1. IDENTIFICATION
Name of the product:              Spinnaker Polyurethane
Chemical family:                      Clear resin for general marine use
Distruted by:                           Cecchi Gustavo & C. srl
Emergency telephone numbers: 0584/383694

SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical Hazards Flam. Liq. 3 - H226
Human health EUH066
Environment Not classified.
Classification (1999/45/EEC) R10, R66.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
2.2. Label elements
Label In Accordance With (EC) No. 1272/2008

GHS02

Signal Word Warning
Hazard Statements
H226 Flammable liquid and vapour.
Precautionary Statements
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Supplementary Precautionary Statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P370+378 In case of fire: Use foam, carbon dioxide, dry powder or water fog for
extinction.
P403+235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to …
Supplemental label information
EUH066 Repeated exposure may cause skin dryness or cracking.
EUH208 Contains ETHYL METHYL KETOXIME. May produce an allergic reaction.
2.3. Other hazards

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
ETHYL METHYL KETOXIME <0.5
CAS-No.: 96-29-7 EC No.: 202-496-6
Classification (67/548/EEC)
Carc. Cat. 3;R40
Xn;R21
R43
Xi;R41
Classification (EC 1272/2008)
Acute Tox. 4 - H312
Eye Dam. 1 - H318
Skin Sens. 1 - H317
Carc. 2 - H351
White Spirit, D40 <0.1% Benzene 40-60%
CAS-No.: 64742-48-9 EC No.:
Classification (67/548/EEC)
Xn;R65.
R10,R66.
Classification (EC 1272/2008)
Flam. Liq. 3 - H226
EUH066
Asp. Tox. 1 - H304
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown are in accordance with the latest EC Directives.

SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. Get medical attention if any discomfort continues.
Ingestion
Immediately rinse mouth and provide fresh air. Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach
vomit doesn't enter the lungs. Get medical attention immediately!
Skin contact
Immediately remove contaminated clothing. Wash off promptly and flush contaminated skin with water. Promptly remove clothing if soaked
through and flush skin with water. Get medical attention if any discomfort continues.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Get medical attention promptly if symptoms occur after washing.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed

SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Fire can be extinguished using: Foam, carbon dioxide or dry powder. Dry chemicals, sand, dolomite etc.
5.2. Special hazards arising from the substance or mixture
Specific hazards
When heated and in case of fire, irritating vapours/gases may be formed. In case of fire, toxic gases may be formed (COx, NOx).
5.3. Advice for firefighters
Special Fire Fighting Procedures
Use pressurised air mask if product is involved in a fire. Cool containers exposed to flames with water until well after the fire is out.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.

SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate
regulatory body.
6.3. Methods and material for containment and cleaning up
Keep combustibles away from spilled material. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb
in vermiculite, dry sand or earth and place into containers.
6.4. Reference to other sections
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use
approved respirator if air contamination is above accepted level.
7.2. Conditions for safe storage, including any incompatibilities
Flammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container in a dry, cool and
well-ventilated place. Keep in original container. Avoid contact with oxidising agents. Store in closed original container at temperatures
between 5°C and 25°C.
Storage Class
Flammable liquid storage.
7.3. Specific end use(s)

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
8.2. Exposure controls
Protective equipment
Process conditions
Provide eyewash station.
Engineering measures
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not
exceeded. All handling to take place in well-ventilated area.
Respiratory equipment
Wear mask supplied with: Gas cartridge suitable for organic substances.
Hand protection
Use protective gloves made of: Neoprene. Nitrile. Rubber (natural, latex).
Eye protection
Wear splash-proof eye goggles to prevent any possibility of eye contact.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly
remove any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Coloured liquid.
Colour Amber.
Odour Mild.
Solubility Immiscible with water
Initial boiling point and boiling range
(°C)
160-200 760 mm Hg
Relative density 0.92
Flash point (°C) 40 CC (Closed cup).
Flammability Limit - Upper(%) 0.8
9.2. Other information
Volatile By Vol. (%) 51
Volatile Organic Compound (VOC) 420 g/litre

SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
10.2. Chemical stability
No particular stability concerns.
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
Avoid heat, flames and other sources of ignition. Avoid contact with strong oxidisers.
10.5. Incompatible materials
10.6. Hazardous decomposition products
Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.

SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
General information
Prolonged and repeated contact with solvents over a long period may lead to permanent health problems.
Inhalation
In high concentrations, vapours may irritate throat and respiratory system and cause coughing. Harmful by inhalation.
Ingestion
Gastrointestinal symptoms, including upset stomach.
Skin contact
Harmful in contact with skin. Irritating to skin.
Eye contact
Irritating and may cause redness and pain.

SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
The product is not expected to be hazardous to the environment.
12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects

SECTION 13: DISPOSAL CONSIDERATIONS
General information
Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority.
13.1. Waste treatment methods

SECTION 14: TRANSPORT INFORMATION
14.1. UN number
UN No. (ADR/RID/ADN) 1263
UN No. (IMDG) 1263
UN No. (ICAO) 1263
14.2. UN proper shipping name
Proper Shipping Name PAINT
14.3. Transport hazard class(es)
ADR/RID/ADN Class 3
ADR/RID/ADN Class Class 3: Flammable liquids.
ADR Label No. 3
IMDG Class 3
ICAO Class/Division 3
Transport Labels
FLAMMABLE
LIQUID
3
14.4. Packing group
ADR/RID/ADN Packing group III
IMDG Packing group III
ICAO Packing group III
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
EMS F-E, S-E
Emergency Action Code •3YE
Hazard No. (ADR) 30
Tunnel Restriction Code (D/E)
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
15.2. Chemical Safety Assessment

SECTION 16: OTHER INFORMATION
Revision Date 30/10/2013
Revision 4
Supersedes date 21/06/2013
Risk Phrases In Full
R10 Flammable.
R21 Harmful in contact with skin.
R40 Limited evidence of a carcinogenic effect.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
Hazard Statements In Full
EUH066 Repeated exposure may cause skin dryness or cracking.
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H351 Suspected of causing cancer.