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1. DESIGNATION OF PRODUCT AND COMPANY
Trade name C-SYSTEMS STEEL BLUE component A
Chemical description: Epoxy resin based compound.
Supplier: CECCHI GUSTAVO & C. – Via Coppino 253 Viareggio (LUCCA) Italy.
Emergency telephone number: 0039/584 383692 fax 0039/584 395182
2. Hazards identification
2.1 Classification of the substance or mixture
Classification (67/548/EEC, 1999/45/EC)
Sensitising R43: May cause sensitization by skin contact.
Irritant R36/38: Irritating to eyes and skin.
Dangerous for the environment R52/53: Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)
Labelling according to EC Directives (1999/45/EC)
Hazard pictograms :
Irritant
R-phrase(s) : R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S-phrase(s) : S24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37 Wear suitable gloves.
S60 This material and its container must be disposed of as hazardous waste.
Hazardous components which must be listed on the label:
• 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) and epoxy resin (number
average molecular weight <= 700)
• 28064-14-4 Phenol, polymer with formaldehyde, oxiranylmethyl ether
• 16096-31-4 1,6-bis(2,3-epoxypropoxy)hexane
• 68081-84-5 Oxirane, mono[(C10-16-alkyloxy)methyl] derivs.
3. Composition/information on ingredients
3.2 Mixtures
Chemical nature : Filled Epoxy Resin
Hazardous components
- reaction product: bisphenol-A- (epichlorhydrin) and epoxy resin (number average molecular weight <= 700) Concentration >= 12,5 - < 20
N. CAS N. CE Registration number 25068-38-6 01- 2119456619- 26
Classificazione (67/548/CEE) Xi; R36/38 R43 N; R51-R53
Classification (REGULATION (CE) N. 1272/2008) Eye Irrit. 2; H319 Skin Irrit. 2; H315 Skin Sens. 1; H317
Aquatic Chronic 2; H411
- Phenol, polymer with formaldehyde, oxiranylmethyl ether
N. CAS N. CE 28064-14-4 Concentration [%] >= 5 - < 7
Classificazione (67/548/CEE) Xi; R36/38 R43 N; R51/53
Classification (REGULATION (CE) N. 1272/2008) Skin Irrit. 2; H315 Eye Irrit. 2; H319 Skin Sens. 1; H317 Aquatic Chronic 2; H411
- Quartz (SiO2) Concentration [%] >= 3 - < 5
N. CAS N. CE Registration number 14808-60-7 238-878-4
Classificazione (67/548/CEE) Xn; R48/20
Classification (REGULATION (CE) N. 1272/2008)
STOT RE 2; H373
- 1,6-bis(2,3- epoxypropoxy)hexane Concentration [%] >= 1 - < 2,5
N. CAS N. CE Registration number 16096-31-4 240-260-401- 2119463471-41
Classificazione (67/548/CEE) Xi; R36/38 Xi; R43 N; R52/53
Classification (REGULATION (CE) N. 1272/2008) Skin Irrit. 2; H315 Eye Irrit. 2; H319 Skin Sens. 1; H317 Aquatic Chronic 3; H412
- Oxirane, mono[(C10-16-alkyloxy)methyl] derivs. Concentration [%] >= 1 - < 2,5
N. CAS N. CE Registration number 68081-84-5 268-358-2 /
Classificazione (67/548/CEE) Xi; R36/38 Xi; R43 N; R51/53
Classification (REGULATION (CE) N. 1272/2008) Skin Irrit. 2; H315 Eye Irrit. 2; H319 Skin Sens. 1; H317 Aquatic Chronic 2; H411
For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.
4. First aid measures
4.1 Description of first aid measures
General advice : Do not leave the victim unattended.
If inhaled : If unconscious place in recovery position and seek medical advice.
If symptoms persist, call a physician.
In case of skin contact : Do not wash off with: Cleansing agents, acidic.
Do NOT use solvents or thinners.
Before washing use a dry brush to remove dust from skin.
In case of eye contact : Remove contact lenses.
Protect unharmed eye.
If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
5. Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media : Foam
5.2 Special hazards arising from the substance or mixture
Specific hazards during firefighting
: Burning produces irritant fumes.
5.3 Advice for firefighters
Special protective equipment for firefighters
: Wear self contained breathing apparatus for fire fighting if
necessary.
