SAFETY DATA SHEET
 

 

 

 

C-Systems 10 10 CFS COMPONENT B Rev. 3 - april 2011 - n° batch 161-AA
 

1. DESIGNATION OF PRODUCT AND COMPANY
Trade name                    C-Systems 10 10 CFS component B
Chemical description:  Cycloaliphatic amine based compound
Supplier:                          Cecchi Gustavo & C., Via Coppino 253, Viareggio 55049 (LU) –
                                     tel 0039 0584/383694 fax 0039 0584/395182 www.cecchi.it - info@cecchi.it

2. HAZARDS IDENTIFICATION
The product is harmful following acute exposure to it and poses a serious health threat if ingested.
The product is corrosive. If brought into contact with the skin causes burning and in case of contact
with eyes may cause damages to the eyelids and to the cornea.
If brought into contact with the skin, the product may cause sensitisation of the skin.
This product is a threat to the environment; it is toxic for aquatic organisms following acute
exposure.
In the long term this product may have negative effects on the aquatic environment, because it is
not easily biodegradable and/or bioaccumulable.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components under the EEC directive 67/548 or components for which European
Community exposure values exists:
20% - 50% benzyl alcohol
N.67/548/EEC: 603-057-00-5   CAS: 100-51-6   EC: 202-859-9   
Xn; R20/22

20% - 30% Polyoxypropylendiamin
CAS: 9046-10-0   
C; R34

10% - 30% 3-aminomethyl-3,5,5-trimethylcyclohexylamine
N.67/548/EEC: 612-067-00-9   CAS: 2855-13-2   EC: 220-666-8   
Xn,Xi,C; R21/22-34-43-52-53

10% - 30% 3,6,9,12-tetra-azatetradecamethylenediamine
N.67/548/EEC: 612-064-00-2   CAS: 4067-16-7   EC: 223-775-9   
Xi,C,N; R34-43-50-53

< 5% 4,4'-isopropylidenediphenol
N.67/548/EEC: 604-030-00-0   CAS: 80-05-7   EC: 201-245-8   
Repr. Cat. 3,Xi; R37-41-43-62

< 5%  M-fenilenebis(metilammina)
CAS: 1477-55-0   EC: 216-032-5   
Xn,Xi,C; R20/22-35-43-52-53

< 5% 2-piperazin-1-ylethylamine
N.67/548/EEC: 612-105-00-4   CAS: 140-31-8   EC: 205-411-0   
Xn,Xi,C; R21/22-34-43-52-53

4. FIRST-AID MEASURES
Contact with skin:
Immediately take off all contaminated clothing.
Remove the product with a cloth or absorbent paper. Do not use solvents.
Wash with plenty of water and soap.
Seek medical advice.
Contact with eyes:
Wash immediately and thoroughly with running water, keeping eyelids raised, for at least 10
minutes. Following this, protect the eyes with sterile gauze or a clean, dry, handkerchief. Seek
medical advise.
Do not use eyewash or ointment of any kind before obtaining an examination or advice from
an ophthalmologist.
Swallowing:
Do not under any circumstance induce vomiting. Seek medical advice immediately.
Inhalation:
Ventilate the premises. The patient is to be removed immediately from the premises
contaminated and made to rest in a well ventilated area. Should the patient feel unwell,
consult a physician.

5. FIRE FIGHTING MEASURES
Recommended extinguishers:
CO2, Foam, Chemical powders. Use carefully water based extinguishing media.
Extinguishers not to be used:
None in particular.
Risks arising from combustion:
Avoid inhaling the fumes. Incomplete combustion releases toxic gases.
Protective equipment:
Use protection for the airways.

6. MEASURES IN CASE OF ACCIDENTAL RELEASE
Measures for personal safety:
Use a mask, gloves and protective clothing.
Environmental measures:
Limit leakages with earth or sand.
If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities.
Cleaning methods:
Rapidly recover the product. To do so, wear a mask and protective clothing.
If the product is in a liquid form, stop it from entering the drainage system.
Recover the product for re-use if possible, or for elimination in compliance with waste disposal regulations in force. The product might, where appropriate, be absorbed by inert material.
After the product has been recovered, rinse the involved area and materials with water that must be disposed in compliance with regulations in force.

