1. IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY
Product Name:                      C-Systems Colla Rossa induritore in polvere
Product Type:                         Hardener in powder of paraformaldeide for resorcinica resin
Supplier:                                 Cecchi Gustavo & C. srl
Emergency Phone Numbers:  0584/383694

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
Properties / Symbols:
Carcinogenic category 3
Xn Harmful
Xi Irritant
R Phrases:
R20/21/22 Harmful by inhalation,in contact with skin and if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R40 Limited evidence of a carcinogenic effect.
R43 May cause sensitization by skin contact.
Adverse physicochemical, human health and environmental effects:
No other hazards
2.2 Label elements
Symbols:
Xn Harmful
R Phrases:
R20/21/22 Harmful by inhalation,in contact with skin and if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R40 Limited evidence of a carcinogenic effect.
R43 May cause sensitization by skin contact.
S Phrases:
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S36/37 Wear suitable protective clothing and gloves.
S7 Keep container tightly closed.
Contents:
paraformaldeide
2.3 Other hazards
Other Hazards:
No other hazards

3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
N.A.
3.2 Mixtures
Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and
corresponding classification:
25% - 30% paraformaldeide
CAS: 30525-89-4
Carc. Cat. 3,Xn,Xi; R40-20/21/22-36/37/38-43
3.1/4/Inhal Acute Tox. 4 H332
3.1/4/Dermal Acute Tox. 4 H312
3.1/4/Oral Acute Tox. 4 H302
3.3/2 Eye Irrit. 2 H319
3.8/3 STOT SE 3 H335
3.2/2 Skin Irrit. 2 H315
3.4.2/1 Skin Sens. 1 H317
3.6/2 Carc. 2 H351
0.5% - 1% methanol
N.67/548/CEE: 603-001-00-X CAS: 67-56-1 EC: 200-659-6
F,T; R11-23/24/25-39/23/24/25
2.6/2 Flam. Liq. 2 H225
3.8/1 STOT SE 1 H370
3.1/3/Oral Acute Tox. 3 H301
3.1/3/Dermal Acute Tox. 3 H311
3.1/3/Inhal Acute Tox. 3 H331

4. FIRST AID MEASURES
4.1 Description of first aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
Areas of the body that have - or are only even suspected of having - come into contact with the
product must be rinsed immediately with plenty of running water and possibly with soap.
Wash thoroughly the body (shower or bath).
Remove contaminated clothing immediatley and dispose off safely.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time,
then consult an opthalmologist immediately.
Protect uninjured eye.
In case of Ingestion:
Give nothing to eat or drink.
Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION
IMMEDIATELY.
In case of Inhalation:
If breathing is irregular or stopped, administer artificial respiration.
In case of inhalation, consult a doctor immediately and show him packing or label.
After contact with skin, wash immediately with soap and plenty of water.
4.2 Most important symptoms and effects, both acute and delayed
None
4.3 Indication of any immediate medical attention and special treatment needed
In case of accident or unwellness, seek medical advice immediately (show directions for use or
safety data sheet if possible).
Treatment:
None

5. FIRE-FIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2 Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3 Advice for fire-fighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.
Move undamaged containers from immediate hazard area if it can be done safely.

6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Wear breathing apparatus if exposed to vapours/dusts/aerosols.
Provide adequate ventilation.
Use appropriate respiratory protection.
See protective measures under point 7 and 8.
6.2 Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible
authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3 Methods and material for containment and cleaning up
Wash with plenty of water.
6.4 Reference to other sections
See also section 8 and 13

7. HANDLING AND STORAGE
7.1 Precautions for safe handling:
Avoid contact with skin and eyes, inhaltion of vapours and mists.
Use localized ventilation system.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals
in the containers.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recomened protective equipment.
7.2 Conditions for safe storage, including any incompatibilities
Always keep the containers tightly closed.
Keep away from food, drink and feed.
Instructions as regards storage premises:
Adequately ventilated premises.
7.3 Specific end use(s)
None in particular

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
paraformaldeide - Index: NA, CAS: 30525-89-4, EC No: NA
TLV TWA - TLV STEL- EC8H-MG/M3- ECST-MG/M3: None.
methanol - Index: 603-001-00-X, CAS: 67-56-1, EC No: 200-659-6
TLV TWA: 262 mg/m3, 200 ppm
TLV STEL: 328 skin mg/m3(1976)
8.2 Exposure controls
Eye protection:
Use close fitting safety goggles, don't use eye lens.
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or
viton.
Protection for hands:
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
Respiratory protection:
Use respiratory protection where ventilation is insufficient or exposure is prolonged, e.g.
CEN/FFP-2 or CEN/FFP-3.
Use adequate protective respiratory equipment, e.g. CEN/FFP-2 or CEN/FFP-3.
Thermal Hazards:
None
Environmental exposure controls:
None

9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance and colour: Solid
Odour: characteristic
Odour threshold: N.A.
pH: N.A.
Melting point / freezing point: N.D. °C
Initial boiling point and boiling range: N.D. °C
Solid/gas flammability: N.D.
Upper/lower flammability or explosive limits: N.A.
Vapour density: N.D.
Flash point: 78 °C
Evaporation rate: N.A.
Vapour pressure: paraformaldeide = 1.5 - 2 mbar ( 20°C)
Relative density: 0,576 kg/l
Solubility in water: Insoluble
Lipid solubility: N.D.
Partition coefficient (n-octanol/water): N.D.
Auto-ignition temperature: paraformaldeide = 370 °C
Decomposition temperature: N.A.
Viscosity: N.A.
Explosive properties: N.D.
Oxidizing properties: N.D.
9.2 Other information
Miscibility: N.A.
Fat Solubility: N.A.
Conductivity: N.A.
Substance Groups relevant properties N.A.

10. STABILITY AND REACTIVITY
10.1 Reactivity
Stable under normal conditions
10.2 Chemical stability
Stable under normal conditions
10.3 Possibility of hazardous reactions
It may generate flammable gases on contact with dithiocarbamates, elementary metals (alkalis,
alkaline earth), and nitrides.
It may generate toxic gases on contact with dithiocarbamates.
It may catch fire on contact with oxidising mineral acids, elementary metals (alkalis and alkaline
earth), nitrides, powerful oxidising agents, and powerful reducing agents.
10.4 Conditions to avoid:
Stable under normal conditions.
10.5 Incompatible materials:
None in particular.
10.6 Hazardous decomposition products:
None.

11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
There is no toxicological data available on the mixture. Consider the individual concentration of
each component to assess toxicological effects resulting from exposure to the mixture.
Toxicological information on main components of the mixture:
No toxicological information is available on the substances. However, refer to Section 3.
Carcinogenic category 3

12. ECOLOGICAL INFORMATION
12.1 Toxicity
Adopt good working practices, so that the product is not released into the environment.
12.2 Persistence and degradability
None
12.3 Bioaccumulative potential
N.A.
12.4 Mobility in soil
N.A.
12.5 Results of PBT and vPvB assessment
12.6 Other adverse effects
None

13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Recover, if possible. Send to authorised disposal plants or for incineration under controlled
conditions. In so doing, comply with the local and national regulations currently in force.

14. TRANSPORT INFORMATION

14.1 UN number:
Not classified as dangerous in the meaning of transport regulations.
14.2 UN proper shipping name:
N.A.
14.3 Transport hazard class(es):
N.A.
14.4 Packing Group:
N.A.
14.5 Environmental hazards
14.6 Special Precautions for User
N.A.
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Environmental Pollutant:
No

15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances). Dir. 99/45/EEC
(Classification, packaging and labelling of dangerous preparations). Dir. 98/24/EC (Risks related to
chemical agents at work). Dir. 2000/39/EC (Occupational exposure limit values); Dir. 2006/8/CE.
Regulation (CE) n. 1907/2006 (REACH), Regulation (CE) n. 1272/2008 (CLP), Regulation (CE) n.
790/2009 (1° ATP CLP), Regulation (EU) n. 453/2010 (Annex I).
Volatile CMR substances = 0.00 %
Halogenated VOCs which are assigned the risk phrase R40 = 0.00 %
Organic Carbon - C = 0.33
Where applicable, refer to the following regulatory provisions :
Directive 82/501/EEC ('Activities linked to risks of serious accidents') and subsequent
amendments.
Regulation (EC) nr 648/2004 (detergents).
1999/13/EC (VOC directive)
15.2 Chemical Safety Assessment
No

16. OTHER INFORMATION
Text of phrases referred to under heading 3:
R11 Highly flammable.
R20/21/22 Harmful by inhalation,in contact with skin and if swallowed.
R23/24/25 Toxic by inhalation,in contact with skin and if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with
skin and if swallowed.
R40 Limited evidence of a carcinogenic effect.
R43 May cause sensitization by skin contact.
This safety data sheet has been completely updated in compliance to Regulation 453/2010/EU.
This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van
Nostrand Reinold
CCNL - Appendix 1
Insert further consulted bibliography
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.