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1. DESIGNATION OF PRODUCT AND COMPANY
Trade name Spinnaker Wood Life
Application of the substance: transparent wood preservatives wax based
Supplier: Cecchi Gustavo & C., Via Coppino 253, Viareggio 55049 (LU)
tel 0039 0584/383694 fax 0039 0584/395182 www.cecchi.it - info@cecchi.it
Information in case of emergency: 0039 0584/383694
2. Hazards identification.
2.1. Classification of the substance or mixture.
The product is classified as hazardous pursuant to the provisions set forth in Directives 67/548/EEC and 1999/45/EC and/or EC Regulation
1272/2008 (CLP) (and subsequent amendments and supplements). The product thus requires a safety datasheet that complies with the provisions
of EC Regulationn 1907/2006 and subsequent amendments.
Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet.
Danger Symbols: Xn-N
R phrases: 10-50/53-65-66
The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet.
2.2. Label elements.
Hazard labelling pursuant to Directives 67/548/EEC and 1999/45/EC and subsequent amendments and supplements.
HARMFUL
Xn
DANGEROUS FOR THE ENVIRONMENT
N
R10 FLAMMABLE.
R50/53 VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT.
R65 HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED.
R66 REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
S 2 KEEP OUT OF THE REACH OF CHILDREN.
S23 DO NOT BREATHE SPRAY.
S29 DO NOT EMPTY INTO DRAINS.
S46 IF SWALLOWED, SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THIS CONTAINER OR LABEL.
S51 USE ONLY IN WELL-VENTILATED AREAS.
S61 AVOID RELEASE TO THE ENVIRONMENT.
Contains: Naphtha (petroleum) hydrotreated heavy:Low boiling point hydrogen treated naphtha
Contains: 2-BUTANONE OXIME
May produce an allergic reaction.
2.3. Other hazards.
Information not available.
3. Composition/information on ingredients.
3.1. Substances.
Information not relevant.
3.2. Mixtures.
Contains:
Identification. Conc. %. Classification 67/548/EEC. Classification 1272/2008 (CLP).
- Naphtha (petroleum) hydrotreated heavy:
Low boiling point hydrogen treated naphtha 50 – 54 %
CAS. 64742-48-9 R10, R66, Xn R65, Note H P Carc. 1B H350, Muta. 1B H340, Asp. Tox. 1 H304, Note H P
EC. 265-150-3
INDEX. 649-327-00-6
- NAPHTA (PETROL.) HYDRODESULFURIZED HEAVY 6 – 7%
CAS. 64742-82-1 Xn R65, Note H P Carc. 1B H350, Muta. 1B H340, Asp. Tox. 1 H304, Note H P
EC. 265-185-4
INDEX. 649-330-00-2
- XYLENE (MIXTURE OF ISOMERS) 1,5 – 2%
CAS. 1330-20-7 R10, Xn R20/21, Xi R38, Note C Flam. Liq. 3 H226, Acute Tox. 4 H332, Acute Tox. 4 H312,
Skin Irrit. EC. 215-535-7 2 H315, Note C
INDEX. 601-022-00-9
- OCTANE 0,5 - 0,6%
CAS. 111-65-9 R67, F R11, Xn R65, Xi R38, N R50/53, Note C Flam. Liq. 2 H225, Asp. Tox. 1 H304, Skin Irrit. 2 H315,
STOT SE 3 H336, Aquatic Acute 1 H400, Aquatic Chronic 1 H410,
Note C EC. 203-892-1
INDEX. 601-009-00-8
- 1,2,4-TRIMETHYLBENZENE 0,35 - 0,4%
CAS. 95-63-6 R10, Xn R20, Xi R36/37/38, N R51/53 Flam. Liq. 3 H226, Acute Tox. 4 H332, Eye Irrit. 2 H319,
EC. 202-436-9 Skin Irrit. 2 H315, STOT SE 3 H335, Aquatic Chronic 2 H411
INDEX. 601-043-00-3
-MESITYLENE 8 0,15 - 0,2%
CAS. 108-67-R10, Xi R37, N R51/53 Flam. Liq. 3 H226, STOT SE 3 H335, Aquatic Chronic 2 H411
EC. 203-604-4
INDEX. 601-025-00-5
-CUMENE 0,15 - 0,2%
CAS. 98-82-8 R10, Xn R65, Xi R37, N R51/53, Note C Flam. Liq. 3 H226, Asp. Tox. 1 H304, STOT SE 3 H335,
EC. 202-704-5 Aquatic Chronic 2 H411, Note C
INDEX. 601-024-00-X
T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N =
Dangerous for the Environment(N)
The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet.
