SAFETY DATA SHEET
 

 

 

 

COLLA ROSSA - resin
Rev. 1 march 2012 - n° batch 086-AB
 

1. IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY
Product Name:                        C-Systems Colla Rossa Resin
Product Type:                        Adhesive for wood
Supplier:                                 Cecchi Gustavo & C. srl
Emergency Phone Numbers:  0584/383694

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
Properties / Symbols:
Mutagenic category 3
T Toxic
Xn Harmful
C Corrosive
R Phrases:
R10 Flammable.
R23/24/25 Toxic by inhalation,in contact with skin and if swallowed.
R34 Causes burns.
R48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through
inhalation, in contact with skin and if swallowed.
R68 Possible risk of irreversible effects.
Adverse physicochemical, human health and environmental effects:
No other hazards
2.2 Label elements
Symbols:
T Toxic
R Phrases:
R10 Flammable.
R23/24/25 Toxic by inhalation,in contact with skin and if swallowed.
R34 Causes burns.
R48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through
inhalation, in contact with skin and if swallowed.
R68 Possible risk of irreversible effects.
S Phrases:
S27/28 After contact with skin, take off immediately all contaminated clothing, and wash
immediately with plenty of ... (to be specified by the manufacturer).
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S43 In case of fire, use foam, CO2,powder halogenated. To cool the containers to use vapour
water. Not to use directed water jets on flames.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible).
S63 In case of accident by inhalation: remove casualty to fresh air and keep at rest.
S7 Keep container tightly closed.
Contents:
phenol; carbolic acid; monohydroxybenzene; phenylalcohol
resorcinol; 1,3-benzenediol
2.3 Other hazards
Other Hazards:
No other hazards

3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
N.A.
3.2 Mixtures
Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and
corresponding classification:
20% - 25% phenol; carbolic acid; monohydroxybenzene; phenylalcohol
REACH No.: 01-2119471329-32 CAS: 108-95-2 EC: 203-632-7
Muta. Cat. 3,T,Xn,C; R23/24/25-34-48/20/21/22-68
3.5/2 Muta. 2 H341
3.9/2 STOT RE 2 H373
3.2/1B Skin Corr. 1B H314
3.1/3/Oral Acute Tox. 3 H301
3.1/3/Dermal Acute Tox. 3 H311
3.1/3/Inhal Acute Tox. 3 H331
10% - 12.5% resorcinol; 1,3-benzenediol
REACH No.: 01-2119480136-40 CAS: 108-46-3 EC: 203-585-2
Xn,Xi,N; R22-36/38-50
3.1/4/Oral Acute Tox. 4 H302
3.2/2 Skin Irrit. 2 H315
3.3/1 Eye Dam. 1 H318
3.8/1 STOT SE 1 H370
3.8/2 STOT SE 2 H371
3.4.2/1 Skin Sens. 1 H317
4.1/A1 Aquatic Acute 1 H400
7% - 10% ethanol; ethyl alcohol
N.67/548/CEE: 603-002-00-5 CAS: 64-17-5 EC: 200-578-6
F; R11; substance with a Community workplace exposure limit
2.6/2 Flam. Liq. 2 H225
1% - 3% methanol
N.67/548/CEE: 603-001-00-X CAS: 67-56-1 EC: 200-659-6
F,T; R11-23/24/25-39/23/24/25
2.6/2 Flam. Liq. 2 H225
3.8/1 STOT SE 1 H370
3.1/3/Oral Acute Tox. 3 H301
3.1/3/Dermal Acute Tox. 3 H311
3.1/3/Inhal Acute Tox. 3 H331

4. FIRST AID MEASURES
4.1 Description of first aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
WARNING! This product is toxic through skin contact. OBTAIN IMMEDIATE MEDICAL
ATTENTION.
Remove contaminated clothing immediatley and dispose off safely.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time,
then consult an opthalmologist immediately.
Protect uninjured eye.
In case of Ingestion:
Do NOT induce vomiting.
Give nothing to eat or drink.
In case of Inhalation:
If breathing is irregular or stopped, administer artificial respiration.
In case of inhalation, consult a doctor immediately and show him packing or label.
After contact with skin, wash immediately with soap and plenty of water.
4.2 Most important symptoms and effects, both acute and delayed
None
4.3 Indication of any immediate medical attention and special treatment needed
In case of accident or unwellness, seek medical advice immediately (show directions for use or
safety data sheet if possible).
Treatment:
None

5. FIRE-FIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media:
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2 Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3 Advice for fire-fighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.
Move undamaged containers from immediate hazard area if it can be done safely.

6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove all sources of ignition.
Wear breathing apparatus if exposed to vapours/dusts/aerosols.
Provide adequate ventilation. Use appropriate respiratory protection.
See protective measures under point 7 and 8.
6.2 Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible
authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3 Methods and material for containment and cleaning up
Wash with plenty of water.
6.4 Reference to other sections
See also section 8 and 13

7. HANDLING AND STORAGE
7.1 Precautions for safe handling:
Avoid contact with skin and eyes, inhaltion of vapours and mists.
Use localized ventilation system.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals
in the containers.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recomened protective equipment.
7.2 Conditions for safe storage, including any incompatibilities
Always keep the containers tightly closed.
Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to sunlight.
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Cool and adequately ventilated.
7.3 Specific end use(s)
None in particular

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
phenol; carbolic acid; monohydroxybenzene; phenylalcohol - REACH: 01-2119471329-32, CAS:
108-95-2, EC No: 203-632-7
TLV TWA: 19 Skin mg/m3, 5 ppm
resorcinol; 1,3-benzenediol - REACH: 01-2119480136-40, CAS: 108-46-3, EC No: 203-585-2
TLV TWA - TLV STEL- EC8H-MG/M3- ECST-MG/M3: None.
ethanol; ethyl alcohol - Index: 603-002-00-5, CAS: 64-17-5, EC No: 200-578-6
TLV TWA: 1880 mg/m3, 1000 ppm
methanol - Index: 603-001-00-X, CAS: 67-56-1, EC No: 200-659-6
TLV TWA: 262 mg/m3, 200 ppm
TLV STEL: 328 skin mg/m3(1976)
8.2 Exposure controls
Eye protection:
Use close fitting safety goggles, don't use eye lens.
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or
viton.
Protection for hands:
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
Respiratory protection:
Use adequate protective respiratory equipment, e.g. CEN/FFP-2 or CEN/FFP-3.
Thermal Hazards:
None
Environmental exposure controls:
None

9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance and colour: Liquid
Odour: characteristic
Odour threshold: N.A.
pH: 6 - 8.5
Melting point / freezing point: N.D. °C
Initial boiling point and boiling range: N.A.
Solid/gas flammability: N.D.
Upper/lower flammability or explosive limits: N.A.
Vapour density: N.D.
Flash point: 37 °C
Evaporation rate: N.A.
Vapour pressure: N.D. mbar ( 20°C)
Relative density: (25°C) = 1.15 kg/l
Solubility in water: Soluble
Lipid solubility: N.D.
Partition coefficient (n-octanol/water): 1.8 log Pow
Auto-ignition temperature: N.D. °C
Decomposition temperature: N.A.
Viscosity: (25°C) = 250 - 800 mPas
Explosive properties: N.D.
Oxidizing properties: N.D.
9.2 Other information
Miscibility: N.A.
Fat Solubility: N.A.
Conductivity: N.A.
Substance Groups relevant properties N.A.

10. STABILITY AND REACTIVITY
10.1 Reactivity
Stable under normal conditions
10.2 Chemical stability
Stable under normal conditions
10.3 Possibility of hazardous reactions
None
10.4 Conditions to avoid:
Stable under normal conditions.
10.5 Incompatible materials:
Avoid contact with combustible materials. The product could catch fire.
10.6 Hazardous decomposition products:
None.

11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
There is no toxicological data available on the mixture. Consider the individual concentration of
each component to assess toxicological effects resulting from exposure to the mixture.
Toxicological information on main components of the mixture:
methanol - Index: 603-001-00-X, CAS: 67-56-1, EC No: 200-659-6
OBSERVATIONS ON HUMAN SUBJECTS:
Methanol poisoning as a result of ingestion produces three types of effect. The first to
appear is a narcotic effect, similar to that observed in ethanol poisoning. The next to
appear is metabolic acidosis, caused by an accumulation of formate which is produced
more quickly than it is eliminated.
The third type of effect consists in disorders affecting vision and the nervous system.
In human subjects, exposure (of variable intensity and duration) to methanol vapours
causes irritation to all the mucous membranes, headache, buzzing in the ears, tiredness,
insomnia, nystagmus, tremors, dizziness, nausea, colic, dilated pupils, double vision,
blindness, itching of the skin, eczema and dermatitis.
Mutagenic category 3

