DECO-DECK PAINT Rev. 1 february 2013 - n° batch 052-AC white
053-AC grey
 

1. DESIGNATION OF PRODUCT AND COMPANY
Trade name                              DECO-DECK
Chemical description:      Elastic paint for decks for ships and yachts
Supplier:                                    Cecchi Gustavo & C
                                                        tel +39 0584/383694 fax +39 0584/395182 www.cecchi.it - info@cecchi.it

2. Hazards identification
 2.1. Classification of the substance or mixture.
The product is classified as hazardous pursuant to the provisions set forth in Directives 67/548/EEC and 1999/45/EC and/or EC Regulation 1272/2008 (CLP) (and subsequent amendments and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulationn 1907/2006 and subsequent amendments.
Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet.
Danger Symbols: Xn
R phrases: 65
The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet.
2.2. Label elements.
Hazard labelling pursuant to Directives 67/548/EEC and 1999/45/EC and subsequent amendments and supplements.
Xn
HARMFUL
R65 HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED.
S62 IF SWALLOWED, DO NOT INDUCE VOMITING: SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THIS
CONTAINER OR LABEL.
Contains: NAPHTA (PETROL.) HYDROTREATED HEAVY

2.3. Other hazards.
Information not available.

3. Composition/information on ingredients.
3.1. Substances. Information not relevant.
3.2. Mixtures.


Contains:

Identification.

Conc. %.

Classification 67/548/EEC.

Classification 1272/2008 (CLP).

NAPHTA (PETROL.) HYDROTREATED HEAVY

CAS.

64742-48-9 10 - 11

Xn R65, Note H P

Carc. 1B H350, Muta. 1B H340, Asp. Tox. 1 H304, Note H P

EC.

265-150-3

INDEX.

649-327-00-6

T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N = Dangerous for the Environment(N)
The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet.

4. First aid measures.
4.1. Description of first aid measures.
EYES: Irrigate copiously with clean, fresh water for at least 15 minutes. Seek medical advice.
SKIN: Wash immediately with plenty of water. Remove contaminated clothing. If irritation persists, seek medical attention. Wash contaminated clothing before using them again.
INHALATION: Remove to open air. If breathing is irregular, seek medical advice.
INGESTION: Obtain immediate medical attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person.
4.2. Most important symptoms and effects, both acute and delayed.
For symptoms and effects caused by the contained substances see chap. 11.
4.3. Indication of any immediate medical attention and special treatment needed.
Follow doctor's orders.

5. Firefighting measures.
5.1. Extinguishing media.
SUITABLE EXTINGUISHING MEDIA
The extinction equipment should be of the conventional kind: carbon dioxide, foam, powder and nebulised water. EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS
None in particular.
5.2. Special hazards arising from the substance or mixture.
HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products (carbon oxide, toxic pyrolysis products, etc).
5.3. Advice for firefighters.
GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Hardhat with visor, fireproof clothing (fireproof jacket and trousers with straps around arms, legs and waist), work gloves (fireproof, cut proof and dielectric), a depressurised mask with facemask covering the whole of the operator’s face or a self-respirator (self-protector) in the event of large quantities of fume.

6. Accidental release measures.
6.1. Personal precautions, protective equipment and emergency procedures. Eliminate all sources of ignition (cigarettes,
flames, sparks, etc.) from the leakage site. If there are no contraindications, spray solid products
with water to prevent the formation of dust. Use breathing equipment if fumes or powders are released into the air. Block the leakage if there is no hazard. Do not handle damaged containers or the leaked product before donning appropriate protective gear. For information on risks for the environmental and health, respiratory tract protection, ventilation and personal protection equipment, see the other sections of this sheet.
6.2. Environmental precautions.
The product must not penetrate the sewers, surface water, ground water and neighbouring areas.
6.3. Methods and material for containment and cleaning up.
Use inert absorbent material (sand, vermiculite, diatomeous earth, Kieselguhr, etc.) to soak up leaked product. Collect the majority of the remaining material and deposit it in containers for disposal. If there are no contraindications, use jets of water to eliminate product residues. Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.
6.4. Reference to other sections.
Any information on personal protection and disposal is given in sections 8 and 13.

7. Handling and storage.
7.1. Precautions for safe handling.

Do not smoke while handling and use.
7.2. Conditions for safe storage, including any incompatibilities.
Store in a well ventilated place, keep far away from sources of heat, bright flames and sparks and other sources of ignition.
7.3. Specific end use(s).
Information not available.

