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1. Identification of the substance
Trade name: SPINNAKER GOLD FASHION cod YACHT VARNISH
Application of the substance: High gloss varnish for wood
Manufacturer/Supplier Cecchi Gustavo & C. srl - Via M. Coppino 253,
55049 Viareggio (LU) ITALY www.cecchi.it - info@cecchi.it
Information in case of emergency: +39 0584/383694 - info@cecchi.it
From monday to friday office hours 8:30 – 12:30, 14:00 – 18:30
2 Hazards identification
· Classification of the substance or mixture
· Classification system:
The classification is according to the latest editions of the EU-lists, and
extended by company and literature data.
· Label elements
· Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives /
Ordinance on Hazardous Materials.
· Risk phrases:
10 Flammable.
66 Repeated exposure may cause skin dryness or cracking.
· Safety phrases:
2 Keep out of the reach of children.
23 Do not breathe vapour/spray.
24 Avoid contact with skin.
46 If swallowed, seek medical advice immediately and show this container or label.
51 Use only in well-ventilated areas.
56 Dispose of this material and its container to hazardous or special waste collection point.
· Special labelling of certain preparations:
Contains 2-butanone oxime, cobalt carboxylate. May produce an allergic reaction.
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description:
Resin mixture
Solvent mixture with additives
Mixture of synthetic binders, additives and organic solvents
· Dangerous components:
- naphta (petroleum), hydrotreated heavy 25-50%
Xn R65
R10-66
Flam. Liq. 3, H226
CAS: 64742-48-9
EINECS: 265-150-3
- barium sulphate, natural ≤ 2.5%
substance with a Community workplace exposure limit
CAS: 7727-43-7
EINECS: 231-784-4
- butan-1-ol ≤ 2.5%
Xn R22
Xi R37/38-41
R10-67
Flam. Liq. 3, H226
Eye Dam. 1, H318
Acute Tox. 4, H302; Skin Irrit. 2, H315; STOT
SE 3, H335-H336
CAS: 71-36-3
EINECS: 200-751-6
- A mixture of branched and linear C7-C9 alkyl 3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethyl-ethyl)-4-hydroxyphenyl]propionates £ 2.5%
N R51/53
Aquatic Chronic 2, H411
CAS: 127519-17-9
ELINCS: 407-000-3
- 2-butanone oxime ≤ 2.5%
Xn R21-40
Xi R41
Xi R43
Carc. Cat. 3
Carc. 2, H351
Eye Dam. 1, H318
Acute Tox. 4, H312; Skin Sens. 1, H317
CAS: 96-29-7
EINECS: 202-496-6
- p-mentha-1.4(8)-dieen ≤ 2.5%
Xn R65
N R51/53
Asp. Tox. 1, H304
Aquatic Chronic 2, H411
CAS: 586-62-9
- 4-(1,1,3,3-tetramethylbutyl)phenol ≤ 2.5%
CAS: 140-66-9
EINECS: 205-426-2
- 4-tert-butylphenol ≤ 2.5%
Xi R36/37/38
N R51/53
Aquatic Chronic 2, H411
Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT
SE 3, H335
CAS: 98-54-4
EINECS: 202-679-0
- cobalt bis(2-ethylhexanoate) ≤ 2.5%
Xn R22
N R50/53
Aquatic Acute 1, H400; Aquatic Chronic 1, H410
Acute Tox. 4, H302
CAS: 136-52-7
EINECS: 205-250-6
· SVHC
140-66-9 4-(1,1,3,3-tetramethylbutyl) phenol
· Additional information:
For the wording of the listed risk phrases refer to section 16.
4 First aid measures
· Description of first aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol
resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
No further relevant information available.
· Advice for firefighters
· Protective equipment: No special measures required.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal
binders, sawdust).
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
· Handling:
· Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store only in the original receptacle.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
· Additional information about design of technical facilities:
No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
7727-43-7 barium sulphate, natural
WEL Long-term value: 10* 4** mg/m3
*inhalable dust **respirable dust
71-36-3 butan-1-ol
WEL Short-term value: 154 mg/m3, 50 ppm
Sk
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
· Respiratory protection:
Suitable respiratory protective device recommended.
In case of brief exposure or low pollution use respiratory filter device. In
case of intensive or longer exposure use self-contained respiratory protective
device.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the
substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for
the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times,
rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but
also on further marks of quality and varies from manufacturer to manufacturer.
As the product is a preparation of several substances, the resistance of the
glove material can not be calculated in advance and has therefore to be checked
prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the
protective gloves and has to be observed.
· Eye protection:
Tightly sealed goggles
· Body protection: Use protective suit.
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: According to product specification
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
· Flash point: 36 °C
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 240.0 °C
· Decomposition temperature: Not determined.
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However, formation
of explosive air/vapour mixtures are
possible.
· Explosion limits:
Lower: 0.6 Vol %
Upper: 7.0 Vol %
· Vapour pressure at 20 °C: 1.0 hPa
· Density at 20 °C: 0.94 g/cm3 (ISO 2811)
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/
water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic at 20 °C: 55 s (ISO 6 mm)
· Solvent content:
Organic solvents: 38.8 %
VOC content: 38.8 %
VOC content:
373.8 g/l / 3.12 lb/gl
Solids content: 61.2 % (SC% 1h 150C)
· Other information No further relevant information available.
10 Stability and reactivity
· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
96-29-7 2-butanone oxime
Oral LD50 3700 mg/kg (rat)
Dermal LD50 200-2000 mg/kg (rat)
Inhalative LC50/4 h 20 mg/l (rat)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous
for water
Do not allow undiluted product or large quantities of it to reach ground water,
water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to
reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· UN-Number
· ADR, IMDG, IATA UN1263
· UN proper shipping name
· ADR 1263 PAINT (not viscous)
· IMDG, IATA PAINT
· Transport hazard class(es)
· ADR
· Class 3 (F1) Flammable liquids.
· Label 3
· IMDG
· Class Void
· IATA
· Class 3 Flammable liquids.
· Label 3
· Packing group
· ADR, IATA III
· IMDG Void
· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 30
· EMS Number: F-E,S-E
· Transport in bulk according to Annex
II of MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 5L
· Transport category 3
· Tunnel restriction code D/E
· UN "Model Regulation": UN1263, PAINT (not viscous), 3, III
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the
substance or mixture
· National regulations:
· Technical instructions (air):
Class Share in %
I <= 2,5
· Waterhazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57
140-66-9 4-(1,1,3,3-tetramethylbutyl)phenol
· Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not
constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship.
· Relevant phrases
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
R10 Flammable.
R21 Harmful in contact with skin.
R22 Harmful if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R37/38 Irritating to respiratory system and skin.
R40 Limited evidence of a carcinogenic effect.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organization
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement
concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
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