4. First aid measures.
4.1. Description of first aid measures.
EYES: Irrigate copiously with clean, fresh water for at least 15 minutes. Seek medical advice.
SKIN: Wash immediately with plenty of water. Remove contaminated clothing. If irritation persists, seek medical attention. Wash contaminated clothing before using them again.
INHALATION: Remove to open air. If breathing is irregular, seek medical advice.
INGESTION: Obtain immediate medical attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person.
4.2. Most important symptoms and effects, both acute and delayed.
For symptoms and effects caused by the contained substances see chap. 11.
4.3. Indication of any immediate medical attention and special treatment needed.
Follow doctor's orders.
5. Firefighting measures.
5.1. Extinguishing media.
SUITABLE EXTINGUISHING MEDIA
The extinction equipment should contain carbon dioxide, foam or chemical powders. For product leaks and spills that have not caught fire, nebulised water can be used to dispel flammable fumes and protect the individuals taking part in stemming the leak.
EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS
Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent explosions.
5.2. Special hazards arising from the substance or mixture.
HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Excess pressure may form in containers exposed to fire at a risk of explosion.
Do not breathe combustion products (carbon oxide, toxic pyrolysis products, etc).
5.3. Advice for firefighters.
GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health.
Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Hardhat with visor, fireproof clothing (fireproof jacket and trousers with ties around arms, legs and waist) work gloves (fireproof, cut proof and dielectric), self-respirator (self-protector).
6. Accidental release measures.
6.1. Personal precautions, protective equipment and emergency procedures.
Eliminate sources of ignition (cigarettes, flames, sparks, etc.) from the air in which the leak occurred. If there are no contraindications, spray solid products with water to prevent the formation of dust. Use breathing equipment if fumes or powders are released into the air. Block the leakage if
there is no hazard. Do not handle damaged containers or leaked product before donning ppropriate protective gear. Send away individuals who are not suitably equipped. For information on risks for the environmental and health, respiratory tract protection, ventilation and personal protection equipment, refer to the other sections of this sheet.
6.2. Environmental precautions.
The product must not penetrate the sewers, surface water, ground water and neighbouring areas.
6.3. Methods and material for containment and cleaning up.
For liquid products, suck into a suitable container (made of material not incompatible with the product) and soak up any leaked product with absorbent inert material (sand, vermiculite, diatomeous earth, Kieselguhr, etc). Collect the majority of the remaining material and deposit in
containers for disposal. For solid products, use spark proof mechanical tools to collect the leaked product and place in plastic containers. If there are no contraindications, use jets of water to eliminate product residues. Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.
6.4. Reference to other sections.
Any information on personal protection and disposal is given in sections 8 and 13.
7. Handling and storage.
7.1. Precautions for safe handling.
Avoid the accumulation of electrostatic charges.
Vapours may ignite with explosion, it is therefore necessary to avoid accumulation keeping the windows and doors open, ensuring crossventilation.
Without adequate ventilation, the vapours may accumulate at the bottom and ignite at a distance, if triggered off, with the risk of flashback. Keep far away from sources of heat, sparks and bright flames. Do not smoke, use matches or lighters. Keep the containers earthed while decanting and
wear antistatic boots. Vigorous stirring and flow through the pipings and equipment may cause the formation and accumulation of electrostatic charges due to the low conductivity of the product. In order to avoid the risk of fire outbreak and explosion never use compressed air during movement.