Further information : Standard procedure for chemical fires.
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions : Refer to protective measures listed in sections 7 and 8.
Evacuate personnel to safe areas.
Use personal protective equipment.
6.2 Environmental precautions
Environmental precautions : If the product contaminates rivers and lakes or drains inform
respective authorities.
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up : Wipe up with absorbent material (e.g. cloth, fleece).
Keep in suitable, closed containers for disposal.
6.4 Reference to other sections
Only qualified personnel equipped with suitable protective equipment may intervene.
7. Handling and storage
7.1 Precautions for safe handling
Advice on safe handling : For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the application area.
Advice on protection against fire and explosion
: Normal measures for preventive fire protection.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
: Electrical installations / working materials must comply with the technological safety standards.
Advice on common storage : No materials to be especially mentioned.
Other data : No decomposition if stored and applied as directed.
8. Exposure controls/personal protection
8.1 Control parameters
Components CAS-No. Value Control
parameters Update Basis
zircon 14940-68-
2
TWA 5 mg/m3 2005-04-06 GB EH40
Further
information
:
Zirconium
STEL 10 mg/m3 2005-04-06 GB EH40
Further
information
:
Zirconium
Quartz
(SiO2)
14808-60-
7
TWA 0,1 mg/m3 2007-08-01 GB EH40
Further information
: 15: For the purposes of these limits, respirable dust and inhalable dust are those fractions of
airborne dust which will be collected when sampling is undertaken in accordance with the
methods described in MDHS14/3 General methods for sampling and gravimetric analysis of
respirable and inhalable dust
The COSHH definition of a substance hazardous to health includes dust of any kind when
present at a concentration in air equal to or greater than 10 mg.m-3 8-hour TWA of inhalable
dust or 4 mg.m-3 8-hour TWA of respirable dust. This means that any dust will be subject to
COSHH if people are exposed above these levels. Some dusts have been assigned specific
WELs and exposure to these must comply with the appropriate limit.
Most industrial dusts contain particles of a wide range of sizes. The behaviour, deposition and
fate of any particular particle after entry into the human respiratory system and the body
response that it elicits, depend on the nature and size of the particle. HSE distinguishes two
size fractions for limit-setting purposes termed 'inhalable' and 'respirable'.
Inhalable dust approximates to the fraction of airborne material that enters the nose and mouth
during breathing and is therefore available for deposition in the respiratory tract. Respirable
dust approximates to the fraction that penetrates to the gas exchange region of the lung. Fuller
definitions and explanatory material are given in MDHS14/3.
Where dusts contain components that have their own assigned WEL, all the relevant limits
should be complied with.
Where no specific short-term exposure limit is listed, a figure three times the long-term
exposure should be used
HSC/E plans to review the limit values for this substance.
TWA 6 mg/m3 2005-04-06 GB EH40
Further
information
: 15: For the purposes of these limits, respirable dust and inhalable dust are those fractions of
airborne dust which will be collected when sampling is undertaken in accordance with the
methods described in MDHS14/3 General methods for sampling and gravimetric analysis of
respirable and inhalable dust
The COSHH definition of a substance hazardous to health includes dust of any kind when
present at a concentration in air equal to or greater than 10 mg.m-3 8-hour TWA of inhalable
dust or 4 mg.m-3 8-hour TWA of respirable dust. This means that any dust will be subject to
COSHH if people are exposed above these levels. Some dusts have been assigned specific
WELs and exposure to these must comply with the appropriate limit.
Most industrial dusts contain particles of a wide range of sizes. The behaviour, deposition and
fate of any particular particle after entry into the human respiratory system and the body
response that it elicits, depend on the nature and size of the particle. HSE distinguishes two
size fractions for limit-setting purposes termed 'inhalable' and 'respirable'.
Inhalable dust approximates to the fraction of airborne material that enters the nose and mouth
during breathing and is therefore available for deposition in the respiratory tract. Respirable
dust approximates to the fraction that penetrates to the gas exchange region of the lung. Fuller
definitions and explanatory material are given in MDHS14/3.
Where dusts contain components that have their own assigned WEL, all the relevant limits
should be complied with.
