|
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY
Product name: Spinnaker Standard Yacht Varnish
Name : transparent varnish for marine use
Supplier: Cecchi Gustavo & C. srl.
Emergency telephone number : 0584/383694
SECTION 2: Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
R10-66: Flammable. Repeated exposure may cause skin dryness or cracking.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General
Classification guideline for preparations of the EU" in the latest valid version.
At long or repeated contact with skin it may cause dermatitis due to the
degreasing effect of the solvent.
· Classification system:
The classification is according to the latest editions of the EU-lists, and
extended by company and literature data.
· Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
 |
|
| GHS02 |
|
· Signal word Warning
· Hazard statements
H226 Flammable liquid and vapour.
· Precautionary statements
P101 If medical advice is needed, have product container or label at
hand.
P102 Keep out of reach of children.
P103 Read label before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No
smoking.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P280 Wear protective gloves/protective clothing/eye protection/face
protection.
P240 Ground/bond container and receiving equipment.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
P501 Dispose of contents/container in accordance with local/regional/
national/international regulations.
· Additional information:
EUH066 Repeated exposure may cause skin dryness or cracking.
Contains 2-butanone oxime,carboxylate. May cause an allergic reaction.
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
naphta (petroleum), hydrotreated heavy 25-50%
CAS: 64742-48-9 EINECS: 265-150-3
Flam. Liq. 3, H226 Asp. Tox. 1, H304
-xilene <=2,5%
CAS: 1330-20-7 EINECS: 215-535-7
Flam. Liq. 3, H226
Acute Tox. 4, H312; Acute Tox. 4, H332; Skin
Irrit. 2, H315
- A mixture of branched and linear C7-C9 alkyl 3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethyl-ethyl)-4-hydroxyphenyl]propionates <=2,5%
CAS: 127519-17-9 ELINCS: 407-000-3
Aquatic Chronic 2, H411
-2-butanone ossima <=2,5%
CAS: 96-29-7 EINECS: 202-496-6
Carc. 2, H351
Eye Dam. 1, H318
Acute Tox. 4, H312; Skin Sens. 1, H317
4-(1,1,3,3-tetrametilbutil)fenolo <=2,5%
CAS: 140-66-9 EINECS: 205-426-2
-4-terz-butilfenolo <=2,5%
CAS: 98-54-4 EINECS: 202-679-0
Aquatic Chronic 2, H411
Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335
-bis(2-etilesanoato) di cobalto <=2,5
CAS: 136-52-7 EINECS: 205-250-6
Aquatic Acute 1, H400; Aquatic Chronic 1, H410
Acute Tox. 4, H302
· SVHC
140-66-9 4-(1,1,3,3-tetrametilbutil)fenolo
SECTION 4: First aid measures
· Description of first aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5: Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol
resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
No further relevant information available.
· Advice for firefighters
· Protective equipment: No special measures required.
SECTION 6: Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal
binders, sawdust).
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
· Handling:
· Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities:
No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
1330-20-7 xylene
WEL Short-term value: 441 mg/m3, 100 ppm
Long-term value: 220 mg/m3, 50 ppm
Sk; BMGV
· Ingredients with biological limit values:
1330-20-7 xylene
BMGV 650 mmol/mol creatinine
Medium: urine
Sampling time: post shift
Parameter: methyl hippuric acid
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In
case of intensive or longer exposure use self-contained respiratory protective
device.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the
substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for
the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times,
rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but
also on further marks of quality and varies from manufacturer to manufacturer.
As the product is a preparation of several substances, the resistance of the
glove material can not be calculated in advance and has therefore to be checked
prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the
protective gloves and has to be observed.
· Eye protection:
Tightly sealed goggles
SECTION 9: Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: According to product specification
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value at 20 °C: 7
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 150 °C
· Flash point: 36 °C
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature:
Decomposition temperature: Not determined.
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However, formation
of explosive air/vapour mixtures are
possible.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure: Not determined.
· Density at 20 °C: 0.919 g/cm3
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/
water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic at 20 °C: 40 s (ISO 6 mm)
· Solvent content:
Organic solvents: 41.2 %
VOC content: 41.2 %
VOC content:
379.0 g/l / 3.16 lb/gl
SECTION 10: Stability and reactivity
· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.
SECTION 11: Toxicological information
· Information on toxicological effects
· Acute toxicity:
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.
SECTION 12: Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous
for water
Do not allow undiluted product or large quantities of it to reach ground water,
water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to
reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
SECTION 14: Transport information
· UN-Number
· ADR, IMDG, IATA UN1263
· UN proper shipping name
· ADR 1263 PAINT (not viscous)
· IMDG, IATA PAINT
· Transport hazard class(es)
· ADR
· Class 3 (F1) Flammable liquids.
· Label 3
· IMDG, IATA
· Class 3 Flammable liquids.
· Label 3
· Packing group
· ADR, IMDG, IATA III
· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 30
· EMS Number: F-E,S-E
· Transport in bulk according to Annex
II of MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 5L
· Transport category 3
· Tunnel restriction code D/E
· UN "Model Regulation": UN1263, PAINT (not viscous), 3, III
SECTION 15: Regulatory information
· Safety, health and environmental regulations/legislation specific for the
substance or mixture
· National regulations:
· Technical instructions (air):
Class Share in %
I <= 2,5
· Waterhazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57
140-66-9 4-(1,1,3,3-tetramethylbutyl)phenol
· Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not
constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship.
· Relevant phrases
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organization
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement
concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU) |
