SAFETY DATA SHEET
 

 

 

 

SPINNAKER WOOD PROTECTION Revision 2 ottobre 2012 - n° batch 354-AB
 

1 Identification of the substance/preparation and of the company/undertaking
Trade name:                                   SPINNAKER WOOD PROTECTION
Application of the substance:      pigmented varnish for wood
Manufacturer/Supplier                  Cecchi Gustavo & C. srl
Information in case of emergency: 0584/383694

2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
R10-66: Flammable. Repeated exposure may cause skin dryness or cracking.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General
Classification guideline for preparations of the EU" in the latest valid
version.
At long or repeated contact with skin it may cause dermatitis due to the
degreasing effect of the solvent.
· Classification system:
The classification is according to the latest editions of the EU-lists, and
extended by company and literature data.
· Label elements
· Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives /
Ordinance on Hazardous Materials.
· Risk phrases:
10 Flammable.
66 Repeated exposure may cause skin dryness or cracking.
· Safety phrases:
2 Keep out of the reach of children.
23 Do not breathe fumes/aerosol.
24 Avoid contact with skin.
46 If swallowed, seek medical advice immediately and show this container or
label.
51 Use only in well-ventilated areas.
· Special labelling of certain preparations:
Contains 2-butanone oxime, cobalt carboxylate. May produce an allergic
reaction.
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description:
Resin mixture
Solvent mixture with additives
· Dangerous components:
CAS: 64742-48-9
EINECS: 265-150-3
naphta (petroleum), hydrotreated heavy
Xn R65
R10-66
Flam. Liq. 3, H226
Asp. Tox. 1, H304
50-100%
CAS: 64742-95-6 petroleum, nafta, licht aromatisch
Xn R65
Xi R36/38
N R51/53
R10
Flam. Liq. 3, H226
Asp. Tox. 1, H304
Aquatic Chronic 2, H411
Skin Irrit. 2, H315; Eye Irrit. 2, H319
<= 2.5%
CAS: 96-29-7
EINECS: 202-496-6
2-butanone oxime
Xn R21-40
Xi R41
Xi R43
Carc. Cat. 3
Carc. 2, H351
Eye Dam. 1, H318
Acute Tox. 4, H312; Skin Sens. 1, H317
<= 2.5%
CAS: 64742-94-5
EINECS: 265-198-5
Solvent naphtha (petroleum), heavy arom.
Xn R65
N R51/53
Asp. Tox. 1, H304
<= 2.5%
CAS: 95-63-6
EINECS: 202-436-9
1,2,4-trimethylbenzene
Xn R20
Xi R36/37/38
N R51/53
R10
Flam. Liq. 3, H226
Aquatic Chronic 2, H411
Acute Tox. 4, H332; Skin Irrit. 2, H315;
Eye Irrit. 2, H319; STOT SE 3, H335
<= 2.5%
· Additional information:
For the wording of the listed risk phrases refer to section 16.

4 First aid measures
· Description of first aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: Seek medical treatment.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol
resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
No further relevant information available.
· Advice for firefighters
· Protective equipment: No special measures required.

6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal
binders, sawdust).
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage
· Handling:
· Precautions for safe handling
Work only in fume cupboard.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· Specific end use(s) No further relevant information available.

 8 Exposure controls/personal protection
· Additional information about design of technical facilities:
No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical
values that have to be monitored at the workplace.
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Do not eat, drink, smoke or sniff while working.
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In
case of intensive or longer exposure use self-contained respiratory protective
device.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the
substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for
the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times,
rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but
also on further marks of quality and varies from manufacturer to manufacturer.
As the product is a preparation of several substances, the resistance of the
glove material can not be calculated in advance and has therefore to be checked
prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the
protective gloves and has to be observed.
· Eye protection:
Tightly sealed goggles
· Body protection: Use protective suit.

9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: According to product specification
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
· Flash point: > 36°C
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 240°C
· Decomposition temperature: Not determined.
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However,
formation of explosive air/vapour mixtures
are possible.
· Explosion limits:
Lower: 0.6 Vol %
Upper: 7.0 Vol %
· Vapour pressure at 20°C: 1 hPa
· Density at 20°C: 0.89 g/cm3
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Segregation coefficient (n-octanol/
water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic at 20°C: 25 s (DIN 53211/4)
· Solvent content:
Organic solvents: 56.9 %
VOC content: 506.6 g/l / 4.23 lb/gl
Solids content: 40.5 % (VB% 1h 150C)
· Other information No further relevant information available.

10 Stability and reactivity
· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.

12 Ecological information
· Toxicity
· Acquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous
for water
Do not allow product to reach ground water, water course or sewage system, even
in small quantities.
Danger to drinking water if even extremely small quantities leak into the
ground.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to
reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· Land transport ADR/RID (cross-border)
· ADR/RID class: 3 (F1) Flammable liquids.
· Danger code (Kemler): 30
· UN-Number: 1263
· Packaging group: III
· Hazard label 3
· UN proper shipping name: 1263 PAINT (not viscous)
· Tunnel restriction code D/E
· Maritime transport IMDG:
· IMDG Class: 3
· UN Number: 1263
· Label 3
· Packaging group: III
· EMS Number: F-E,S-E
· Marine pollutant: No
· Proper shipping name: PAINT
· Air transport ICAO-TI and IATA-DGR:
· ICAO/IATA Class: 3
· UN/ID Number: 1263
· Label 3
· Packaging group: III
· Proper shipping name: PAINT
· UN "Model Regulation": UN1263, VERF (niet viskeus), 3, III
· Special precautions for user Warning: Flammable liquids.
· Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the
substance or mixture
· National regulations:
· Technical instructions (air):
Class Share in %
I <= 2,5
· Waterhazard class:
Water hazard class 3 (Self-assessment): extremely hazardous for water.
· Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not
constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship.
· Relevant phrases
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H411 Toxic to aquatic life with long lasting effects.
R10 Flammable.
R20 Harmful by inhalation.
R21 Harmful in contact with skin.
R36/37/38 Irritating to eyes, respiratory system and skin.
R36/38 Irritating to eyes and skin.
R40 Limited evidence of a carcinogenic effect.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement
concerning the International Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
VOC: Volatile Organic Compounds (USA, EU)