1. Identification of the substance/preparation and company.
Product Name: C-Systems Colla Bianca
Product Type Adhesive for wood and similar, in powder to melt in water
Supplier:       Cecchi Gustavo & C. srl
Emergency Phone Numbers:  +39 0584/383694

2 Hazards identification
2.1. Classification of the substance or mixture
Classification according to Directive 1999/45/EC [DPD]
The product is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Not classified
See section 16 for the full text of the R-phrases declared above
2.2. Label elements
Risk phrases : This product is not classified according to EU legislation.
Product use : Industrial applications
2.3. Other hazards
Based on the substance information, the mixture is not expected to meet the criteria for PBT/vPvB.
Handling and/or processing of this material may generate a dust which can cause mechanical
irritation of the eyes, skin, nose and throat. Fine dust clouds may form explosive mixtures with air.
- Kaolina 3,0 -5,0 %
Pericolo fisico: not classified
Pericolo salute: not classified
N° CAS/n° 1332-58-7   310-194-1

- Solfato di alluminio  1,0-2,0 %
Pericolo fisico: not classified
R-Phrases/Hazard statement Code(s) (Xi) R36.
N° CAS/n° 10043-01-3 

233-135-0
See Section 16 for the full text of the H statements and R phrases declared above.

4 First aid measures
4.1. Description of first aid measures
First aid measures
Inhalation : Move exposed person to fresh air. Keep person warm and
at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Get medical attention if symptoms occur. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Ingestion : Wash out mouth with water. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur.
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs.

4.2. Most important symptoms and effects, both acute and delayed
Over-exposure signs/symptoms
Inhalation : Adverse symptoms may include the following: respiratory tract irritation, coughing,
Ingestion : No specific data.
Skin : No specific data.
Eyes : Adverse symptoms may include the following: irritation, redness,
See section 11 for more detailed information on health effects and symptoms.
4.3. Indication of immediate medical attention and special treatment needed
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Protection of first aid Personnel : No action shall be taken involving any personal risk or without suitable training.

5 Fire-fighting measures
5.1. Extinguishing media
Suitable : Use water spray or mist, dry chemical, foam or CO2.
Not suitable : Do not use water jet.
5.2. Special hazards arising from the substance or mixture
Hazards from the substance or mixture : Combustible solid that burns. Fine dust clouds may form explosive mixtures with air.
Hazardous thermal
decomposition products : Decomposition products may include the following materials: carbon dioxide, carbon monoxide, nitrogen oxides,
5.3. Special protective actions for fire-fighters Special precautions for fire-fighters
: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Special protective equipment for fire-fighters : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Additional information : Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspended in air or some other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion (including secondary explosions). The ATEX Directive defines combustible powders as less than 500 microns in diameter. When processed with flammable liquids/vapors/mists, ignitable (hybrid) mixtures may be formed with combustible dusts. Ignitable mixtures will
increase the rate of explosion pressure rise and the MIE will be lower than the pure dust in air mixture. The Lower Explosive Limit (LEL) of the vapor/dust mixture will be lower than the individual LELs for the vapors/mists or dusts. See NFPA 77 for additional guidance.

6 Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
No action shall be taken involving any personal risk or without suitable training. Evacuate
surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or
walk through spilled material. Minimize airborne dust and eliminate all fire/ignition sources. Clean up
spill as soon as possible using procedures described below. Do not breathe dust. Provide adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal
protective equipment (see section 8).
6.2. Environmental precautions
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Inform the relevant authorities if the product has caused environmental pollution (sewers,
waterways, soil or air).
6.3. Methods and material for containment and cleaning up
Small spill : Move containers from spill area. Do not use air hoses for cleaning. Minimize dry sweeping to avoid generation of dust clouds. Vacuum dust-accumulating surfaces and
remove to a chemical disposal area. Use spark-proof tools and explosion-proof equipment. Vacuums with
explosion-proof motors should be used. Dispose of via a licensed waste disposal contractor.
Large spill : Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid creating dusty conditions and prevent wind dispersal. Do not use air hoses for cleaning. Minimize dry sweeping to avoid generation of dust clouds. Vacuum dust-accumulating surfaces and remove to a chemical disposal area. Use spark-proof tools and explosion-proof equipment.
Vacuums with explosion-proof motors should be used. Dispose of via a licensed waste disposal contractor. Note: see section 1 for emergency contact information and section 13 for waste disposal.

