1. DESIGNATION OF PRODUCT AND COMPANY
Trade name C-Systems Colla Rossa hardner
Chemical description: Hardner of the adhesive for timber
Supplier: Cecchi Gustavo & C., Via Coppino 253, Viareggio 55049 (LU) – ITALY
tel 0039 0584/383694 fax 0039 0584/395182 www.cecchi.it - info@cecchi.it
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
Properties / Symbols:
Carcinogenic category 3
Xn Harmful
Xi Irritant
R Phrases:
R20/21/22 Harmful by inhalation,in contact with skin and if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R40 Limited evidence of a carcinogenic effect.
R43 May cause sensitization by skin contact.
Adverse physicochemical, human health and environmental effects:
No other hazards
2.2. Label elements
Symbols:
Xn Harmful
R Phrases:
R20/21/22 Harmful by inhalation,in contact with skin and if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R40 Limited evidence of a carcinogenic effect.
R43 May cause sensitization by skin contact.
S Phrases:
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37 Wear suitable protective clothing and gloves.
S7 Keep container tightly closed.
Contents:
paraformaldeide
Special provisions according to Annex XVII of REACH and subsequent amendments:
None
2.3. Other hazards
vPvB Substances: None - PBT Substances: None
Other Hazards:
No other hazards
SECTION 3: Composition/information on ingredients
3.1. Substances
N.A.
3.2. Mixtures
Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and related
classification:
>= 25% - < 30% paraformaldeide
CAS: 30525-89-4
Carc. Cat. 3,Xn,Xi; R40-20/21/22-36/37/38-43
3.1/4/Inhal Acute Tox. 4 H332
3.1/4/Dermal Acute Tox. 4 H312
3.1/4/Oral Acute Tox. 4 H302
3.3/2 Eye Irrit. 2 H319
3.8/3 STOT SE 3 H335
3.2/2 Skin Irrit. 2 H315
3.4.2/1-1A-1B Skin Sens. 1, 1A, 1B H317
3.6/2 Carc. 2 H351
>= 0.5% - < 1% methanol
REACH No.: 01-2119433307-44, Index number: 603-001-00-X, CAS: 67-56-1, EC: 200-659-6
F,T; R11-23/24/25-39/23/24/25
2.6/2 Flam. Liq. 2 H225
3.1/3/Inhal Acute Tox. 3 H331
3.1/3/Dermal Acute Tox. 3 H311
3.1/3/Oral Acute Tox. 3 H301
3.8/1 STOT SE 1 H370
SECTION 4: First aid measures
4.1. Description of first aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
Areas of the body that have - or are only even suspected of having - come into contact with the product must
be rinsed immediately with plenty of running water and possibly with soap.
Wash thoroughly the body (shower or bath).
Remove contaminated clothing immediately and dispose off safely.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult
an opthalmologist immediately.
Protect uninjured eye.
In case of Ingestion:
Give nothing to eat or drink.
Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY.
In case of Inhalation:
If breathing is irregular or stopped, administer artificial respiration.
In case of inhalation, consult a doctor immediately and show him packing or label.
4.2. Most important symptoms and effects, both acute and delayed
None
4.3. Indication of any immediate medical attention and special treatment needed
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data
sheet if possible).
Treatment:
None
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3. Advice for firefighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Wear breathing apparatus if exposed to vapours/dusts/aerosols.
Provide adequate ventilation.
Use appropriate respiratory protection.
See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3. Methods and material for containment and cleaning up
Wash with plenty of water.
6.4. Reference to other sections
See also section 8 and 13
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Use localized ventilation system.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals in the
containers.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
Always keep the containers tightly closed.
Keep away from food, drink and feed.
Instructions as regards storage premises:
Adequately ventilated premises.
7.3. Specific end use(s)
None in particular
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
methanol - CAS: 67-56-1
TLV TWA - 262 mg/m3, 200 ppm
TLV STEL - 328 skin mg/m3(1976)
DNEL Exposure Limit Values
N.A.
PNEC Exposure Limit Values
N.A.
8.2. Exposure controls
Eye protection:
Use close fitting safety goggles, don't use eye lens.
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Protection for hands:
Chemical resistant gloves (EN 374) Suitable materials: nitrile rubber - 0,4 mm thick (recommendation: at least protection index 6, corresponding to> 480 minutes permeation time according to EN 374)
Because of the many types of gloves available on the market it is appropriate to comply with the instructions of the manufacturers.
The information contained herein is based on bibliographic data, the information of glove manufacturers, or is derived by analogy with similar substances. It should be borne in mind that, because of several factors (eg. Temperature), the useful life of a glove for protection against chemical agents can be significantly less than the permeation time detected by the tests.
If signs of wear and tear the gloves should be replaced.
Use protective gloves that provides comprehensive protection, approved according to the standard EN 374
(e.g. P.V.C., neoprene or rubber).
Respiratory protection:
In case of dust formation Should workers wear appropriate respiratory protection mask and approved, with filter (s)
Anti gases and vapors (combined filters In accordance with EN 14387: A2 filter P3).
Use respiratory protection where ventilation is insufficient or exposure is prolonged.
Use adequate protective respiratory equipment.
Thermal Hazards:
None
Environmental exposure controls:
None
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance and colour: Solid
Odour: characteristic
Odour threshold: N.A.
pH: N.A.
Melting point / freezing point: N.D. °C
Initial boiling point and boiling range: N.D. °C
Solid/gas flammability: N.D.
Upper/lower flammability or explosive limits: N.A.
Vapour density: N.D.
Flash point: ~ 70 °C
Evaporation rate: N.A.
Vapour pressure: paraformaldeide = 1.5 - 2 mbar ( 20°C)
Relative density: N.D. kg/l
Solubility in water: Insoluble
Solubility in oil: N.D.
Partition coefficient (n-octanol/water): N.D.
Auto-ignition temperature: paraformaldeide = 370 °C
Decomposition temperature: N.A.
Viscosity: N.A.
Explosive properties: N.D.
Oxidizing properties: N.D.
9.2. Other information
Miscibility: N.A.
Fat Solubility: N.A.
Conductivity: N.A.
Substance Groups relevant properties N.A.
SECTION 10: Stability and reactivity
10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
Stable under normal conditions
10.3. Possibility of hazardous reactions
It may generate flammable gases on contact with dithiocarbamates, elementary metals (alkalis, alkaline
earth), and nitrides.
It may generate toxic gases on contact with dithiocarbamates.
It may catch fire on contact with oxidising mineral acids, elementary metals (alkalis and alkaline earth),
nitrides, powerful oxidising agents, and powerful reducing agents.
10.4. Conditions to avoid
Stable under normal conditions.
10.5. Incompatible materials
None in particular.
10.6. Hazardous decomposition products
None.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicological information of the mixture:
N.A.
Toxicological information of the main substances found in the mixture:
N.A.
Carcinogenic category 3
If not differently specified, the information required in Regulation 453/2010/EC listed below must be considered as
N.A.:
a) acute toxicity;
b) skin corrosion/irritation;
c) serious eye damage/irritation;
d) respiratory or skin sensitisation;
e) germ cell mutagenicity;
f) carcinogenicity;
g) reproductive toxicity;
h) STOT-single exposure;
i) STOT-repeated exposure;
j) aspiration hazard.
SECTION 12: Ecological information
12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment.
N.A.
12.2. Persistence and degradability
None
N.A.
12.3. Bioaccumulative potential
N.A.
12.4. Mobility in soil
N.A.
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
None
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so
doing, comply with the local and national regulations currently in force.
SECTION 14: Transport information
14.1. UN number
Not classified as dangerous in the meaning of transport regulations.
14.2. UN proper shipping name
N.A.
14.3. Transport hazard class(es)
N.A.
14.4. Packing group
N.A.
14.5. Environmental hazards
14.6. Special precautions for user
N.A.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
No
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances)
Dir. 99/45/EC (Classification, packaging and labelling of dangerous preparations)
Dir. 98/24/EC (Risks related to chemical agents at work)
Dir. 2000/39/EC (Occupational exposure limit values)
Dir. 2006/8/EC
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013
Regulation (EU) n. 453/2010 (Annex I)
Regulation (EU) n. 286/2011 (ATP 2 CLP)
Regulation (EU) n. 618/2012 (ATP 3 CLP)
Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006
(REACH) and subsequent modifications: None
Where applicable, refer to the following regulatory provisions :
Directive 82/501/EEC ('Activities linked to risks of serious accidents') and subsequent amendments.
Regulation (EC) nr 648/2004 (detergents).
1999/13/EC (VOC directive)
Volatile Organic compounds - VOCs = 0.87 %
Volatile CMR substances = 0.00 %
Halogenated VOCs which are assigned the risk phrase R40 = 0.00 %
Organic Carbon - C = 0.33
SECTION 16: Other information
Text of phrases referred to under heading 3:
R11 Highly flammable.
R20/21/22 Harmful by inhalation,in contact with skin and if swallowed.
R23/24/25 Toxic by inhalation,in contact with skin and if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
R40 Limited evidence of a carcinogenic effect.
R43 May cause sensitization by skin contact.
H332 Harmful if inhaled.
H312 Harmful in contact with skin.
H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H351 Suspected of causing cancer.
H225 Highly flammable liquid and vapour.
H331 Toxic if inhaled.
H311 Toxic in contact with skin.
H301 Toxic if swallowed.
H370 Causes damage to organs.
This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of
the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
CCNL - Appendix 1
Insert further consulted bibliography
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This MSDS cancels and replaces any preceding release.
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
CAS: Chemical Abstracts Service (division of the American Chemical Society).
CLP: Classification, Labeling, Packaging.
DNEL: Derived No Effect Level.
EINECS: European Inventory of Existing Commercial Chemical Substances.
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of Chemicals.
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
LTE: Long-term exposure.
PNEC: Predicted No Effect Concentration.
RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.
STE: Short-term exposure.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day.
(ACGIH Standard).
WGK: German Water Hazard Class.
|
