SAFETY DATA SHEET
 

 

 

 

SPINNAKER GOLD FASHION MAT cod Rev. 1 dicember 2012 n° batch 352-AB
 

1. Identification of the substance/preparation and of the company/undertaking
Trade name:                                        SPINNAKER GOLD FASHION MAT
Application of the substance:             the preparation Satin varnish alternative
Supplier:                                              Cecchi Gustavo & C. srl
Information in case of emergency: 0584/383694

2 Hazards identification
· Hazard description: Not applicable.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General
Classification guideline for preparations of the EU" in the latest valid
version.
At long or repeated contact with skin it may cause dermatitis due to the
degreasing effect of the solvent.
R 10 Flammable.
R 66 Repeated exposure may cause skin dryness or cracking.
· Classification system:
The classification is according to the latest editions of the EU-lists, and
extended by company and literature data.
· GHS label elements
Warning
H226 - Flammable liquid and vapour.
EUH066 - Repeated exposure may cause skin dryness or cracking.
Contains 2-butanone oxime. May produce an allergic reaction.
· Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P240 Ground/bond container and receiving equipment.
· Response:
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
· Disposal:
P501 Dispose of contents/container in accordance with local/regional/national/
international regulations.

3 Composition/information on ingredients
· Chemical characterization
· Description:
Resin mixture
Solvent mixture with additives
Mixture of synthetic binders, matting agent, additives
and organic solvents
· Dangerous components:
CAS: 64742-48-9
EINECS: 265-150-3
naphta (petroleum), hydrotreated heavy
Xn; R 10-65-66
Danger: 3.10/1
Warning: 2.6/3
25-50%
CAS: 107-98-2
EINECS: 203-539-1
1-methoxy-2-propanol
R 10
Warning: 2.6/3
<= 2.5%
CAS: 64742-95-6 petroleum, nafta, licht aromatisch
Xn, Xi, N; R 10-36/38-51/53-65
Danger: 3.10/1
Warning: 2.6/3; 3.2/2, 3.3/2
4.1.C/2
<= 2.5%
CAS: 96-29-7
EINECS: 202-496-6
2-butanone oxime
Xn, Xi; R 21-40-41-43
Danger: 3.3/1
Warning: 3.6/2; 3.1.D/4, 3.4.S/1
<= 2.5%
CAS: 127519-17-9
ELINCS: 407-000-3
A mixture of branched and linear C7-C9 alkyl 3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethyl-ethyl)-4-hydroxyphenyl]propionates
N; R 51/53
4.1.C/2
<= 2.5%
CAS: 95-63-6
EINECS: 202-436-9
1,2,4-trimethylbenzene
Xn, Xi, N; R 10-20-36/37/38-51/53
Warning: 2.6/3; 3.1.I/4, 3.2/2, 3.3/2,
3.8/3
4.1.C/2
<= 2.5%
· Additional information:
For the wording of the listed risk phrases refer to section 16.

4 First-aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.

5 Fire-fighting measures
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol
resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Protective equipment: No special measures required.

6 Accidental release measures
· Person-related safety precautions:
Ensure adequate ventilation
Wear protective equipment. Keep unprotected persons away.
· Measures for environmental protection:
Do not allow to enter sewers/ surface or ground water.
· Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal
binders, sawdust).
Ensure adequate ventilation.

 7 Handling and storage
· Handling:
· Information for safe handling:
Keep away from heat and direct sunlight.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.

8 Exposure controls/personal protection
· Additional information about design of technical facilities:
No further data; see item 7.
· Ingredients with limit values that require monitoring at the workplace:
107-98-2 1-methoxy-2-propanol
WEL Short-term value: 560 mg/m3, 150 ppm
Long-term value: 375 mg/m3, 100 ppm
Sk
· Additional information: The lists valid during the making were used as basis.
· Personal protective equipment:
· General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
· Respiratory protection:
Suitable respiratory protective device recommended.
In case of brief exposure or low pollution use respiratory filter device. In
case of intensive or longer exposure use self-contained respiratory protective
device.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the
substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for
the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times,
rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but
also on further marks of quality and varies from manufacturer to manufacturer.
As the product is a preparation of several substances, the resistance of the
glove material can not be calculated in advance and has therefore to be checked
prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the
protective gloves and has to be observed.
· Eye protection: Tightly sealed goggles

9 Physical and chemical properties
· General Information
Form: Fluid
Colour: According to product specification
Odour: Characteristic
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 150°C
· Flash point:  42°C
· Ignition temperature: 240.0°C
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However, formation
of explosive air/vapour mixtures are
possible.
· Explosion limits:
Lower: 0.6 Vol %
Upper: 7.0 Vol %
· Vapour pressure at 20°C: 1.0 hPa
· Density at 20°C: 0.92854 g/cm3
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Viscosity:
Kinematic at 20°C: 35 s (ISO 6 mm)
· Solvent content:
Organic solvents: 48.1 %
VOC content: 48.1 %
VOC content:
473.6 g/l / 3.95 lb/gl
Solids content: 51.9 % (SC % 1h150 C)

10 Stability and reactivity
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Materials to be avoided:
· Dangerous reactions No dangerous reactions known.
· Dangerous decomposition products: No dangerous decomposition products known.

11 Toxicological information
· Acute toxicity:
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.

12 Ecological information
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous
for water
Do not allow undiluted product or large quantities of it to reach ground water,
water course or sewage system.

13 Disposal considerations
· Product:
· Recommendation
Must not be disposed together with household garbage. Do not allow product to
reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· Land transport ADR/RID (cross-border)
· ADR/RID class: 3 (F1) Flammable liquids.
· Danger code (Kemler): 30
· UN-Number: 1263
· Packaging group: III
· Hazard label 3
· Description of goods: 1263 PAINT (not viscous)
· Tunnel restriction code D/E
· Maritime transport IMDG:
· IMDG Class: 3
· UN Number: 1263
· Label 3
· Packaging group: III
· EMS Number: F-E,S-E
· Marine pollutant: No
· Proper shipping name: PAINT
· Air transport ICAO-TI and IATA-DGR:
· ICAO/IATA Class: 3
· UN/ID Number: 1263
· Label 3
· Packaging group: III
· Proper shipping name: PAINT
· UN "Model Regulation": UN1263, PAINT, 3, III

15 Regulatory information
· Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives /
Ordinance on Hazardous Materials.
· Risk phrases:
10 Flammable.
66 Repeated exposure may cause skin dryness or cracking.
· Safety phrases:
2 Keep out of the reach of children.
23 Do not breathe fumes/aerosol.
24 Avoid contact with skin.
46 If swallowed, seek medical advice immediately and show this container or
label.
51 Use only in well-ventilated areas.
56 Dispose of this material and its container to hazardous or special waste
collection point.
· Special labelling of certain preparations:
Contains 2-butanone oxime, cobalt carboxylate. May produce an allergic
reaction.
· National regulations:
· Technical instructions (air):
Class Share in %
I <= 2,5
· Waterhazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.

16 Other information
This information is based on our present knowledge. However, this shall not
constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship.
· Relevant R-phrases
10 Flammable.
20 Harmful by inhalation.
21 Harmful in contact with skin.

36/37/38 Irritating to eyes, respiratory system and skin.
36/38 Irritating to eyes and skin.
40 Limited evidence of a carcinogenic effect.
41 Risk of serious damage to eyes.
43 May cause sensitisation by skin contact.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
65 Harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement
concerning the International Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
VOC: Volatile Organic Compounds (USA, EU)