SAFETY DATA SHEET
 

 

 

 

  SPINNAKER EGGSHELL Rev. 1 june 2012 - n° batch 181-AB
 

1 Identification of the substance/preparation and of the company/undertaking
Trade name: SPINNAKER EGGSHELL YACHT VARNISH
Application of the substance: one-component mat varnish.
Manufacturer/Supplier Cecchi Gustavo & C. srl - Via M. Coppino 253,
55049 Viareggio (LU) ITALY www.cecchi.it - info@cecchi.it
Information in case of emergency: +39 0584/383694 - info@cecchi.it
From monday to friday office hours 8:30 – 12:30, 14:00 – 18:30

SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
R10-66: Flammable. Repeated exposure may cause skin dryness or cracking.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General
Classification guideline for preparations of the EU" in the latest valid version.
At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature data.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms

 
GHS02  

 


GHS02
· Signal word Warning
· Hazard statements
H226 Flammable liquid and vapour.
· Precautionary statements
P101 If medical advice is needed, have product container or label at
hand.
P102 Keep out of reach of children.
P103 Read label before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No
smoking.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P280 Wear protective gloves/protective clothing/eye protection/face
protection.
P240 Ground/bond container and receiving equipment.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
P501 Dispose of contents/container in accordance with local/regional/
national/international regulations.
· Additional information:
EUH066 Repeated exposure may cause skin dryness or cracking.
Contains 2-butanone oxime,carboxylate. May cause an allergic reaction.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

 

SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterization: Mixtures
· Description:
Resin mixture
Solvent mixture with additives
Mixture of synthetic binders, matting agent, additives and organic solvents

- naphta (petroleum), hydrotreated heavy 25-50%
CAS: 64742-48-9
EINECS: 265-150-3
Xn R65
R10-66
Flam. Liq. 3, H226
Asp. Tox. 1, H304

- Solvent naphtha (petroleum), heavy arom. <= 1%
CAS: 64742-94-5
EINECS: 265-198-5
Xn R65
N R51/53
Asp. Tox. 1, H304

- 2-butanone oxime <= 0.5%
CAS: 96-29-7
EINECS: 202-496-6
Xn R21-40
Xi R41
Xi R43
Carc. Cat. 3
Carc. 2, H351
Eye Dam. 1, H318
Acute Tox. 4, H312; Skin Sens. 1, H317

- A mixture of branched and linear C7-C9 alkyl 3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethyl-ethyl)-4- hydroxyphenyl]propionates <= 0.5%
CAS: 127519-17-9 ELINCS: 407-000-3
N R51/53 Aquatic Chronic 2, H411

-1,2,4-trimethylbenzene <= 0.5%
CAS: 95-63-6 EINECS: 202-436-9
Xn R20 Xi R36/37/38  N R51/53 R10
Flam. Liq. 3, H226
Aquatic Chronic 2, H411
Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye
Irrit. 2, H319; STOT SE 3, H335

- cobalt bis(2-ethylhexanoate) <= 0.5%
CAS: 136-52-
EINECS: 205-250-6
Xn R22
N R50/53
Aquatic Acute 1, H400; Aquatic Chronic 1, H410
Acute Tox. 4, H302
· Additional information:
For the wording of the listed risk phrases refer to section 16.

· Additional information:
For the wording of the listed risk phrases refer to section 16.

SECTION 4: First aid measures
· 4.1 Description of first aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures
· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol
resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixture
No further relevant information available.
· 5.3 Advice for firefighters
· Protective equipment: No special measures required.

SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal
binders, sawdust).
Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage
· 7.1 Precautions for safe handling
Keep away from heat and direct sunlight.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities:
No further data; see item 7.

8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
107-98-2 1-methoxy-2-propanol
WEL Short-term value: 560 mg/m3, 150 ppm
Long-term value: 375 mg/m3, 100 ppm
Sk
· DNELs
64742-48-9 naphta (petroleum), hydrotreated heavy
Dermal Long-term - systemic effects, worker 300 mg/kg bw/day (Werker/ Worker)
Inhalative Long-term - systemic effects, worker 1500 mg/m3 (Werker/Worker)
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
· Respiratory protection:
Suitable respiratory protective device recommended.
In case of brief exposure or low pollution use respiratory filter device. In
case of intensive or longer exposure use self-contained respiratory protective device.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the
substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for
the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times,
rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but
also on further marks of quality and varies from manufacturer to manufacturer.
As the product is a preparation of several substances, the resistance of the
glove material can not be calculated in advance and has therefore to be checked
prior to the application.
· Penetration time of glove material
Nitrilrubber; handglove thickness >0.45mm, penetrationtime >480min. according
EN374.
PVA, Fluorised rubber; handglove thickness >0.45mm, penetrationtime >480min.
according EN347.
The exact break trough time has to be found out by the manufacturer of the
protective gloves and has to be observed.
· As protection from splashes gloves made of the following materials are
suitable:
Cloropene; handglove thickness >0.7mm, penetration time >60min. according
EN374.
Nitrilrubber; handglove thickness >0.3mm, penetration time >60min. according
EN374.
· Eye protection:
Tightly sealed goggles

SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: According to product specification
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 150 °C
· Flash point:  42 °C
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 240.0 °C
· Decomposition temperature: Not determined.
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However, formation
of explosive air/vapour mixtures are possible.
· Explosion limits:
Lower: 0.6 Vol %
Upper: 7.0 Vol %
· Vapour pressure at 20 °C: 1.0 hPa
· Density at 20 °C: 0.92854 g/cm3
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/
water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic at 20 °C: 35 s (ISO 6 mm)
· Solvent content:
Organic solvents: 48.1 %
VOC content: 48.1 %
VOC content:
473.6 g/l / 3.95 lb/gl
Solids content: 51.9 % (SC % 1h150 C)
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity
· 10.1 Reactivity
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products:
No dangerous decomposition products known.

 SECTION 11: Toxicological information
· 11.1 Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
64742-48-9 naphta (petroleum), hydrotreated heavy
Oral LD50 >5000 mg/kg bw (rat)
Dermal LD50 >5000 mg/kg bw (rabbit) ((24h))
Inhalative LC50 >5000 mg/m3 (vapour) (rat) ((8h))
107-98-2 1-methoxy-2-propanol
Oral LD50 5660 mg/kg bw (rat)
Dermal LD50 13000 mg/kg bw (rabbit)
Inhalative LC50/4 h 6 mg/l (rat)
96-29-7 2-butanone oxime
Oral LD50 3700 mg/kg bw (rat)
Dermal LD50 200-2000 mg/kg bw (rat)
Inhalative LC50/4 h 20 mg/l (rat)
95-63-6 1,2,4-trimethylbenzene
Oral LD50 5000 mg/kg bw (rat)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.

 SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
64742-48-9 naphta (petroleum), hydrotreated heavy
EL50 (48h) >1000 mg/l ((Daphnia magna-OECD 202))
EbL50 (72h) >1000 mg/l (Pseudokirchneriella subcapitata-OECD 201)
ErL (72h) >1000 mg/l (Pseudokirchneriella subcapitata-OECD 201)
LL50 (96h) >1000 mg/l ((Onorhynchus mykiss OECD 203))
NOELR (72h) 3 mg/l ((Pseudo. subcapitata-biomass-OECD 201))
100 mg/l ((Pseudo. subcap. growth rate OECD 201))
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous
for water
Do not allow undiluted product or large quantities of it to reach ground water,
water course or sewage system.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations
· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to
reach sewage system.
· European waste catalogue
08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF
COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES,
SEALANTS AND PRINTING INKS
08 01 00 wastes from MFSU and removal of paint and varnish
08 01 11* waste paint and varnish containing organic solvents or other
dangerous substances
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

 SECTION 14: Transport information
· 14.1 UN-Number
· ADR, IMDG, IATA UN1263
· 14.2 UN proper shipping name
· ADR 1263 PAINT (not viscous)
· IMDG, IATA PAINT
· 14.3 Transport hazard class(es)
· ADR
· Class 3 (F1) Flammable liquids.
· Label 3
· IMDG, IATA
· Class 3 Flammable liquids.
· Label 3
· 14.4 Packing group
· ADR, IMDG, IATA III
· 14.5 Environmental hazards:
· Marine pollutant: No
· 14.6 Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 30
· EMS Number: F-E,S-E
· 14.7 Transport in bulk according to
Annex II of MARPOL73/78 and the IBC
Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 5L
· Transport category 3
· Tunnel restriction code D/E
· UN "Model Regulation": UN1263, PAINT (not viscous), 3, III

SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
· National regulations:
· Technical instructions (air):
Class Share in %
I <=0.5
· Waterhazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
· 15.2 Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information
This information is based on our present knowledge. However, this shall not
constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship.
· Relevant phrases
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
R10 Flammable.
R20 Harmful by inhalation.
R21 Harmful in contact with skin.
R22 Harmful if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R36/38 Irritating to eyes and skin.
R40 Limited evidence of a carcinogenic effect.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organization
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement
concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
DNEL: Derived No-Effect Level (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent