SAFETY DATA SHEET
 

 

 

 

SPINNAKER POLYURETHANE Revision 1 june 2012 - n° batch 173-AB
 

1. IDENTIFICATION
Name of the product:              Spinnaker Polyurethane
Chemical family:                      Clear resin for general marine use
Distruted by:                           Cecchi Gustavo & C. srl
Emergency telephone numbers: 0584/383694

2. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous ingredients
Conc. CAS EINECS Symbols/Risk phrases
- mineral spirit.                      1 - 10% 64742-48-9 265-150-3 R10 Xn;R65
- White Spirit D40/ BAS 40     20 - 30% 64742-48-9 265-150-3 Xn
- Benzene                               0-0.5% 71-43-2 F; R11 Carc Cat 1; R45 Muta Cat 2;
R46 T; R48/23/24/25 Xn; R65 Xi; R36/38 200-753-7
- white spirit                           1 - 10% 64742-82-1 265-185-4 R10 N;R51/53 Xn;R65 R66
- Aromatic Hydrocarbon solvent 1 - 10% 64742-95-6 265-199-0 Xn;R65

3. HAZARDS IDENTIFICATION
Main hazards Flammable Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment. Harmful: may cause lung damage if swallowed. Repeated
exposure may cause skin dryness or cracking. Vapours may cause drowsiness and
dizziness.

4. FIRST AID MEASURES
Skin contact May cause irritation to skin. Wash off immediately with plenty of soap and water.
Remove contaminated clothing. Seek medical attention if irritation or symptoms persist.
Eye contact May cause irritation to eyes. Rinse immediately with plenty of water for 15 minutes
holding the eyelids open. Seek medical attention if irritation or symptoms persist.
Inhalation Inhalation may cause coughing, tightness of the chest and irritation of the respiratory
system. Move the exposed person to fresh air. Seek medical attention.
Ingestion Ingestion may cause nausea and vomiting. Seek medical attention if irritation or
symptoms persist.
General information In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).

5. FIRE FIGHTING MEASURES
Extinguishing media Alcohol resistant foam. Carbon dioxide (CO2) Dry chemical. Sand.
Fire hazards Burning produces irritating, toxic and obnoxious fumes.
Protective equipment Wear suitable respiratory equipment when necessary.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions Ensure adequate ventilation of the working area. Evacuate personnel to a safe area.
Eliminate all sources of ignition. Wear suitable protective equipment.
Environmental precautions Do not allow product to enter drains. Prevent further spillage if safe.
Clean up methods Absorb with inert, absorbent material. Transfer to suitable, labelled containers for
disposal. Clean spillage area thoroughly with plenty of water.

7. HANDLING AND STORAGE
Handling Avoid contact with eyes and skin. Ensure adequate ventilation of the working area.
Keep away from sources of ignition - No smoking.
Storage Keep in a cool, dry, well ventilated area. Keep containers tightly closed. Store in
correctly labelled containers. Store at temperatures between 5 °C and 25 °C.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure limits
Benzene WEL 8-hr limit ppm: 1
WEL 15 min limit ppm: -
WEL 8-hr limit mg/m3: -
WEL 15 min limit mg/m3: -
Engineering measures Ensure adequate ventilation of the working area.
Respiratory protection Wear suitable respiratory equipment when necessary.
Hand protection Chemical resistant gloves (PVC)
Eye protection Approved safety goggles.
Protective equipment Wear chemical protective clothing.

9. PHYSICAL AND CHEMICAL PROPERTIES
Description Liquid.
Colour Amber.
Odour Aromatic.
Flash point 38°C
Relative density 0.92
Water solubility immiscible in water.
VOC (Volatile organic
compounds)
0.430 Kgs/Lt.

10. STABILITY AND REACTIVITY
Stability Stable under normal conditions.
Conditions to avoid Heat, sparks and open flames.
Materials to avoid Oxidising agents.

11. TOXICOLOGICAL INFORMATION
Toxicological information
Benzene Oral Mouse LD50 = 4700 mg/kg
Oral Rat LD50 = 6400 mg/kg
Dermal Rabbit LD50 = >9400 uL/kg
Inhalation Rat LC50/7H h = 10000 ppm
Dermal Guinea Pig LD50 = >9400 uL/kg
Aromatic Hydrocarbon solvent Oral Rat LD50 = 8400 mg/kg
Acute toxicity Harmful if swallowed. No data is available on this product.

12. ECOLOGICAL INFORMATION
Ecotoxicity No data is available on this product.

13. DISPOSAL CONSIDERATIONS
General information Dispose of in compliance with all local and national regulations.

14. TRANSPORT INFORMATION
ADR/RID
UN 1263 Packing group III
Class 3 Hazard ID 33
Proper Shipping
Name
PAINT .
IMDG
UN 1263 Packing group III
Class 3 Marine pollutant NO
EmS Code F-E S-E
IATA
UN 1263 Packing group III
Class 3 Subsidiary risk -
Packing Instruction
(Cargo)
310 Maximum quantity 220 L
Packing Instruction
(Passenger)
309 Maximum quantity 60 L
Print

15. REGULATORY INFORMATION
Labelling The product is classified in accordance with 67/548/EEC.
Risk phrases
R10 - Flammable.
R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R65 - Harmful: may cause lung damage if swallowed.
R66 - Repeated exposure may cause skin dryness or cracking.
R67 - Vapours may cause drowsiness and dizziness.
Safety phrases
S1/2 - Keep locked up and out of the reach of children.
S13 - Keep away from food, drink and animal feedingstuffs.
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show
this container or label.
S23 - Do not breathe gas/fumes/vapour/spray.
S24/25 - Avoid contact with skin and eyes.
S36/37 - Wear suitable protective clothing and gloves.
S43 - In case of fire, use [].
S46 - If swallowed, seek medical advice immediately and show this container or label.
S61 - Avoid release to the environment. Refer to special instructions/safety data sheets.

16. OTHER INFORMATION
Text of risk phrases in
Section 2
R10 - Flammable.
R11 - Highly flammable.
R36/38 - Irritating to eyes and skin.
R45 - May cause cancer.
R46 - May cause heritable genetic damage.
R48/23/24/25 - Toxic: danger of serious damage to health by prolonged exposure
through inhalation, in contact with skin and if swallowed.
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R65 - Harmful: may cause lung damage if swallowed.
R66 - Repeated exposure may cause skin dryness or cracking.

Further information
The information contained in this safety data sheet is provided in accordance with the requirements of the Chemical (Hazard Information & packaging) Regulations. The information contained in this safety data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be constructed as any guarantee of technical perforamnce or suitability for particular applications.