12. ECOLOGICAL INFORMATION
12.1 Toxicity
Adopt good working practices, so that the product is not released into the environment.
phenol; carbolic acid; monohydroxybenzene; phenylalcohol - REACH: 01-2119471329-32, CAS:
108-95-2, EC No: 203-632-7
Test: EC50 Species: Daphnia Duration h: 48 mg/l: 3.1
Test: LC50 Species: Fish Duration h: 96 mg/l: 8.9
Test: EC50 Species: Algae Duration h: 96 mg/l: 61.1
12.2 Persistence and degradability
None
12.3 Bioaccumulative potential
N.A.
12.4 Mobility in soil
N.A.
12.5 Results of PBT and vPvB assessment
List of substances dangerous for the environment and corresponding classification:
10% - 12.5% resorcinol; 1,3-benzenediol
REACH No.: 01-2119480136-40 CAS: 108-46-3 EC: 203-585-2
R50 Very toxic to aquatic organisms.
12.6 Other adverse effects
None

13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Recover, if possible. Send to authorised disposal plants or for incineration under controlled
conditions. In so doing, comply with the local and national regulations currently in force.

14. TRANSPORT INFORMATION
14.1 UN number:
ADR-UN Number: 2927
IATA-UN Number: 2927
IMDG-UN Number: 2927
14.2 UN proper shipping name:
ADR-Shipping Name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. (phenol;
carbolic acid; monohydroxybenzene; phenylalcohol)
IATA-Shipping Name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. (phenol;
carbolic acid; monohydroxybenzene; phenylalcohol)
IMDG-Shipping Name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. (phenol;
carbolic acid; monohydroxybenzene; phenylalcohol)
14.3 Transport hazard class(es):
ADR-Class: 6.1
ADR-HI number: 68
IATA-Class: 6.1
IATA-Label: Toxic & Corrosive
IMDG-Class: 6.1
14.4 Packing Group:
ADR-Packing Group: II
IATA-Packing group: II
IMDG-Packing group: II
14.5 Environmental hazards
IMDG-Marine pollutant: No
14.6 Special Precautions for User
ADR-Subsidiary risks: 8
ADR-Tunnel Restriction Code: (D/E)
IATA-Passenger Aircraft: 653
IATA-Subsidiary risks: 8
IATA-Cargo Aircraft: 660
IATA-S.P.: A137
IATA-ERG: 6C
IMDG-EmS: F-A , S-B
IMDG-Subsidiary risks: 8
IMDG-Storage category: B
IMDG-Storage notes: Clear of living quarters.
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Environmental Pollutant:
No

15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances). Dir. 99/45/EEC
(Classification, packaging and labelling of dangerous preparations). Dir. 98/24/EC (Risks related to
chemical agents at work). Dir. 2000/39/EC (Occupational exposure limit values); Dir. 2006/8/CE.
Regulation (CE) n. 1907/2006 (REACH), Regulation (CE) n. 1272/2008 (CLP), Regulation (CE) n.
790/2009 (1° ATP CLP), Regulation (EU) n. 453/2010 (Annex I).
Where applicable, refer to the following regulatory provisions :
Directive 82/501/EEC ('Activities linked to risks of serious accidents') and subsequent
amendments.
Regulation (EC) nr 648/2004 (detergents).
1999/13/EC (VOC directive)
Volatile Organic compounds - VOCs = 29.60 %
Volatile Organic compounds - VOCs = 340.40 g/l
Volatile CMR substances = 0.00 %
Halogenated VOCs which are assigned the risk phrase R40 = 0.00 %
Organic Carbon - C = 20.09

16. OTHER INFORMATION
Text of phrases referred to under heading 3:
R11 Highly flammable.
R22 Harmful if swallowed.
R23/24/25 Toxic by inhalation,in contact with skin and if swallowed.
R34 Causes burns.
R36/38 Irritating to eyes and skin.
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with
skin and if swallowed.
R48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through
inhalation, in contact with skin and if swallowed.
R50 Very toxic to aquatic organisms.
R68 Possible risk of irreversible effects.
Paragraphs modified from the previous revision:
3. COMPOSITION/INFORMATION ON INGREDIENTS
7. HANDLING AND STORAGE
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
9. PHYSICAL AND CHEMICAL PROPERTIES
10. STABILITY AND REACTIVITY
12. ECOLOGICAL INFORMATION
15. REGULATORY INFORMATION

The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.