7 Handling and storage
7.1. Precautions for safe handling
Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking
should be prohibited in areas where this material is handled, stored and processed. Workers should
wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing.
Do not breathe dust. Do not ingest. Avoid the creation of dust when handling and avoid all possible
sources of ignition (spark or flame). Prevent dust accumulation. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not in use. Electrical
equipment and lighting should be protected to appropriate standards to prevent dust coming into
contact with hot surfaces, sparks or other ignition sources. Take precautionary measures against
electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by
grounding and bonding containers and equipment before transferring material. Empty containers
retain product residue and can be hazardous. Do not reuse container.

COMBUSTIBLE DUST HANDLING PROCEDURES:
Combustible dusts at sufficient concentrations can form explosive mixtures with air. High dust
concentrations should be avoided. Follow US NFPA Standard 654, "Standard for the Prevention of
Fire and Dust Explosions from the Manufacturing, Processing, and Handling of Combustible
Particulate Solids," UK HSE Guidance HSG 103, approved Codes of Practice (ACOPS) established
for Explosive Atmospheres under the ATEX Directive 1999/92/EC for worker protection and ATEX
Directive 94/9/EC that regulates equipment and protection systems used in potentially explosive
atmospheres or other national guidance on safe handling of combustible dusts. Train workers in the
recognition and prevention of hazards associated with combustible dust in the plant.
Minimize airborne dust and eliminate all ignition sources. Keep away from heat, hot surfaces,
sparks, and flame. Establish good housekeeping practices. Remove dust accumulations on a
regular basis by vacuuming or gentle sweeping to avoid creating dust clouds. Use continuous
suction at points of dust generation to capture and minimize the accumulation of dusts. Particular
attention should be given to overhead and hidden horizontal surfaces to minimize the probability of
a "secondary" explosion. According to NFPA Standard 654, dust layers 1/32 in.(0.8 mm) thick can
be sufficient to warrant immediate cleaning of the area.
Control sources of static electricity. This product or the package itself can accumulate static
charges, and static discharge can be a source of ignition. Solids handling systems must be
designed in accordance with applicable NFPA standards (including 654 and 77) and other national
guidance. Do not empty directly into flammable solvents or in the presence of flammable vapors.
The operator, the packaging container and all equipment must be grounded with electrical bonding
and grounding systems. Plastic bags and plastics cannot be grounded, and antistatic bags do not
completely protect against development of static charges.
7.2. Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Store in a segregated and approved area. Store in
original container protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate
from oxidizing materials. Keep away from heat, hot surfaces, sparks and flame. Keep container
tightly closed and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
Packaging materials
Recommended : Use original container.
Specific uses : Adhesive
7.3. Specific end use(s)
Not applicable.

8 Exposure controls/personal protection
8.1. Control parameters
Exposure limit values Ingredient name Occupational exposure limits
No exposure limit value known.

8.2. Exposure controls Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances.
Occupational exposure controls : Use only with adequate ventilation. If user operations
generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before
reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the
selected respirator.
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.
Eye protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If operating conditions cause high dust concentrations to be produced, use dust goggles.
Skin protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before
handling this product. For PPE selection see National Fire Protection Association (NFPA) 2113, Standard on
Selection, Care, Use and Maintenance of Flame-Resistant Garments for Protection of Industrial Personnel Against Flash Fire.
Environmental exposure controls : Emissions from ventilation or work process equipment
should be checked to ensure they comply with the requirements of environmental protection legislation.

