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1. DESIGNATION OF PRODUCT AND COMPANY
Trade name C-Systems 10 10 CFS component B
Chemical description: Cycloaliphatic amine based compound
Supplier: Cecchi Gustavo & C., Via Coppino 253, Viareggio 55049 (LU) –
tel 0039 0584/383694 fax 0039 0584/395182 www.cecchi.it - info@cecchi.it
2. HAZARDS IDENTIFICATION
The product is harmful following acute exposure to it and poses a serious health threat if ingested or
brought into contact with the skin.
The product is corrosive. If brought into contact with the skin causes burning and in case of contact
with eyes may cause damages to the eyelids and to the cornea.
If brought into contact with the skin, the product may cause sensitisation of the skin.
This product is a threat to the environment; it is harmful to aquatic organisms following acute exposure.
In the long term this product may have negative effects on the aquatic environment, because it is
not easily biodegradable and/or bioaccumulable.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components under the EEC directive 67/548 or components for which European
Community exposure values exists:
30% - 50% 3-aminomethyl-3,5,5-trimethylcyclohexylamine
N.67/548/EEC: 612-067-00-9 CAS: 2855-13-2 EC: 220-666-8
Xn,Xi,C; R21/22-34-43-52-53
20% - 30% benzyl alcohol
N.67/548/EEC: 603-057-00-5 CAS: 100-51-6 EC: 202-859-9
Xn; R20/22
< 5% M-fenilenebis(metilammina)
CAS: 1477-55-0 EC: 216-032-5
Xn,Xi,C; R20/22-35-43-52-53
< 5% 4,4'-isopropylidenediphenol
N.67/548/EEC: 604-030-00-0 CAS: 80-05-7 EC: 201-245-8
Repr. Cat. 3,Xi; R37-41-43-62
< 5% 2-piperazin-1-ylethylamine
N.67/548/EEC: 612-105-00-4 CAS: 140-31-8 EC: 205-411-0
Xn,Xi,C; R21/22-34-43-52-53
4. FIRST-AID MEASURES
Contact with skin:
Immediately take off all contaminated clothing.
Remove the product with a cloth or absorbent paper. Do not use solvents.
Wash with plenty of water and soap.
Seek medical advice.
Contact with eyes:
Wash immediately and thoroughly with running water, keeping eyelids raised, for at least 10
minutes. Following this, protect the eyes with sterile gauze or a clean, dry, handkerchief. Seek
medical advise.
Do not use eyewash or ointment of any kind before obtaining an examination or advice from
an ophthalmologist.
Swallowing:
Do not under any circumstance induce vomiting. Seek medical advice immediately.
Inhalation:
Ventilate the premises. The patient is to be removed immediately from the premises
contaminated and made to rest in a well ventilated area. Should the patient feel unwell,
consult a physician.
5. FIRE FIGHTING MEASURES
Recommended extinguishers:
CO2, Foam, Chemical powders or sand. Use water based extinguishing media with caution.
Extinguishers not to be used:
None in particular.
Risks arising from combustion:
Avoid inhaling the fumes. Incomplete combustion releases toxic gases.
Protective equipment:
Use protection for the airways.
6. MEASURES IN CASE OF ACCIDENTAL RELEASE
Measures for personal safety:
Use a mask, gloves and protective clothing.
Environmental measures:
Limit leakages with earth or sand.
If the product has flown off into a water course, into the drainage system, or has contaminated
the ground or vegetation, notify the responsible authorities.
Cleaning methods:
Rapidly collect the product. To do so, wear a mask and protective clothing.
If the product is in a liquid form, stop it from entering the drainage system.
Recover the product for re-use if possible, or for elimination in compliance with waste disposal
regulations in force. The product might, where appropriate, be absorbed by inert material.
After the product has been removed, rinse the involved area and materials with water that
must be disposed in compliance with regulations in force.
7. HANDLING AND STORAGE
Handling precautions:
Avoid contact with and inhalation of vapours and/or dusts. See also paragraph 8 below.
Do not eat or drink or smoke while working. Wash hands before breaks and at the end of
work. Mantain a sufficient personal care.
Incompatible materials:
The product reacts with acids, isocyanates, oxidants and epoxy, chlorinated and carbonylic
compounds
Storage conditions:
The product is moisture sensitive. Keep in a dry place in the original containers tightly closed.
Instructions regarding storage facilities:
Avoid exposition to low temperature (T > 15°C).
8. EXPOSURE CONTROL/PERSONAL PROTECTION
Precautionary measures:
Provide adequate ventilation to the areas where the product is stored and/or handled.
Respiratory protection:
Required where ventilation/aspiration is insufficient or exposure is prolonged, or for
applications in which the product is sprayed or heated.
Required in case of machining or applications that release dusts.
Protection for hands:
Use protective gloves.
For an extended exposure of the product, wear nitrile/neoprene gloves.
Eye protection:
Required in case of machining or applications that release dusts.
Safety goggles.
Protection for skin:
Use clothing that provides complete protection to the skin.
Available Exposure Limits (ACGIH) for substances of section 2:
None
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and colour: Pale yellow liquid
Odour: Amoniacal
pH: n.d.
Melting point: N.A.
Boiling point: 200 °C
Flash point: 150 °C (DIN 51758)
Explosive properties: N.A.
Combustion-related properties: N.A.
Vapour pressure: N.A.
Specific gravity ASTM D 1475: 1,01 gr/ml (25°C)
Solubility in water: Soluble
Lipid solubility: N.A.
