SAFETY DATA SHEET
 

 

 

 

SPINNAKER MAHOGANY Rev. 1 february 2011 n° batch 111030
 

1 Identification of the substance/preparation and of the company/undertaking
Trade name:                           SPINNAKER MAHOGANY
Application of the substance: mahogany stain
Manufacturer/Supplier             Cecchi Gustavo & C. srl
Information in case of emergency: 0584/383694

2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
GHS08 health hazard
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
GHS09 environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2 H319 Causes serious eye irritation.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xn; Harmful
R65: Harmful: may cause lung damage if swallowed.
Xi; Irritant
R37: Irritating to respiratory system.
N; Dangerous for the environment
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R10: Flammable.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature data.
· Label elements
· Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials.
· Code letter and hazard designation of product:
Xn Harmful
N Dangerous for the environment
· Hazard-determining components of labelling:
petroleum, nafta, licht aromatisch
· Risk phrases:
10 Flammable.
37 Irritating to respiratory system.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
65 Harmful: may cause lung damage if swallowed.
· Safety phrases:
2 Keep out of the reach of children.
23 Do not breathe fumes/aerosol.
24 Avoid contact with skin.
46 If swallowed, seek medical advice immediately and show this container or label.
51 Use only in well-ventilated areas.
56 Dispose of this material and its container to hazardous or special waste collection point.
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
- petroleum, nafta, licht aromatisch 50-100%
CAS: 64742-95-6
Xn R65
Xi R36/38
N R51/53
R10
Flam. Liq. 3, H226
Asp. Tox. 1, H304
Aquatic Chronic 2, H411
Skin Irrit. 2, H315; Eye Irrit. 2, H319

- 1-methoxy-2-propanol 2.5-10%
CAS: 107-98-2
EINECS: 203-539-1
R10
Flam. Liq. 3, H226

· Additional information:
For the wording of the listed risk phrases refer to section 16.

4 First aid measures
· Description of first aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
No further relevant information available.
· Advice for firefighters
· Protective equipment: No special measures required.

6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage
· Handling:
· Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection
· Additional information about design of technical facilities:
No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
107-98-2 1-methoxy-2-propanol
WEL Short-term value: 560 mg/m3, 150 ppm
Long-term value: 375 mg/m3, 100 ppm
Sk
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective
device.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked
prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the
protective gloves and has to be observed.
· Eye protection:
Tightly sealed goggles

9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: According to product specification
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 120°C
· Flash point: 31°C
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 270°C
· Decomposition temperature: Not determined.
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However,
formation of explosive air/vapour mixtures
are possible.
· Explosion limits:
Lower: 0.7 Vol %
Upper: 7.5 Vol %
· Vapour pressure at 20°C: 5 hPa
· Density at 20°C: 0.9 g/cm3
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Segregation coefficient (n-octanol/
water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· Solvent content:
Organic solvents: 97.2 %
VOC content: 97.2 %
VOC content:
874.4 g/l / 7.30 lb/gl
Solids content: 2.8 %
· Other information No further relevant information available.

10 Stability and reactivity
· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of
the General EU Classification Guidelines for Preparations as issued in the
latest version:
Irritant

12 Ecological information
· Toxicity
· Acquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Toxic for fish
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to
reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· Land transport ADR/RID (cross-border)
· ADR/RID class: 3 (F1) Flammable liquids.
· Danger code (Kemler): 30
· UN-Number: 1993
· Packaging group: III
· Hazard label 3
· Special marking: Symbol (fish and tree)
· UN proper shipping name: 1993 FLAMMABLE LIQUID, N.O.S. (not viscous)
(petroleum, nafta, licht aromatisch, 1-METHOXY-2-
PROPANOL), ENVIRONMENTALLY HAZARDOUS
· Tunnel restriction code D/E
· Maritime transport IMDG:
· IMDG Class: 3
· UN Number: 1993
· Label 3
· Packaging group: III
· EMS Number: F-E,S-E
· Marine pollutant: No
· Proper shipping name: FLAMMABLE LIQUID, N.O.S. (petroleum, nafta, licht aromatisch, 1-METHOXY-2-PROPANOL)
· Air transport ICAO-TI and IATA-DGR:
· ICAO/IATA Class: 3
· UN/ID Number: 1993
· Label 3
· Packaging group: III
· Proper shipping name: FLAMMABLE LIQUID, N.O.S. (petroleum, nafta, licht aromatisch, 1-METHOXY-2-PROPANOL)
· UN "Model Regulation":
UN1993, BRANDBARE VLOEISTOF, N.E.G. (niet viskeus) (petroleum, nafta, licht aromatisch, 1-METHOXY-2-PROPANOL), MILIEUGEVAARLIJK, 3, III
· Special precautions for user Warning: Flammable liquids.
· Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· National regulations:
· Technical instructions (air):
· Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.
· Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not
constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship.
· Relevant phrases
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
R10 Flammable.
R36/38 Irritating to eyes and skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement
concerning the International Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
VOC: Volatile Organic Compounds (USA, EU)