SAFETY DATA SHEET
 

 

 

 

COLLA ROSSA - resin Rev. 2/14 april 2014 - n° batch 98-AD
 

1. DESIGNATION OF PRODUCT AND COMPANY
Trade name                   C-Systems Colla Rossa glue
Chemical description:     Glue for wood-containing resorcinol
Supplier:                        Cecchi Gustavo & C., Via Coppino 253, Viareggio 55049 (LU) – ITALY
                                     tel 0039 0584/383694 fax 0039 0584/395182 www.cecchi.it - info@cecchi.it

SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
Properties / Symbols:
Mutagenic category 3
T Toxic
Xn Harmful
C Corrosive
R Phrases:
R10 Flammable.
R23/24/25 Toxic by inhalation,in contact with skin and if swallowed.
R34 Causes burns.
R48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation, in
contact with skin and if swallowed.
R68 Possible risk of irreversible effects.
Adverse physicochemical, human health and environmental effects:
No other hazards
2.2. Label elements
Symbols:
T Toxic
R Phrases:
R10 Flammable.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R34 Causes burns.
R48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation, in
contact with skin and if swallowed.
R68 Possible risk of irreversible effects.
S Phrases:
S27/28 After contact with skin, take off immediately all contaminated clothing, and wash immediately with
plenty of ... (to be specified by the manufacturer).
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S43 In case of fire, use foam, CO2,powder halogenated. To cool the containers to use vapour water. Not to
use directed water jets on flames.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S63 In case of accident by inhalation: remove casualty to fresh air and keep at rest.
S7 Keep container tightly closed.
Contents:
phenol; carbolic acid; monohydroxybenzene; phenylalcohol resorcinol; 1,3-benzenediol
Special provisions according to Annex XVII of REACH and subsequent amendments:
None
2.3. Other hazards
vPvB Substances: None - PBT Substances: None
Other Hazards:
No other hazards

SECTION 3: Composition/information on ingredients
3.1. Substances
N.A.
3.2. Mixtures
Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and related
classification:

>= 20% - < 25% phenol; carbolic acid; monohydroxybenzene; phenylalcohol
REACH No.: 01-2119471329-32, Index number:: 604-001-00-2, CAS: 108-95-2, EC: 203-632-7
Muta. Cat. 3,T,Xn,C; R23/24/25-34-48/20/21/22-68
3.5/2 Muta. 2 H341
3.9/2 STOT RE 2 H373
3.2/1B Skin Corr. 1B H314
3.1/3/Oral Acute Tox. 3 H301
3.1/3/Dermal Acute Tox. 3 H311
3.1/3/Inhal Acute Tox. 3 H331

>= 10% - < 12.5% resorcinol; 1,3-benzenediol
REACH No.: 01-2119480136-40, Index number:: 604-010-00-1, CAS: 108-46-3, EC: 203-585-2
Xn,Xi,N; R22-36/38-50
3.1/4/Oral Acute Tox. 4 H302
3.2/2 Skin Irrit. 2 H315
3.3/1 Eye Dam. 1 H318
3.8/1 STOT SE 1 H370
3.8/2 STOT SE 2 H371
3.4.2/1-1A-1B Skin Sens. 1, 1A, 1B H317
4.1/A1 Aquatic Acute 1 H400

>= 7% - < 10% ethanol; ethyl alcohol
REACH No.: 01-2119457610-43, Index number:: 603-002-00-5, CAS: 64-17-5, EC: 200-578-6
F; R11; sostanza con un limite comunitario di esposizione sul posto di lavoro
2.6/2 Flam. Liq. 2 H225

>= 1% - < 3% methanol
REACH No.: 01-2119433307-44, Index number::: 603-001-00-X, CAS: 67-56-1, EC: 200-659-6
F,T; R11-23/24/25-39/23/24/25
2.6/2 Flam. Liq. 2 H225
3.1/3/Inhal Acute Tox. 3 H331
3.1/3/Dermal Acute Tox. 3 H311
3.1/3/Oral Acute Tox. 3 H301
3.8/1 STOT SE 1 H370