7.2. Conditions for safe storage, including any incompatibilities.
Store the containers sealed and in a well ventilated place.
7.3. Specific end use(s).
Information not available.
8. Exposure controls/personal protection.
8.1. Control parameters.
Name Tipo Country TWA/8h STEL/15min
mg/m3 ppm mg/m3 ppm
Nafta (petrolio),
frazione pesante di hydrotreating TLV-ACGIH 1755 0 0 0
XILENE (MISCELA DI ISOMERI) TLV-ACGIH 100 150 Pelle
OEL EU 221 50 442 100 Pelle
OTTANO TLV-ACGIH 300
1,2,4-TRIMETILBENZENE TLV-ACGIH 25
OEL EU 100 20
MESITILENE TLV-ACGIH 123 25
OEL EU 100 20
CUMENE TLV-ACGIH 50 Pelle
OEL EU 100 Pelle
8.2. Exposure controls.
As the use of adequate technical equipment must always take priority over personal protection equipment, make sure that the workplace is well aired through effective local aspiration or bad air vent. If such operations do not make it possible to keep the concentration of the product below the
permitted workplace exposure thresholds a suitable respiratory tract protection must be used. See product label for hazard details during use. Ask your chemical substance suppliers for advice when choosing personal protection equipment. Personal protection equipment must comply with the
rules in force indicated below. HAND PROTECTION
Protect hands with category II (ref. Directive 89/686/EEC and standard EN 374) work gloves, such as those in PVC, neoprene, nitryl or equivalent. The following should be considered when choosing work glove material: degradation, breakage times and permeation. Work glove resistance to
preparations should be checked before use, as it can be unpredictable. Gloves` limit depends on the duration of exposure.
EYE PROTECTION
Wear protective airtight goggles (ref. standard EN 166).
SKIN PROTECTION
Wear category II professional long-sleeved overalls and safety footwear (ref. Directive 89/686/CEE and standard EN 344). Wash body with soap and water after removing overalls.
RESPIRATORY PROTECTION
If the threshold value for one or more of the substances present in the preparation for daily exposure in the workplace or to a fraction established by the company`s prevention and protection service is exceeded, wear a mask with an A or universal filter, the class (1, 2 or 3) of which must be chosen according to the limit concentration of use (ref. standard EN 141).
The use of breathing protection equipment, such as masks with organic vapour and dust/mist cartridges, is necessary in the absence of technical measures limiting worker exposure. The protection provided by masks is in any case limited. If the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in the event of an emergency, or
when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17% volume, wear self-contained, open-circuit compressed air breathing apparatus (ref. standard EN 137) or fresh air hose breathing apparatus for use with full face mask, half mask or mouthpiece (ref. standard EN 138). An emergency eye washing and shower system must be provided.
In the presence of risks of exposure to splashes or squirts during work, adequate mouth, nose and eye protection should be used to prevent accidental absorption.
9. Physical and chemical properties.
9.1. Information on basic physical and chemical properties.
Appearance liquid
Colour colourless
Odour mild
Odour threshold. Not available.
pH. Not available.
Melting or freezing point. Not available.
Boiling point. Not available.
Distillation range. Not available.
Flash point. > 21 °C.
Evaporation Rate Not available.
Flammability of solids and gases Not available.
Lower inflammability limit. Not available.
Upper inflammability limit. Not available.
Lower explosive limit. Not available.
Upper explosive limit. Not available.
Vapour pressure. Not available.
Vapour density Not available.
Specific gravity. 0,860 Kg/l
Solubility not soluble in water
Partition coefficient: n-octanol/water Not available.
Ignition temperature. Not available.
Decomposition temperature. Not available.
Viscosity Not available.
Reactive Properties Not available.
9.2. Other information.
Solid content: 37,53 %
VOC (Directive 2004/42/EC) : 60,18 % - 517,55 g/litre.
VOC (volatile carbon) : 0
Appearence clear
10. Stability and reactivity.
10.1. Reactivity.
There are no particular risks of reaction with other substances in normal conditions of use.
10.2. Chemical stability.
The product is stable in normal conditions of use and storage.
10.3. Possibility of hazardous reactions.
The vapours may also form explosive mixtures with the air.
XYLENE (MIXTURE OF ISOMERS): stable, but may develop violent reactions in the presence of strong oxidising agents such as sulphuric and nitric acids and perchlorates. May form explosive mixtures with the air.
10.4. Conditions to avoid.
Avoid overheating, electrostatic discharge and all sources of ignition.
10.5. Incompatible materials.
Information not available.
10.6. Hazardous decomposition products.
In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released.
11. Toxicological information.
11.1. Information on toxicological effects.
The introduction of even small quantities of this liquid into the respiratory system in case of ingestion or vomit may cause bronchopneumonia and pulmonary edema. This product may have a degreasing action on the skin, producing dryness and chapped skin after repeated exposure. L'introduzione anche di piccole quantità di liquido nel sistema respiratorio durante l'ingestione o per il vomito può provocare broncopolmonite ed edma polmonare. Per esposizione ripetuta il prodotto può esercitare un'azione sgrassante sulla pelle che si manifesta con secchezza e crepolature.
XYLENE (MIXTURE OF ISOMERS): has a toxic effect on the CNS (encephalopathies). Irritating to the skin, conjunctivae, cornea and respiratory apparatus.
XYLENE (MIXTURE OF ISOMERS)
LC50 (Inhalation): 6350 ppm/4h Rat
LD50 (Oral): 3523 mg/kg Rat
LD50 (Dermal): 4350 mg/kg Rabbit
12. Ecological information.
This product is dangerous for the environment and highly toxic for aquatic organisms. In the long term, it may even have negative effects on aquatic
environment.
12.1. Toxicity.
OCTANE
IC50 (72h): 0,001 mg/l/72h Skeletonema costatum
EC50 (48h): 0,34 mg/l/48h Daphnia magna
12.2. Persistence and degradability.
Petroleum distillates, charcoal, vegetable extracts: they are mixtures of paraffinic, naphthenic, diterpenic and aromatic hydrocarbons. Their
behaviour on the environment depends on the concentration. In each case use, according to good working practices, avoiding disposal in the
environment. As a rule, the product is poorly biodegradable.
The paraffinic hydrocarbons fraction may be considered biodegradable in water and in air. They distribute mostly in the air. The small non
biodegradable amount which spreads into water tends to accumulate in fish.
OCTANE: biodegradable.
12.3. Bioaccumulative potential.
OCTANE: moderate bioaccumulation potential (log Ko/w>3).
12.4. Mobility in soil.
OCTANE: not mobile in soil.
12.5. Results of PBT and vPvB assessment.
Information not available.
12.6. Other adverse effects.
Information not available.
13. Disposal considerations.
13.1. Waste treatment methods.
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.
14. Transport information.
These goods must be transported by vehicles authorized to the carriage of dangerous goods according to the provisions set out in the current
edition of the Code of International Carriage of Dangerous Goods by Road (ADR) and in all the applicable national regulations.
These goods must be packed in their original packagings or in packagings made of materials resistant to their content and not reacting dangerously
with it. People loading and unloading dangerous goods must be trained on all the risks deriving from these substances and on all actions that must
be taken in case of emergency situations.
