1. IDENTIFICATION
Name of the product:              Spinnaker Polyurethane 2 Bicomponents comp.B
Chemical family:                      Clear resin for general marine use
Distruted by:                           Cecchi Gustavo & C. srl
Emergency telephone numbers: 0584/383694

2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
GHS07
Eye Irrit. 2 H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xn; Harmful
R20: Harmful by inhalation.
Xi; Irritant
R36: Irritating to eyes.
Xi; Sensitising
R43: May cause sensitisation by skin contact.
R10: Flammable.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General
Classification guideline for preparations of the EU" in the latest valid
version.
· Classification system:
The classification is according to the latest editions of the EU-lists, and
extended by company and literature data.
· Label elements
· Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives /
Ordinance on Hazardous Materials.
· Code letter and hazard designation of product:
Xn Harmful
· Hazard-determining components of labelling:
Alifatische polyisocyanaat.
Alifatic polyisocyanate
Isoforondiisocyanaat
· Risk phrases:
10 Flammable.
20 Harmful by inhalation.
36 Irritating to eyes.
43 May cause sensitisation by skin contact.
· Safety phrases:
2 Keep out of the reach of children.
7 Keep container tightly closed.
23 Do not breathe fumes/aerosol.
25 Avoid contact with eyes.
26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
46 If swallowed, seek medical advice immediately and show this container or
label.
51 Use only in well-ventilated areas.
56 Dispose of this material and its container to hazardous or special waste
collection point.
· Special labelling of certain preparations:
Contains isocyanates. See information supplied by the manufacturer
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Isocyanate resin in organic solvent
· Dangerous components:
- Alifatische polyisocyanaat. Alifatic polyisocyanate 25-50%
CAS: 28182-81-2
Xi R43
Flam. Liq. 3, H226
Skin Sens. 1, H317
- acetato di 1-metil-2-metossietile 25-50%
CAS: 108-65-6
EINECS: 203-603-9
Xi R36
R10
Flam. Liq. 3, H226
Eye Irrit. 2, H319
- Isoforondiisocyanaat 10-25%
CAS: 53880-05-0
Xi R43
Skin Sens. 1, H317
- xilene 2,5-10%
CAS: 1330-20-7
EINECS: 215-535-7
Xn R20/21
Xi R38
R10
Flam. Liq. 3, H226
Acute Tox. 4, H312; Acute Tox. 4, H332;
Skin Irrit. 2, H315
- etilbenzene <= 2,5%
CAS: 100-41-4
EINECS: 202-849-4
Xn R20
F R11
Flam. Liq. 2, H225
Acute Tox. 4, H332
- esametilen-1,6-diisocianato <= 2,5%
CAS: 822-06-0
EINECS: 212-485-8
T R23
Xn R42/43
Xi R36/37/38
Acute Tox. 3, H331
Resp. Sens. 1, H334
Skin Irrit. 2, H315; Eye Irrit. 2, H319;
Skin Sens. 1, H317; STOT SE 3, H335
· Additional information:
For the wording of the listed risk phrases refer to section 16.

4 First aid measures
· Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical
observation for at least 48 hours after the accident.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for
transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist,
consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol
resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
No further relevant information available.
· Advice for firefighters
· Protective equipment: Mouth respiratory protective device.

6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal
binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage
· Handling:
· Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store only in the original receptacle.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection
· Additional information about design of technical facilities:
No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
108-65-6 2-methoxy-1-methylethyl acetate
WEL Short-term value: 548 mg/m3, 100 ppm
Long-term value: 274 mg/m3, 50 ppm
Sk
1330-20-7 xylene
WEL Short-term value: 441 mg/m3, 100 ppm
Long-term value: 220 mg/m3, 50 ppm
Sk; BMGV
100-41-4 ethylbenzene
WEL Short-term value: 552 mg/m3, 125 ppm
Long-term value: 441 mg/m3, 100 ppm
822-06-0 hexamethylene-di-isocyanate
WEL Short-term value: 0.07 mg/m3
Long-term value: 0.02 mg/m3
Sen; as -NCO
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In
case of intensive or longer exposure use self-contained respiratory protective
device.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the
substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for
the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times,
rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but
also on further marks of quality and varies from manufacturer to manufacturer.
As the product is a preparation of several substances, the resistance of the
glove material can not be calculated in advance and has therefore to be checked
prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the
protective gloves and has to be observed.
· Eye protection:
Tightly sealed goggles

9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: According to product specification
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 145°C
· Flash point: 38°C
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 315°C
· Decomposition temperature: Not determined.
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However,
formation of explosive air/vapour mixtures
are possible.
· Explosion limits:
Lower: 1.5 Vol %
Upper: 10.8 Vol %
· Vapour pressure at 20°C: 3.4 hPa
· Density at 20°C: 1.05165 g/cm3 (ISO 2811)
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Segregation coefficient (n-octanol/
water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic at 20°C: 20 s (DIN 53211/4)
· Solvent content:
Organic solvents: 38.9 %
VOC content: 38.9 %
VOC content:
415.4 g/l / 3.47 lb/gl
Solids content: 61.1 % (VB% 1h 150C)
· Other information No further relevant information available.

10 Stability and reactivity
· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
1330-20-7 xylene
Oral LD50 4300 mg/kg (rat)
Dermal LD50 2000 mg/kg (rabbit)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: Irritating effect.
· Sensitization: Sensitization possible through skin contact.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of
the General EU Classification Guidelines for Preparations as issued in the
latest version:
Harmful
Irritant

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to
reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· UN-Number
· ADR, IMDG, IATA UN1263
· UN proper shipping name
· ADR 1263 PAINT (not viscous)
· IMDG, IATA PAINT
· Transport hazard class(es)
· ADR
· Class 3 (F1) Flammable liquids.
· Label 3
· IMDG, IATA
· Class 3 Flammable liquids.
· Label 3
· Packing group
· ADR, IMDG, IATA III
· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 30
· EMS Number: F-E,S-E
· Transport in bulk according to Annex
II of MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Tunnel restriction code D/E
· UN "Model Regulation": UN1263, PAINT (not viscous), 3, III

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the
substance or mixture
· National regulations:
· Technical instructions (air):
Class Share in %
I <= 2,5
· Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.
· Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not
constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship.
· Relevant phrases
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if
inhaled.
H335 May cause respiratory irritation.
R10 Flammable.
R11 Highly flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R23 Toxic by inhalation.
R36 Irritating to eyes.
R36/37/38 Irritating to eyes, respiratory system and skin.
R38 Irritating to skin.
R42/43 May cause sensitisation by inhalation and skin contact.
R43 May cause sensitisation by skin contact.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement
concerning the International Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
ICAO: International Civil Aviation Organization
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Further information
The information contained in this safety data sheet is provided in accordance with the requirements of the Chemical (Hazard Information & packaging) Regulations. The information contained in this safety data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be constructed as any guarantee of technical perforamnce or suitability for particular applications.