8. Exposure controls/personal protection.
8.1. Control parameters.
Information not available.
8.2. Exposure controls.
As the use of adequate technical equipment must always take priority over personal protection equipment, make sure that the workplace is well aired through effective local aspiration or bad air vent. If such operations do not make it possible to keep the concentration of the product below the permitted workplace exposure thresholds a suitable respiratory tract protection must be used. See product label for hazard details during use. Ask your chemical substance suppliers for advice when choosing personal protection equipment. Personal protection equipment must comply with the rules in force indicated below.
HAND PROTECTION
Protect hands with category I (ref. Directive 89/686/EEC and standard EN 374) work gloves, such as those in latex, PVC or equivalent. The following should be considered when choosing work glove material: degradation, breakage times and permeation. Work glove resistance to preparations should be checked before use, as it can be unpredictable. Gloves’ limit depends on the duration of exposure.
EYE PROTECTION
Use of protective airtight goggles (ref. standard EN 166) recommended.
SKIN PROTECTION
Wear category I professional long-sleeved overalls and safety footwear (ref. Directive 89/686/CEE and standard EN 344). Wash body with soap and water after removing overalls.
RESPIRATORY PROTECTION
If the threshold value for one or more of the substances present in the preparation for daily exposure in the workplace or to a fraction
established by the company’s prevention and protection service is exceeded, wear a mask with an B or universal filter, the class (1, 2 or 3) of which must be chosen according to the limit concentration of use (ref. standard EN 141).
The use of breathing protection equipment, such as masks with organic vapour and dust/mist cartridges, is necessary in the absence of technical measures limiting worker exposure. The protection provided by masks is in any case limited.
If the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in the event of an emergency, or when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17% volume, wear self-contained, open-circuit compressed air breathing apparatus (ref. standard EN 137) or fresh air hose breathing apparatus for use with full face mask, half mask or mouthpiece (ref. standard EN 138).
In the presence of risks of exposure to splashes or squirts during work, adequate mouth, nose and eye protection should be used to prevent accidental absorption.

9. Physical and chemical properties.

9.1. Information on basic physical and chemical properties. Appearance

Not available.

Colour

Not available.

Odour

Not available.

Odour threshold.

Not available.

pH.

Not available.

Melting or freezing point. Not available.
Boiling point. Not available.
Distillation range. Not available.
Flash point. Not available.
Evaporation Rate Not available.
Flammability of solids and gases Not available.
Lower inflammability limit. Not available.
Upper inflammability limit. Not available.
Lower explosive limit. Not available.
Upper explosive limit. Not available.
Vapour pressure. Not available.
Vapour density Not available.
Specific gravity. Not available.
Solubility Not available.
Partition coefficient: n-octanol/water Not available.
Ignition temperature. Not available.
Decomposition temperature. Not available.
Viscosity Not available.
Reactive Properties Not available.
9.2. Other information.
Information not available.

10. Stability and reactivity.
10.1. Reactivity.
There are no particular risks of reaction with other substances in normal conditions of use.
10.2. Chemical stability.
The product is stable in normal conditions of use and storage.
10.3. Possibility of hazardous reactions.
The vapours may also form explosive mixtures with the air.
10.4. Conditions to avoid.
Avoid overheating, electrostatic discharge and all sources of ignition.
10.5. Incompatible materials.
Information not available.
10.6. Hazardous decomposition products.
In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released.

11. Toxicological information.
11.1. Information on toxicological effects. The introduction of even small quantities of this liquid into the respiratory system in case of ingestion or vomit may cause bronchopneumonia and pulmonary edema.

12. Ecological information.
Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or sewers or contaminate soil or vegetation.
12.1. Toxicity.
Information not available.
12.2. Persistence and degradability.
Information not available.
12.3. Bioaccumulative potential.
Information not available.
12.4. Mobility in soil.
Information not available.
12.5. Results of PBT and vPvB assessment.
Information not available.
12.6. Other adverse effects.

Information not available.

13. Disposal considerations.
13.1. Waste treatment methods.
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

14. Transport information.
The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations.

15. Regulatory information.
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture.
Seveso category. None.
Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006.
Product.
Point. 3
Contained substance.
Substances in Candidate List (Art. 59 REACH).
None.
Substances subject to authorisarion (Annex XIV REACH).
None.
Healthcare controls.
Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks related to the workers' health and safety are modest and that the 98/24/EC directive is respected.
15.2. Chemical safety assessment.
No chemical safety assessment has been processed for the mixture and the substances it contains.

16. Other information.
Text of hazard (H) indications mentioned in section 2-3 of the sheet:
Carc. 1B Carcinogenicity, category 1B
Muta. 1B Germ cell mutagenicity, category 1B
Asp. Tox. 1 Aspiration hazard, category 1
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H340 May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H304 May be fatal if swallowed and enters airways.
Text of risk (R) phrases mentioned in section 2-3 of the sheet:
R65 HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED.
GENERAL BIBLIOGRAPHY
1. Directive 1999/45/EC and following amendments
2. Directive 67/548/EEC and following amendments and adjustments
3. Regulation (EC) 1907/2006 (REACH) of the European Parliament
4. Regulation (EC) 1272/2008 (CLP) of the European Parliament
5. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament
6. Regulation (EC) 453/2010 of the European Parliament
7. The Merck Index. - 10th Edition
8. Handling Chemical Safety
9. Niosh - Registry of Toxic Effects of Chemical Substances
10. INRS - Fiche Toxicologique (toxicological sheet)
11. Patty - Industrial Hygiene and Toxicology
12. N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition

The information contained herein is based on what we believe to be reliable data, but it is presented without guarantee or warranty by our part and Cecchi Gustavo & C. disclaims any liability incurred from the use thereof.
Nothing contained herein is to be construed as recommendations for use in violation of any existing patent, foreign or domestic, or of applicable laws and regulations.
Apply to Cecchi Gustavo & C.  for further information about the product and its use. It is recommended to pass on this MSDS to customers and handlers.