Where no specific short-term exposure limit is listed, a figure three times the long-term
exposure should be used
TWA 2,4 mg/m3 2005-04-06 GB EH40
Further
information
: 15: For the purposes of these limits, respirable dust and inhalable dust are those fractions of
airborne dust which will be collected when sampling is undertaken in accordance with the
methods described in MDHS14/3 General methods for sampling and gravimetric analysis of
respirable and inhalable dust
The COSHH definition of a substance hazardous to health includes dust of any kind when
present at a concentration in air equal to or greater than 10 mg.m-3 8-hour TWA of inhalable
dust or 4 mg.m-3 8-hour TWA of respirable dust. This means that any dust will be subject to
COSHH if people are exposed above these levels. Some dusts have been assigned specific
WELs and exposure to these must comply with the appropriate limit.
Most industrial dusts contain particles of a wide range of sizes. The behaviour, deposition and
fate of any particular particle after entry into the human respiratory system and the body
response that it elicits, depend on the nature and size of the particle. HSE distinguishes two
size fractions for limit-setting purposes termed 'inhalable' and 'respirable'.
Inhalable dust approximates to the fraction of airborne material that enters the nose and mouth
during breathing and is therefore available for deposition in the respiratory tract. Respirable
dust approximates to the fraction that penetrates to the gas exchange region of the lung. Fuller
definitions and explanatory material are given in MDHS14/3.
Where dusts contain components that have their own assigned WEL, all the relevant limits
should be complied with. Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used
8.2 Exposure controls
Personal protective equipment
Respiratory protection : No personal respiratory protective equipment normally
required.
Hand protection : Chemical resistant gloves made of butyl rubber or nitrile
rubber category III according to EN 374.
Eye protection : Safety glasses
Skin and body protection : Protective suit
Hygiene measures : General industrial hygiene practice.
Protective measures : Wear full protective clothing and self-contained breathing apparatus.
Environmental exposure controls
General advice : If the product contaminates rivers and lakes or drains inform respective authorities.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance : liquid
Colour : blue
Odour : slight
Flash point : 100 °C
Bolling point : > 200 °C
Density : 1,99 g/cm3
at 25 °C
Viscosity, dynamic : 100.000 - 150.000 mPa.s
at 25 °C
10. Stability and reactivity
10.1 Reactivity
10.2 Chemical stability
10.3 Possibility of hazardous reactions
Hazardous reactions : Stable under recommended storage conditions., No hazards
to be specially mentioned.
10.4 Conditions to avoid
Conditions to avoid : no data available
10.5 Incompatible materials
Materials to avoid : Incompatible with oxidizing agents.
10.6 Hazardous decomposition products
Hazardous decomposition products
: This product may release the following:
Carbon monoxide, carbon dioxide and unburned
hydrocarbons (smoke).
Stable under normal conditions.
11. Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Acute oral toxicity : no data available
Skin corrosion/irritation
Skin irritation : no data available
Serious eye damage/eye irritation
Eye irritation : no data available
Respiratory or skin sensitization
Sensitisation : no data available
Target Organ Systemic Toxicant - Repeated exposure
: no data available
Further information : no data available
12. Ecological information
12.1 Toxicity
Toxicity to fish :
no data available
Toxicity to daphnia and other : no data available
aquatic invertebrates
12.2 Persistence and degradability
Biodegradability : no data available
12.3 Bioaccumulative potential
Bioaccumulation : no data available
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
12.6 Other adverse effects
Additional ecological information : no data available
13. Disposal considerations
13.1 Waste treatment methods
Contaminated packaging : Empty containers should be taken to an approved waste
handling site for recycling or disposal.
14. Transport information
Land transport
ADR / RID:
Not dangerous goods
Sea transport
IMDG:
Not dangerous goods
Air transport
IATA-DGR :
Not dangerous goods
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Major Accident Hazard
Legislation
: 96/82/EC Update: 2003
Directive 96/82/EC does not apply
15.2 Chemical Safety Assessment
16. Other information
Full text of R-phrases referred to under sections 2 and 3
R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact.
R48/20 Harmful: danger of serious damage to health by prolonged exposure
through inhalation.
R51 Toxic to aquatic organisms.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R53 May cause long-term adverse effects in the aquatic environment.
Full text of H-Statements referred to under sections 2 and 3.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H373 May cause damage to organs through prolonged or repeated exposure
if inhaled.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
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