Partition coefficient (n-octanol/H20) : n.d.
Dynamic viscosity EN13702-2: 450 - 650 mPa.s (25°C)
Vapour density: N.A.
10. STABILITY AND REACTIVITY
Conditions to avoid:
Stable under normal conditions.
Substances to avoid:
None in particular.
Hazardous decomposition products:
None in particular.
It may generate toxic gases on contact with oxidising mineral acids, halogenated organic
substances, organic peroxides and hydroperoxides, and powerful oxidising agents.
Upon combustion CO, CO2, NH3, NOX and other nitrogen containing compounds are formed.
11. TOXICOLOGICAL INFORMATION
No toxicological data related to the preparation are available.
When available, the toxicological information relating to the main components are listed below.
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Acute toxicity LD50 (oral): > 1.000 mg/kg (rat)
Sensibilisation (Magnusson-Kligman test), test-animal strongly sensibilising.
benzyl alcohol
LD50 (oral): > 1.000 mg/kg (rat)
LD50 (dermal): 2.000 mg/kg (rabbit)
LC50 (inhalation): 2000 ppm (4 h, rat)
High vapours concentrations may cause irritation to eyes and to the respiratory system and
induce narcosis.
Epoxy resin. Reaction productfrom Bisphenol F-Epichlorohydrin.
LD50 (oral): > 2.000 mg/kg (rat)
LD50 (dermal): > 2.000 mg/kg (rabbit)
2-piperazin-1-ylethylamine
LD50 (oral): > 2.000 mg/kg (rat)
LC50 (dermal): > 800 mg/kg (rabbit)
Not mutagen
12. ECOLOGICAL INFORMATION
Adopt sound working practices, so that the product is not released into the environment.
When available, the toxicological information relating to the main components are listed below.
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Not expected to be readily biodegradable.
42% ( Coupled Units Test)
8% (Metodo Ce79/831)
Acute toxicity
Fishes LC50: 110mg/l /96h
Daphnia Magna EC50: 44mg/l 24h
Scenedesmus subspicatus EC50>50mg/l /72h
Pseudomonas putida EC10 1,120 mg/l /18 h
benzyl alcohol
Expected to be readily biodegradable.
Acute toxicity TLm/48h/Daphnia: 360 ppm
Epoxy resin. Reaction productfrom Bisphenol F-Epichlorohydrin.
Sinks in water. Expected to be not readily biodegradable. Has the potential to bioaccumulate.
If product enters soil, it will be mobile and may contaminate groundwater.
Acute toxicity LC/EC/IC 50 = 1-10 mg/l
2-piperazin-1-ylethylamine
Akute Toxicity
LC50-96h (Poecilia reticulata) > 1800mg/l
EC50-48h (Daphnia magna): 58 mg/l
IC50-72h (Selenastrum capricornutum): 494 mg/l
EC50 (Pseudomonas putida) >1000 mg/l
Not easily biodegradable
13. DISPOSAL CONSIDERATIONS
Recover, if possible. Send to authorised disposal plants or for incineration under controlled
conditions. In so doing, comply with the local and national regulations currently in force.
14. TRANSPORT INFORMATION
UN number: 2735
Proper shipping name: POLIAMMINE CORROSIVE, LIQUIDE, NAS (Isophoronediamine) /
POLYAMINES, CORROSIVE, LIQUID, NOS (Isophoronediamine)
Road/Rail (ADR/RID): 8 III
Sea (IMDG): 8 III
Sea (EmS): F-A, S-B
Air (ICAO/IATA): 8 III
15. REGULATORY INFORMATION
Council Directive 67/548/EEC (Classification, packaging and labelling of dangerous substances)
and subsequent amendments. Commmission Directive 1999/45/EC (Classification, packaging and
labelling of dangerous preparation) and subsequent amendments. Commission Directive 98/24/EC
(Protection of the health and safety of workers from the risk related to chemical agent). Commission
Directive 2000/39/EC (Occupational exposure limit values). Regulation (EC) No 1907/2006
(REACH).
Symbols:
C Corrosive
R Phrases:
R21/22 Harmful in contact with skin and if swallowed.
R34 Causes burns.
R43 May cause sensitization by skin contact.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrases:
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S28 After contact with skin, wash immediately with plenty of soaped water.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
Contents: 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Where applicable, refer to the following regulatory provisions :
Directive 98/24/CE
Directive 91/156/EC; 91/689/EC; 94/62/EC (waste disposal).
Activities linked to risks of serious accidents
16. OTHER INFORMATION
R20/22 Harmful by inhalation and if swallowed.
R21/22 Harmful in contact with skin and if swallowed.
R34 Causes burns.
R35 Causes severe burns.
R36/38 Irritating to eyes and skin.
R37 Irritating to respiratory system.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R62 Possible risk of impaired fertility.
Main bibliographic sources:
NIOSH - Registry of toxic effects of chemical substances
I.N.R.S. - Fiche Toxicologique
ACGIH - Threshold Limit Values
The information contained herein is based on our state of knowledge at the above-specified date. It
refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to
the specific intended use.
This MSDS cancels and replaces any previous release.
The information contained herein is based on what we believe to be reliable data, but it is presented without guarantee or warranty by our part and Cecchi Gustavo & C. disclaims any liability incurred from the use thereof. Nothing contained herein is to be construed as recommendations for use in violation of any existing patent, foreign or domestic, or of applicable laws and regulations.
Apply to Cecchi Gustavo & C. for further information about the product and its use.
It is recommended to pass on this MSDS to customers and handlers.
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