAZARDOUS
Sea transport
IMDG:
Class: 8
Packaging group: III
UN number: 2735
Labels: 8
EmS: F-A S-B
Description of the goods: AMINES, LIQUID, CORROSIVE, N.O.S. (Isophorone diamine)
Marine Pollutant
Air transport
IATA-DGR :
Class: 8
Packaging group: III
UN/ID No.: UN 2735
Labels: 8
Description of the goods: Amines, liquid, corrosive, n.o.s. (Isophorone diamine)
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Major Accident Hazard
Legislation : 96/82/EC Update: 2003
Dangerous for the environment
9b
Quantity 1: 200 t
Quantity 2: 500 t
15.2 Chemical Safety Assessment
16. Other information
Full text of R-phrases referred to under sections 2 and 3
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R20/22 Harmful by inhalation and if swallowed.
R21/22 Harmful in contact with skin and if swallowed.
R22 Harmful if swallowed.
R34 Causes burns.
R35 Causes severe burns.
R37 Irritating to respiratory system.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R50 Very toxic to aquatic organisms.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R52 Harmful to aquatic organisms.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R53 May cause long-term adverse effects in the aquatic environment.
R62 Possible risk of impaired fertility.
R63 Possible risk of harm to the unborn child.
Full text of H-Statements referred to under sections 2 and 3.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H361 Suspected of damaging fertility or the unborn child.
H361f Suspected of damaging fertility.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
The information contained herein is based on what we believe to be reliable data, but it is presented without guarantee or warranty by our part and Cecchi Gustavo & C. disclaims any liability incurred from the use thereof. Nothing contained herein is to be construed as recommendations for use in violation of any existing patent, foreign or domestic, or of applicable laws and regulations.
Apply to Cecchi Gustavo & C. for further information about the product and its use.
It is recommended to pass on this MSDS to customers and handlers.
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