9 Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state : Powder
Color : Off-white.
Odor : Not determined
Odor threshold : Not determined
pH : Not determined
Melting Point : Not determined
Initial boiling point and boiling range : Not determined
Flash point : Not determined
Evaporation rate : Not determined
Flammability : Combustible.
Explosion limits
Upper: : Not determined
Lower: : Not determined
Vapor pressure : Not determined
Vapor density : Not determined
Relative density : 0.7
Solubility : Partial
Partition coefficient:
n-octanol/water : Not determined
Auto-ignition temperature : Not determined
Decomposition temperature : Not determined
Explosive properties : Not determined
Oxidising properties : Not oxidising
9.2. Other information
Not applicable.

10 Stability and reactivity
10.1. Reactivity
Stable under normal conditions.
10.2. Chemical stability
The product is stable.
10.3. Possibility of hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
10.4. Conditions to avoid
Avoid the creation of dust when handling and avoid all possible sources of ignition (spark or flame).
Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate
static electricity during transfer by grounding and bonding containers and equipment before
transferring material. Prevent dust accumulation. See Section 7 Handling.
10.5. Incompatible materials
No specific data.
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be
produced. During mixing and use vapors of formaldehyde may be evolved.

11 Toxicological information
Summary of health effects based on the conventional method of Directive 1999/45/EC
None of the health effects meet the criteria for classification.
11.1. Information on toxicological effects
- Colla Bianca
Acute toxicity
Oral
No applicable toxicity data.
Dermal
No applicable toxicity data.
Inhalation
No applicable toxicity data.
Other routes
No applicable toxicity data.
Irritation/Corrosion
No applicable toxicity data.
Skin sensitization
No applicable toxicity data.
Respiratory sensitization
No applicable toxicity data.
Repeated Dose Toxicity
No applicable toxicity data.
Carcinogenicity
No applicable toxicity data.
Mutagenicity
No applicable toxicity data.
Toxic to Reproduction
No applicable toxicity data.

- Kaolin
Acute toxicity
Oral
No applicable toxicity data. No known significant effects or critical hazards.
Dermal
No applicable toxicity data. No known significant effects or critical hazards.
Inhalation
No applicable toxicity data. No known significant effects or critical hazards.
Other routes
No applicable toxicity data. No known significant effects or critical hazards.
Skin corrosion/irritation
No applicable toxicity data. No known significant effects or critical hazards.
Serious eye damage/irritation
No applicable toxicity data. No known significant effects or critical hazards.
Skin sensitization
No applicable toxicity data. No known significant effects or critical hazards.
Respiratory sensitization
No applicable toxicity data. No known significant effects or critical hazards.
Germ cell mutagenicity
No applicable toxicity data. No known significant effects or critical hazards.
Carcinogenicity
No applicable toxicity data. No known significant effects or critical hazards.
Reproductive toxicity
No applicable toxicity data. No known significant effects or critical hazards.
Developmental / Teratogenicity
No applicable toxicity data. No known significant effects or critical hazards.
STOT-single exposure
No applicable toxicity data. No known significant effects or critical hazards.
STOT-repeated exposure
No applicable toxicity data. No known significant effects or critical hazards.
Aspiration hazard
No applicable toxicity data. No known significant effects or critical hazards.
Other information
No applicable toxicity data. No known significant effects or critical hazards.

- aluminium sulphate
Acute toxicity
Oral
LD50: Mouse 6,207 mg/kg;
Dermal
No applicable toxicity data. No known significant effects or critical hazards.
Inhalation
No applicable toxicity data. No known significant effects or critical hazards.
Other routes
No applicable toxicity data. No known significant effects or critical hazards.
Skin corrosion/irritation
No applicable toxicity data. No known significant effects or critical hazards.
Serious eye damage/irritation
No applicable toxicity data. No known significant effects or critical hazards.
Skin sensitization
No applicable toxicity data. No known significant effects or critical hazards.
Respiratory sensitization
No applicable toxicity data. No known significant effects or critical hazards.
Germ cell mutagenicity
No applicable toxicity data. No known significant effects or critical hazards.
Carcinogenicity
No applicable toxicity data. No known significant effects or critical hazards.
Reproductive toxicity
No applicable toxicity data. No known significant effects or critical hazards.
Developmental / Teratogenicity
No applicable toxicity data. No known significant effects or critical hazards.
STOT-single exposure
No applicable toxicity data. No known significant effects or critical hazards.
STOT-repeated exposure
No applicable toxicity data. No known significant effects or critical hazards.
Aspiration hazard
No applicable toxicity data. No known significant effects or critical hazards.
Other information
No applicable toxicity data. No known significant effects or critical hazards.