>= 0.1% - < 0.25% butanone; ethyl methyl ketone
REACH No.: 01-2119457290-43, Index number::: 606-002-00-3, CAS: 78-93-3, EC: 201-159-0
F,Xi; R11-36-66-67
2.6/2 Flam. Liq. 2 H225
3.3/2 Eye Irrit. 2 H319
3.8/3 STOT SE 3 H336

SECTION 4: First aid measures
4.1. Description of first aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
WARNING! This product is toxic through skin contact. OBTAIN IMMEDIATE MEDICAL ATTENTION.
Remove contaminated clothing immediately and dispose off safely.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult
an opthalmologist immediately.
Protect uninjured eye.
In case of Ingestion:
Do NOT induce vomiting.
Give nothing to eat or drink.
In case of Inhalation:
If breathing is irregular or stopped, administer artificial respiration.
In case of inhalation, consult a doctor immediately and show him packing or label.
4.2. Most important symptoms and effects, both acute and delayed
None
4.3. Indication of any immediate medical attention and special treatment needed
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data
sheet if possible).
Treatment:
None

SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media:
In case of fire, use foam, CO2,powder halogenated. To cool the containers to use vapour water. Not to use
directed water jets on flames.
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3. Advice for firefighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.

SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove all sources of ignition.
Wear breathing apparatus if exposed to vapours/dusts/aerosols.
Provide adequate ventilation.
Use appropriate respiratory protection.
See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3. Methods and material for containment and cleaning up
Wash with plenty of water.
6.4. Reference to other sections
See also section 8 and 13

SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Use localized ventilation system.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals in the
containers.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
Always keep the containers tightly closed.
Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to sunlight.
Keep away from food, drink and feed.
Incompatible materials:
See next section 10.
Instructions as regards storage premises:
Cool and adequately ventilated.
7.3. Specific end use(s)
None in particular

SECTION 8: Exposure controls/personal protection
8.1. Control parameters
phenol; carbolic acid; monohydroxybenzene; phenylalcohol - CAS: 108-95-2
TLV TWA - 19 Skin mg/m3, 5 ppm
ethanol; ethyl alcohol - CAS: 64-17-5
TLV TWA - 1880 mg/m3, 1000 ppm
methanol - CAS: 67-56-1
TLV TWA - 262 mg/m3, 200 ppm
TLV STEL - 328 skin mg/m3(1976)
butanone; ethyl methyl ketone - CAS: 78-93-3
TLV TWA - 590 mg/m3, 200 ppm
TLV STEL - 885 mg/m3, 300 ppm
DNEL Exposure Limit Values
N.A.
PNEC Exposure Limit Values
N.A.
8.2. Exposure controls
Eye protection:
Use close fitting safety goggles, don't use eye lens.
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Protection for hands: Chemical resistant gloves (EN 374) materials suitable to a short contact (splash protection): PVC / nitrile rubber - 0.7, mm (recommendation: at least protection index 3, corresponding to> 60 minutes permeation according to EN 374) materials suitable for continuous contact: PVC / nitrile rubber - 0.7, mm (recommendation: at least protection index 4, corresponding to> 120 minutes permeation time according to EN 374)
Because of the many types of gloves available on the market it is appropriate to comply with the instructions of the manufacturers.
The information contained herein is based on bibliographic data, the information of glove manufacturers, or is derived by analogy with similar substances. It should be borne in mind that, because of several factors (eg. Temperature), the useful life of a glove for protection against chemical agents can be significantly less than the permeation time detected by the tests.
If signs of wear and tear the gloves should be replaced.
Use protective gloves that provides comprehensive protection, approved according to the standard EN 374
(e.g. P.V.C., neoprene or rubber).
Respiratory protection:
In case of insufficient ventilation, wear an appropriate breathing apparatus. When workers are exposed to
concentrations above the exposure limit, they must wear a mask respirator appropriate and validated with filter (s)
Anti gases and vapors (combined filters in accordance with EN 14387: A2 filter - brown).
Use adequate protective respiratory equipment.
Thermal Hazards:
None
Environmental exposure controls:
None

SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance and colour: Liquid
Odour: characteristic
Odour threshold: N.A.
pH: 6 - 8.5
Melting point / freezing point: N.D. °C
Initial boiling point and boiling range: N.A.
Solid/gas flammability: N.D.
Upper/lower flammability or explosive limits: N.A.
Vapour density: N.D.
Flash point: 37 °C
Evaporation rate: N.A.
Vapour pressure: N.D. mbar ( 20°C)
Relative density: (25°C) = 1.15 kg/l
Solubility in water: Soluble
Solubility in oil: N.D.
Partition coefficient (n-octanol/water): 1.8 log Pow
Auto-ignition temperature: N.D. °C
Decomposition temperature: N.A.
Viscosity: (25°C) = 250 - 800 mPas
Explosive properties: N.D.
Oxidizing properties: N.D.
9.2. Other information
Miscibility: N.A.
Fat Solubility: N.A.
Conductivity: N.A.
Substance Groups relevant properties N.A.

SECTION 10: Stability and reactivity
10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
The product is stable under recommended storage and handling conditions (see section 7)
10.3. Possibility of hazardous reactions
Exothermic reactions in the presence of oxidizing agents.
10.4. Conditions to avoid
Stable under normal conditions.
Keep away from open flames, sparks and other sources of ignition.
10.5. Incompatible materials
Oxidizing agents.
Avoid contact with combustible materials. The product could catch fire.
10.6. Hazardous decomposition products
In normal conditions none. In case of combustion can give rise to the formation of oxides of carbon and
nitrogen.

SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicological information of the mixture:
N.A.
Toxicological information of the main substances found in the mixture:
methanol - CAS: 67-56-1
OBSERVATIONS ON HUMAN SUBJECTS:
Methanol poisoning as a result of ingestion produces three types of effect. The first to appear is a
narcotic effect, similar to that observed in ethanol poisoning. The next to appear is metabolic
acidosis, caused by an accumulation of formate which is produced more quickly than it is eliminated.
The third type of effect consists in disorders affecting vision and the nervous system.
In human subjects, exposure (of variable intensity and duration) to methanol vapours causes irritation
to all the mucous membranes, headache, buzzing in the ears, tiredness, insomnia, nystagmus,
tremors, dizziness, nausea, colic, dilated pupils, double vision, blindness, itching of the skin, eczema
and dermatitis.
Mutagenic category 3
If not differently specified, the information required in Regulation 453/2010/EC listed below must be considered as
N.A.:
a) acute toxicity;
b) skin corrosion/irritation;
c) serious eye damage/irritation;
d) respiratory or skin sensitisation;
e) germ cell mutagenicity;
f) carcinogenicity;
g) reproductive toxicity;
h) STOT-single exposure;
i) STOT-repeated exposure;
j) aspiration hazard.

SECTION 12: Ecological information
12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment.
phenol; carbolic acid; monohydroxybenzene; phenylalcohol - CAS: 108-95-2
a) Aquatic acute toxicity:
Endpoint: EC50 - Species: Daphnia = 3.1 mg/l - Duration h: 48
Endpoint: LC50 - Species: Fish = 8.9 mg/l - Duration h: 96
Endpoint: EC50 - Species: Algae = 61.1 mg/l - Duration h: 96
12.2. Persistence and degradability
None
N.A.
12.3. Bioaccumulative potential
N.A.
12.4. Mobility in soil
N.A.
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
None

SECTION 13: Disposal considerations
13.1. Waste treatment methods
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so
doing, comply with the local and national regulations currently in force.

SECTION 14: Transport information
14.1. UN number
ADR-UN Number: 2927
IATA-UN Number: 2927
IMDG-UN Number: 2927
14.2. UN proper shipping name
ADR-Shipping Name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. (phenol; carbolic acid;
monohydroxybenzene; phenylalcohol)
IATA-Shipping Name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. (phenol; carbolic acid;
monohydroxybenzene; phenylalcohol)
IMDG-Shipping Name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. (phenol; carbolic acid;
monohydroxybenzene; phenylalcohol)
14.3. Transport hazard class(es)
ADR-Class: 6.1
ADR - Hazard identification number: 68
IATA-Class: 6.1
IATA-Label: 6.1 + 8
IMDG-Class: 6.1
14.4. Packing group
ADR-Packing Group: II
IATA-Packing group: II
IMDG-Packing group: II
14.5. Environmental hazards
ADR-Enviromental Pollutant: No
IMDG-Marine pollutant: No
14.6. Special precautions for user
ADR-Subsidiary risks: 8
ADR-S.P.: 274
ADR-Tunnel Restriction Code: (D/E)
IATA-Passenger Aircraft: 653
IATA-Subsidiary risks: 8
IATA-Cargo Aircraft: 660
IATA-S.P.: A4 A137
IATA-ERG: 6C
IMDG-EmS: F-A , S-B
IMDG-Subsidiary risks: 8
IMDG-Storage category: Category B
IMDG-Storage notes: Clear of living quarters.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
No

SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances)
Dir. 99/45/EC (Classification, packaging and labelling of dangerous preparations)
Dir. 98/24/EC (Risks related to chemical agents at work)
Dir. 2000/39/EC (Occupational exposure limit values)
Dir. 2006/8/EC
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013
Regulation (EU) n. 453/2010 (Annex I)
Regulation (EU) n. 286/2011 (ATP 2 CLP)
Regulation (EU) n. 618/2012 (ATP 3 CLP)
Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006
(REACH) and subsequent modifications:
Restriction 3
Where applicable, refer to the following regulatory provisions :
Directive 82/501/EEC ('Activities linked to risks of serious accidents') and subsequent amendments.
Regulation (EC) nr 648/2004 (detergents).
1999/13/EC (VOC directive)
Volatile Organic compounds - VOCs = 29.20 %
Volatile Organic compounds - VOCs = 335.80 g/l
Volatile CMR substances = 0.00 %
Halogenated VOCs which are assigned the risk phrase R40 = 0.00 %
Organic Carbon - C = 19.91

SECTION 16: Other information
Text of phrases referred to under heading 3:
R11 Highly flammable.
R22 Harmful if swallowed.
R23/24/25 Toxic by inhalation,in contact with skin and if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R36/38 Irritating to eyes and skin.
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
R48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation, in
contact with skin and if swallowed.
R50 Very toxic to aquatic organisms.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
R68 Possible risk of irreversible effects.
H341 Suspected of causing genetic defects.
H373 May cause damage to organs through prolonged or repeated exposure.
H314 Causes severe skin burns and eye damage.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H331 Toxic if inhaled.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H370 Causes damage to organs.
H371 May cause damage to organs.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.

Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of
the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
CCNL - Appendix 1
Insert further consulted bibliography
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This MSDS cancels and replaces any preceding release.
ADR: European Agreement concerning the International Carriage of
Dangerous Goods by Road.
CAS: Chemical Abstracts Service (division of the American Chemical Society).
CLP: Classification, Labeling, Packaging.
DNEL: Derived No Effect Level.
EINECS: European Inventory of Existing Commercial Chemical Substances.
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of
Chemicals.
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport
Association" (IATA).
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization"
(ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
LTE: Long-term exposure.
PNEC: Predicted No Effect Concentration.
RID: Regulation Concerning the International Transport of Dangerous Goods
by Rail.
STE: Short-term exposure.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day.
(ACGIH Standard).
WGK: German Water Hazard Class.
25626/3