1. IDENTIFICATION
Name of the product: Spinnaker Polyurethane 2 Bicomponents comp.A
Chemical family: Clear resin for general marine use
Distruted by: Cecchi Gustavo & C. srl
Emergency telephone numbers: 0584/383694
2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
GHS07
Eye Irrit. 2 H319 Causes serious eye irritation.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xi; Irritant
R36: Irritating to eyes.
R10: Flammable.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General
Classification guideline for preparations of the EU" in the latest valid
version.
· Classification system:
The classification is according to the latest editions of the EU-lists, and
extended by company and literature data.
· Label elements
· Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives /
Ordinance on Hazardous Materials.
· Code letter and hazard designation of product:
Xi Irritant
· Risk phrases:
10 Flammable.
36 Irritating to eyes.
· Safety phrases:
2 Keep out of the reach of children.
23 Do not breathe fumes/aerosol.
25 Avoid contact with eyes.
26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
46 If swallowed, seek medical advice immediately and show this container or
label.
51 Use only in well-ventilated areas.
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description:
Resin mixture
Solvent mixture with additives
· Dangerous components:
2-methoxy-1-methylethyl acetate 50-100%
CAS: 108-65-6
EINECS: 203-603-9
Xi R36
R10
Flam. Liq. 3, H226
Eye Irrit. 2, H319
Xylene <= 2.5%
CAS: 1330-20-7
EINECS: 215-535-7
Xn R20/21
Xi R38
R10
Flam. Liq. 3, H226
Acute Tox. 4, H312; Acute Tox. 4, H332;
Skin Irrit. 2, H315
2-methoxypropyl acetate <= 2.5%
CAS: 70657-70-4
EINECS: 274-724-2
T Repr. Cat. 2 R61
Xi R37
R10
Flam. Liq. 3, H226
Repr. 1B, H360D
STOT SE 3, H335
· Additional information:
For the wording of the listed risk phrases refer to section 16.
4 First aid measures
· Description of first aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist,
consult a doctor.
· After swallowing: Seek medical treatment.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol
resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
No further relevant information available.
· Advice for firefighters
· Protective equipment: Wear fully protective suit.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal
binders, sawdust).
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
· Handling:
· Precautions for safe handling
Keep away from heat and direct sunlight.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store only in the original receptacle.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
· Additional information about design of technical facilities:
No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
108-65-6 2-methoxy-1-methylethyl acetate
WEL Short-term value: 548 mg/m3, 100 ppm
Long-term value: 274 mg/m3, 50 ppm
Sk
1330-20-7 xylene
WEL Short-term value: 441 mg/m3, 100 ppm
Long-term value: 220 mg/m3, 50 ppm
Sk; BMGV
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In
case of intensive or longer exposure use self-contained respiratory protective
device.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the
substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for
the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times,
rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but
also on further marks of quality and varies from manufacturer to manufacturer.
As the product is a preparation of several substances, the resistance of the
glove material can not be calculated in advance and has therefore to be checked
prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the
protective gloves and has to be observed.
· Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: According to product specification
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 146°C
· Flash point: 42°C
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 315°C
· Decomposition temperature: Not determined.
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However,
formation of explosive air/vapour mixtures
are possible.
· Explosion limits:
Lower: 1.5 Vol %
Upper: 10.8 Vol %
· Vapour pressure at 20°C: 3.4 hPa
· Density at 20°C: 1.07 g/cm3
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Segregation coefficient (n-octanol/
water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic at 20°C: 40 s (ISO 4 mm)
· Solvent content:
Organic solvents: 60.4 %
VOC content: 60.4 %
VOC content:
646.3 g/l / 5.39 lb/gl
Solids content: 39.3 % (VB% 1h150 C)
· Other information No further relevant information available.
10 Stability and reactivity
· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
108-65-6 2-methoxy-1-methylethyl acetate
Oral LD50 8532 mg/kg (rat)
Inhalative LC50/4 h 35.7 mg/l (rat)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: Irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of
the General EU Classification Guidelines for Preparations as issued in the
latest version:
Irritant
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous
for water
Do not allow undiluted product or large quantities of it to reach ground water,
water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to
reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· UN-Number
· ADR, IMDG, IATA UN1263
· UN proper shipping name
· ADR 1263 PAINT (not viscous)
· IMDG, IATA PAINT
· Transport hazard class(es)
· ADR
· Class 3 (F1) Flammable liquids.
· Label 3
· IMDG, IATA
· Class 3 Flammable liquids.
· Label 3
· Packing group
· ADR, IMDG, IATA III
· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 30
· EMS Number: F-E,S-E
· Transport in bulk according to Annex
II of MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Tunnel restriction code D/E
· UN "Model Regulation": UN1263, PAINT (not viscous), 3, III
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the
substance or mixture
· National regulations:
· Technical instructions (air):
· Waterhazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
· Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not
constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship.
· Relevant phrases
H226 Flammable liquid and vapour.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H360D May damage the unborn child.
R10 Flammable.
R20/21 Harmful by inhalation and in contact with skin.
R36 Irritating to eyes.
R37 Irritating to respiratory system.
R38 Irritating to skin.
R61 May cause harm to the unborn child.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement
concerning the International Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
ICAO: International Civil Aviation Organization
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Further information
The information contained in this safety data sheet is provided in accordance with the requirements of the Chemical (Hazard Information & packaging) Regulations. The information contained in this safety data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be constructed as any guarantee of technical perforamnce or suitability for particular applications.
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