7. HANDLING AND STORAGE
Handling precautions:
Avoid contact and inhalation of vapours and/or dusts. See, too, paragraph 8 below.
Do not eat or drink or smoke while working. Wash hands before breaks and at the end of work. Provide a correct personal care.
Incompatible materials:
The product reacts with acids, isocyanates, oxidants and epoxy, chlorinated and carbonylic compounds
Storage conditions:
The product is moisture sensitive. Keep in a dry place in the original containers tightly closed.
Instructions as regards storage premises:
Avoid exposition to low temperature (T > 15°C).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Precautionary measures:
Provide adequate ventilation to the areas where the product is stored and/or handled.
Respiratory protection:
Required where ventilation/aspiration is insufficient or exposure is prolonged, or for
applications in which the product is sprayed or heated.
Required in case of machining or applications that release dusts.
Protection for hands:
Use protective gloves.
For an extended exposure of the product, wear nitrile/neoprene gloves.
Eye protection:
Required in case of machining or applications that release dusts.
Safety goggles.
Protection for skin:
Use clothing that provides complete protection to the skin.
Available Exposure Limits (ACGIH) for substances of section 2:
 None

 

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and colour:     Pale yellow liquid
Odour:                            Amoniacal
pH:                                 7 About
Melting point:                   N.A.
Boiling point:                    N.A.
Flash point:                     100 °C  (DIN 51758)
Explosive properties:        N.A.
Combustion-related properties:              N.A.
Vapour pressure:                                N.A.
Specific gravity ASTM D 1475:              1,01 gr/ml (25°C)
Solubility in water:                               Soluble
Lipid solubility:                                    N.A.
Partition coefficient (n-octanol/H20) :     N.A.
Dynamic viscosity EN13702-2:              350 - 550 mPa.s (25°C)
Vapour density:                                  N.A.

10. STABILITY AND REACTIVITY
Conditions to avoid:
Stable under normal conditions.
Substances to avoid:
None in particular.
Hazardous decomposition products:
None in particular.
It may generate toxic gases on contact with oxidising mineral acids, halogenated organic
substances, organic peroxides and hydroperoxides, and powerful oxidising agents.
Upon combustion CO, CO2, NH3, NOX and other nitrogen containing compounds are formed.

11. TOXICOLOGICAL INFORMATION
No toxicological data related to the preparation are available.
When available, the toxicological information relating to the main components are listed below.
benzyl alcohol
LD50 (oral): > 1.000 mg/kg (rat)
LD50 (dermal):  2.000 mg/kg (rabbit)
LC50 (inhalation):  2000 ppm (4 h, rat)
High vapours concentrations may cause irritation to eyes and to the respiratory system and
induce narcosis.
Polyoxypropylendiamin
Acute toxicity:
LD50 (oral): 2.880 mg/kg (rat)
LC50 (dermal):  2.980 mg/kg (rabbit)
Cronic toxicity:
Can cause dermatites. Lung damage may be caused by repeated and prolonged exposure to
the product. 
Sensitization: not sensitizing.
Irritating to skin (corrosive): Draize Method 6,40-8.00/8.0 (rabbit)
Irritating to eyes (irritant): Draize Method 80.00-110.00/110 (rabbit)
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Acute toxicity LD50 (oral): > 1.000 mg/kg (rat)
Sensibilisation (Magnusson-Kligman test), test-animal strongly sensibilising.
3,6,9,12-tetra-azatetradecamethylenediamine
LD50 (oral): > 1.500 mg/kg (rat)
Studies carried out by manufactures have observed that a particular ethyleneamine, DETA
(diethylenetriamine), has a very high acute toxicity by inhalation of aerosols. The NOEL (no
effect level) has been established at concentrations <0,07 mg/l (4 h). It can be assumed that
same effects are applicable to other ethyleneamines.
Even if the formation of aerosols is rare in industrial applications of ethyleneamines, it is
necessary to avoid inhalation by good ventilation and using masks to protect respiratory
system.
2-piperazin-1-ylethylamine
LD50 (oral): > 2.000 mg/kg (rat)
LC50 (dermal): > 800 mg/kg (rabbit)
Not mutagen