12 Ecological information
Summary of environmental hazards based on the conventional method of Directive
1999/45/EC
None of environmental hazard criteria are met.
12.1. Toxicity
COLLA BIANCA
No applicable toxicity data.
Kaolin
No applicable toxicity data. No known significant effects or critical hazards.
aluminium sulphate
Fresh water LC50: 4.4 mg/l/96 h Fathead minnow
12.2. Persistence and degradability
COLLA BIANCA
No data available.
Kaolin
No data available.
aluminium sulphate
No data available.
12.3. Bioaccumulative potential
Not tested but expected to be minimal.
Kaolin
No data available.
aluminium sulphate
No data available.
12.4. Mobility in soil
COLLA BIANCA
Solid powder
Kaolin
No data available.
aluminium sulphate
No data available.
12.5. Results of PBT and vPvB assessment
COLLA BIANCA
Based on the substance information, the mixture is not expected to meet the criteria for
PBT/vPvB.
Kaolin
No data available.
aluminium sulphate
No data available.
12.6. Other adverse effects
COLLA BIANCA
Toxicity to bacteria, algae and higher marine organisms not tested. COD: Not determined.
Kaolin
No known adverse effects.
aluminium sulphate
No known adverse effects.

13  Disposal considerations
13.1. Waste treatment methods
Methods of disposal : The generation of waste should be avoided or minimized
wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Hazardous waste : Within the present knowledge of the supplier, this product is not regarded as hazardous waste, as defined by EU Directive 91/689/EEC.

14 Transport information
Regulatory information
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
14.4. Packing group
ADR Non-regulated
RID Non-regulated
ADN/ADNR Non-regulated
ICAO/IATA Non-regulated
IMO/IMDG Non-regulated
14.5. Environmental hazards
Environmentally hazardous and/or Marine Pollutant : No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.

15 Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
SEVESO Directive 96/82/EC : Ingredient name Listed
Kaolin No.
aluminium sulphate No.
REACH Annex XVII : Not listed
Biocides - Annex I to Directive 98/8/EC: Not listed
Prior Informed Consent. List of chemicals subject to the international PIC procedure (Part I, II, III)
: None required.
Integrated pollution prevention and control list (IPPC) – Air : Not listed
Integrated pollution prevention and control list (IPPC) – Water : Not listed
International regulations
Chemical inventories REACH Status The substance(s) in this product has (have) been
Pre-Registered and/or Registered, or are exempted from registration, according to Regulation (EC) No. 1907/2006 (REACH). Australia inventory (AICS) All components are listed or exempted. Canada inventory All components are listed or exempted. Japan inventory Not determined. China inventory (IECSC) All components are listed or exempted. Korea inventory All components are listed or exempted. New Zealand Inventory (NZIoC) Not determined. Philippines inventory (PICCS) All components are listed or exempted. United States inventory (TSCA 8b) All components are listed or exempted.
15.2. Chemical Safety Assessment
Chemical Safety Assessment not applicable.

16 Other information
The product is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Full text of abbreviated H statements : Full text of classifications (CLP):
Full text of abbreviated R phrases : R36- Irritating to eyes.
Full text of classification (DSD/DPD) : Xi Irritant
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II
Notice to reader
The information provided herein was believed by Momentive Specialty Chemicals ("Momentive") to
be accurate at the time of preparation or prepared from sources believed to be reliable, but it is the
responsibility of the user to investigate and understand other pertinent sources of information, to
comply with all laws and procedures applicable to the safe handling and use of the product and to
determine the suitability of the product for its intended use. All products supplied by Momentive are
subject to Momentive's terms and conditions of sale. MOMENTIVE MAKES NO WARRANTY,
EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR
FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY
INFORMATION PROVIDED BY MOMENTIVE, except that the product shall conform to
Momentive's specifications. Nothing contained herein constitutes an offer for the sale of any
product.