Road and rail transport:
ADR/RID Class: 3 UN: 1306
Packing Group: III
Label: 3
Nr. Kemler: 30
Limited Quantity. 5 L
Tunnel restriction code. (D/E)
Proper Shipping Name: WOOD PRESERVATIVES, LIQUID
Special Provision: 640E
Carriage by sea (shipping):
IMO Class: 3 UN: 1306
Packing Group: III
Label: 3
EMS: F-E, S-D
Marine Pollutant. YES
Proper Shipping Name: WOOD PRESERVATIVES, LIQUID (OCTANE)
Transport by air:
IATA: 3 UN: 1306
Packing Group: III
Label: 3
Cargo:
Packaging instructions: 366 Maximum quantity: 220 L
Pass.:
Packaging instructions: 355 Maximum quantity: 60 L
Special Instructions: A3
Proper Shipping Name: WOOD PRESERVATIVES, LIQUID
15. Regulatory information.
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture.
Seveso category. 9i, 6
Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006.
Product.
Point. 3 - 40
Contained substance.
Substances in Candidate List (Art. 59 REACH).
None.
Substances subject to authorisarion (Annex XIV REACH).
None.
Healthcare controls.
Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks related
to the workers' health and safety are modest and that the 98/24/EC directive is respected.
VOC (Directive 2004/42/EC) :
Interior and exterior minimal build woodstain.
VOC given in g/litre of product in a ready-to-use condition :
Limit value: 700,00 (2010)
VOC of product : 517,55
D.Lgs. 152/2006 e successive modifiche
Emissioni:
TAB. D Classe 3 00,80 %
TAB. D Classe 4 01,69 %
15.2. Chemical safety assessment.
No chemical safety assessment has been processed for the mixture and the substances it contains.
16. Other information.
Text of hazard (H) indications mentioned in section 2-3 of the sheet:
Carc. 1B Carcinogenicity, category 1B
Muta. 1B Germ cell mutagenicity, category 1B
Asp. Tox. 1 Aspiration hazard, category 1
Flam. Liq. 3 Flammable liquid, category 3
Acute Tox. 4 Acute toxicity, category 4
Skin Irrit. 2 Skin irritation, category 2
Flam. Liq. 2 Flammable liquid, category 2
STOT SE 3 Specific target organ toxicity - single exposure, category 3
Aquatic Acute 1 Hazardous to the aquatic environment, acute toxicity category 1
Aquatic Chronic 1 Hazardous to the aquatic environment, chronic toxicity category 1
Eye Irrit. 2 Eye irritation, category 2
Aquatic Chronic 2 Hazardous to the aquatic environment, chronic toxicity category 2
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H340 May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the
hazard>.
H332 Harmful if inhaled.
H312 Harmful in contact with skin.
H304 May be fatal if swallowed and enters airways.
H319 Causes serious eye irritation.
H315 Causes skin irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
Text of risk (R) phrases mentioned in section 2-3 of the sheet:
R10 FLAMMABLE.
R11 HIGHLY FLAMMABLE.
R20 HARMFUL BY INHALATION.
R20/21 HARMFUL BY INHALATION AND IN CONTACT WITH SKIN.
R36/37/38 IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
R37 IRRITATING TO RESPIRATORY SYSTEM.
R38 IRRITATING TO SKIN.
R50/53 VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC
ENVIRONMENT.
R51/53 TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT.
R65 HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED.
R66 REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
R67 VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS.
GENERAL BIBLIOGRAPHY
1. Directive 1999/45/EC and following amendments
2. Directive 67/548/EEC and following amendments and adjustments
3. Regulation (EC) 1907/2006 (REACH) of the European Parliament
4. Regulation (EC) 1272/2008 (CLP) of the European Parliament
5. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament
6. Regulation (EC) 453/2010 of the European Parliament
7. The Merck Index. - 10th Edition
8. Handling Chemical Safety
9. Niosh - Registry of Toxic Effects of Chemical Substances
10. INRS - Fiche Toxicologique (toxicological sheet)
11. Patty - Industrial Hygiene and Toxicology
12. N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition
Note for users:
The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability
and thoroughness of provided information according to each specific use of the product .
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and
safety laws and regulations. The producer is relieved from any liability arising from improper uses. |