12. ECOLOGICAL INFORMATION
Adopt sound working practices, so that the product is not released into the environment.
When available, the toxicological information relating to the main components are listed below.
benzyl alcohol
Expected to be readily biodegradable.
Acute toxicity TLm/48h/Daphnia: 360 ppm
Polyoxypropylendiamin
Leuciscus idus/CL50 (96h) > 220 mg/l
Not readily bidegradable.
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Not expected to be readily biodegradable.
42% ( Coupled Units Test)
8% (Metodo Ce79/831)
  Acute toxicity 
Fishes LC50: 110mg/l /96h 
Daphnia Magna EC50: 44mg/l 24h
Scenedesmus subspicatus EC50>50mg/l /72h
Pseudomonas putida EC10 1,120 mg/l /18 h
3,6,9,12-tetra-azatetradecamethylenediamine
Not readily biodegradable.
Acute toxicity LC/EC/IC 50 = 1-200 mg/l
2-piperazin-1-ylethylamine
Akute Toxicity
LC50-96h (Poecilia reticulata) > 1800mg/l
EC50-48h (Daphnia magna): 58 mg/l
IC50-72h (Selenastrum capricornutum): 494 mg/l
EC50 (Pseudomonas putida) >1000 mg/l
Not easily biodegradable

 

13. DISPOSAL CONSIDERATIONS
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and national regulations currently in force.

14. TRANSPORT INFORMATION
UN number:                     2735
Proper shipping name:       POLIAMMINE CORROSIVE, LIQUIDE, NAS (Isophoronediamine) /
                                     POLYAMINES, CORROSIVE, LIQUID, NOS (Isophoronediamine)
Road/Rail (ADR/RID):        8 III
Sea (IMDG):                    8-III
Sea (EmS):                      F-A, S-B
Air (ICAO/IATA):               8-III

15. REGULATORY INFORMATION
Council Directive 67/548/EEC (Classification, packaging and labelling of dangerous substances)
and subsequent amendments. Commmission Directive 1999/45/EC (Classification, packaging and
labelling of dangerous preparation) and subsequent amendments. Commission Directive 98/24/EC
(Protection of the health and safety of workers from the risk related to chemical agent). Commission
Directive 2000/39/EC (Occupational exposure limit values). Regulation (EC) No 1907/2006 (REACH).

Symbols:
C Corrosive
N Dangerous for the environment
R Phrases:
R22 Harmful if swallowed.
R34 Causes burns.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
S Phrases:
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S28 After contact with skin, wash immediately with plenty of soaped water.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.
Contents:
 3,6,9,12-tetraazatetradecano-1,14-diamine

Where applicable, refer to the following regulatory provisions :
Directive 98/24/CE
Directive 91/156/EC; 91/689/EC; 94/62/EC (waste disposal).
Activities linked to risks of serious accidents

16. OTHER INFORMATION
R20/22 Harmful by inhalation and if swallowed.
R21/22 Harmful in contact with skin and if swallowed.
R34 Causes burns.
R35 Causes severe burns.
R37 Irritating to respiratory system.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R62 Possible risk of impaired fertility.

 Main bibliographic sources:
NIOSH - Registry of toxic effects of chemical substances
I.N.R.S. - Fiche Toxicologique
ACGIH - Threshold Limit Values

 

This MSDS cancels and replaces any previous release.
The information contained herein is based on what we believe to be reliable data, but it is presented without guarantee or warranty by our part and Cecchi Gustavo & C. disclaims any liability incurred from the use thereof.
Nothing contained herein is to be construed as recommendations for use in violation of any existing patent, foreign or domestic, or of applicable laws and regulations.
Apply to Cecchi Gustavo & C. for further information about the product and its use.
It is recommended to pass on this MSDS to customers and handlers.